THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

频率域电磁法中视电阻率全区定义

视电阻率定义在电法勘探中得到广泛的应用。目前在频率域电磁法中常常采用远区视电阻率定义。由于在频率域中收发距并非足够大,以致在低频段远区定义视电阻率往往不能反映地下电阻率值。我们定义全区电阻率及引入校正系数K,经二层三层模型及野外实测资料的计算,证明了方法的有效性。     

华北板块北缘东段陆缘活动带构造岩片划分及变质变形特征

1∶25万和龙市幅、汪清县幅等九幅区域地质调查成果显示,华北板块北缘东段残存着数条元古代-古生代不同时期的构造岩片,这些构造岩片均经历了强烈的变形改造及变质作用叠加,记录了增生型造山带在不同演化阶段热-动力学条件。吉林东部华北板块北缘陆缘活动带东段内元古代-古生代构造地层单位的确定,对探讨吉黑地区的大地构造演化具有重要意义。     

某矿山天然放射性核素的调查

对某矿山工作场所和生活区分别进行了样品采集,并使用ORTEC公司生产的16000道HPGeγ能谱仪进行了测量。结果表明,该矿山工作场所天然放射性核素的比活度大多高于生活区,其中危害最大的为尾矿坝;某些生活区天然放射性核素的比活度比对照点和国家均值要高,但多数都在国家均值范围内,最高值出现在3号生活区的农田土样中,其天然放射性核素的比活度分别为：α（226^Ra）——750．4Bq/kg、α（232^Th）——91．5Bq/kg、α（40^K）——1202Bq/kg。     

杭州湾大桥北航道桥索塔施工高精度

在高大建筑施工中,高精度的标高传递测量是施工测量的难点之一.本文以杭州湾跨海大桥高大索塔标高传递测量为例,提出了全站仪垂直向上测距法高差测量,较好地解决了高大索塔施工标高控制的问题,实践证明该法是恶劣环境下高大建筑物高程传递测量的一种较为有效的方法,可以满足施工的高精度要求和保证工期.     

农田排水对沼泽湿地毛果苔草的影响及效应

随着三江平原沼泽湿地的垦殖,农田排水不断进入沼泽湿地,对湿地生态系统造成不同程度的影响。当一定氮、磷浓度的农田排水进入毛果苔草沼泽湿地后,水中TN、NH₄+-N、TP和PO₄3--P的含量均明显升高,8~9月份TN和NH₄+-N含量分别为自然沼泽湿地水体的1.51~2.10倍和1.53~3.02倍;TP和PO₄3--P含量分别为1.30~4.08倍和4.33~11.33倍。接受农田排水的毛果苔草根、茎叶生物量明显增高,相应的植物不同部分TN、TP含量也明显增高,其毛果苔草根部TN、TP含量与水中TN、TP含量的相关关系比自然湿地毛果苔草的这一相关关系更强,表明农田排水可促进毛果苔草的生长和对氮、磷的吸收。由于农田排水中磷的含量相对较高,造成湿地水系统N/P失衡,对湿地毛果苔草生态系统的稳定性和生物生产力形成潜在的威胁,因此应控制农田排水直接排入沼泽湿地。