龙门山的石炭系

四川江油马角坝、北川沙窝子是龙门山上泥盆统、下石炭统区域性主要岩石地层单位的命名地,对这两地及前龙门山北段地区的调查发现:1)前人关于马角坝地区下石炭统的层序和马角坝组主要化石群的记载有与实际不符之处,当地实际缺失杜内期至维宪早、中期地层,总长沟群的时代应属晚维宪—谢尔普霍夫期,重新厘定马角坝组含义,新指定北川桂溪沙窝子的长滩子剖面为该组的参考剖面;2)在长滩子剖面长滩子组顶部Beichuano-phyllum与Cystophrentis珊瑚化石富集层之上、马角坝组Pseudouralinia富集层之下的大套厚层白云岩层组合的中上部层位,发现Cystophrentis等化石,基于这套厚层白云岩组合的岩性特征明显、顶底接触关系清楚、区域展布广泛,建议引用前人提出的黑岩窝组,同时对黑岩窝组的岩性、岩层组合与古生物组合特征、厚度和时代归属等作了补充和修正,根据其中所含生物群认为黑岩窝组时代为晚泥盆世法门晚期;3)通过与周边地区的地层对比,探讨了龙门山石炭纪的古地理格局及环境演变,认为除前龙门山中部的桂溪—沙窝子等狭窄地区因长期地处泥盆纪海水入侵通道,地势低洼,出现了残存式的杜内期沉积外,前龙门山南、北段广大地区杜内期至维宪早、中期已大部抬升露出水面,直到维宪晚期的全球性海侵,前龙门山遂再度没于水下,出现准平原化浅滩相沉积环境,并延续至石炭纪末。     

兰坪金顶铅锌矿床泥底辟流体成矿特征初探

兰坪金顶铅锌矿床的成矿过程与油气的生成有许多相似之处,泥底辟构造在金顶铅锌矿床的成矿过程中起着极为重要的作用。首先,随着泥底辟的上侵,塑性泥流夹带大量气体到构造圈闭中释放压力,扩大成矿空间;其次,流体的去气作用在构造圈闭中进行一系列的强改造活动,进而促使铅锌矿体的形成。文章通过对金顶铅锌矿床形成有关的泥底辟流体的来源、流体形成原因、流体在张性-挤压走滑盆地阶段的演化及金顶铅锌矿床成矿的泥底辟流体特征的分析,认为兰坪金顶铅锌矿床的形成与泥底辟构造密切相关,该矿床具泥底辟流体的成矿特征。     

广西大厂锡矿铟的地球化学特征及成因机制初探

广西大厂锡矿位于江南古陆西南缘,桂西北海西-印支期被动陆缘裂谷盆地北部的断裂凹陷盆地中,是中国重要的、以锡为主的有色金属矿床。它主要由长坡-铜坑和高峰矿床、拉么矿床、大福楼矿床和亢马矿床等组成,其铟资源量约6 000 t。文章在对长坡-铜坑矿床、高峰矿床以及拉么矿床不同类型围岩（包括花岗岩质岩石）、矿石以及不同矿床类型中矿石矿物（硫化物和氧化物）中的In、Cu、Cd、Sn、Fe、Zn等微量元素分析的基础上,结合不同类型矿床、不同矿物组合中硫化物的微量元素电子探针测试以及硫同位素分析结果,初步认为大厂锡矿岩浆源区是富铟的,在正常的沉积岩中不存在铟的初始富集;In主要赋存于闪锌矿中,与层状和块状的矿体关系密切。在成矿作用过程中,In的分布和富集对矿物组合和矿石类型具有明显的选择性。大厂铟矿的形成是富铟的岩浆源区重融产生含铟岩浆,在岩浆侵位冷却过程中,由岩浆结晶所产生的流体携带In、Cu、Fe、Zn、Sn等成矿元素从岩浆中出溶,形成含In的成矿流体。水-岩反应以及在大气降水来源流体的参与下,导致In、Cu、Fe、Zn、Sn等从成矿流体中沉淀、富集成矿。     

常规次生晕法在广西资源县云头界钨钼矿找矿中的成果及意义

广西资源县云头界钨矿异常区多被表土覆盖,局部出露钨矿化。据钨重砂矿物化学性质较稳定,风化剥蚀后迁移距离较近,而异常区表土覆盖不厚的特点,采用次生晕化探方法对云头界钨矿异常区1.4km2开展化探扫面找矿。根据8条化探剖面线共575个样品分析结果,圈出了6个钨异常区,在其中4个钨异常区施工槽探工程,都发现对应的石英脉型钨矿体。这揭示了该区矿体与次生晕异常的分布具有非常一致的对应关系。次生晕化探异常表明,该矿主矿脉沿走向长度超过1km,矿床规模可望达到中型。常规次生晕法在云头界钨矿异常区找矿效果明显,这对华南风化土层覆盖区钨矿找矿工作有重要的启示。     

Oxidative pre-treatment in thiosulphate leaching of sulphide gold ores

A diagnostic leaching showed that partial oxidation of the sulphide minerals in a gold ore was beneficial for thiosulphate leaching of gold. A pre-treatment process with oxidative ammoniacal solution enhanced the thiosulphate leaching of the sulphide ore, while the thiosulphate consumption was substantially reduced. The sulphide minerals partially decomposed in the pre-treatment process, exposing gold to the leach solution. Oxygen input by air bubbling and a longer contact time enhanced the oxidative ammonia pre-treatment process and hence accelerated subsequent thiosulphate leaching of the sulphide ore. Gold extraction in 0.8 M ammonia and 0.1 M thiosulphate solution after 24 h increased from 69% without pre-treatment to 81%, 84%, 90% and 94% respectively after 1, 3, 7 and 22 h pre-treatment. The consumption of sodium thiosulphate was 2.37 kg/t after 24 h leaching without pre-treatment, but was negligible after over 1 h oxidative ammonia pre-treatment. A counter-current leaching process was conducted in the leaching of the sulphide ore. The fresh leachant still gave higher leaching rates in contact with the pre-leached ore, while the pre-used leachant had significantly lower leaching kinetics and overall gold extraction in contact with the fresh ore. This 2-step counter-current leaching process proved that the leachant, other than the passivation, was the determinant factor causing the gold leaching rates to decrease after a certain time of leaching. The findings enable the thiosulphate leaching of high sulphide containing gold ores to be more efficient at lower thiosulphate consumption following the oxidative ammoniacal pre-treatment.     

兰坪盆地演化与成矿特征

兰坪盆地的演化受控于盆地所处的构造背景,经历了中三叠世至早侏罗世的陆内裂谷盆地、中-晚侏罗世的拗陷盆地、白垩纪的前陆盆地、古新世-中新世的走滑盆地。盆内成矿与盆地性质密切相关,陆内裂谷盆地阶段是重要的成矿期,具热水沉积矿床特征;拗陷盆地阶段多形成铜多金属矿床;前陆盆地阶段为喜山期的成矿作了物质准备;走滑盆地阶段,由于推覆构造活动强烈,深部流体和浅部红层中的盆地流体的混合,提供了大量的矿物质,并就位于构造圈闭中,形成如金顶铅锌矿等大型矿床。     

鄂尔多斯盆地天环坳陷迁移演化与坳陷西翼油气成藏

鄂尔多斯盆地是我国陆上最重要的含油气盆地之一,本文以鄂尔多斯盆地西缘为研究对象,以地震反射资料为基础,主要采用地震剖面"层拉平"与"平衡剖面恢复"等技术手段,对天环坳陷形成与迁移演化历史进行了动态分析。研究结果表明:1)天环坳陷最早形成于晚侏罗世,后期由于受燕山晚期及喜马拉雅山期构造运动影响,坳陷核部逐渐向东迁移至现今位置,前后累计迁移距离约30 km;2)当坳陷核部向东迁移至有效烃源岩范围附近时,原先已形成的油气藏发生重新调整,油气向坳陷西翼高部位运移、聚集,从而形成了次生构造油气藏。     

安徽峙门口铜—铁—金—硫矿床地球化学特征

峙门口铜—铁—金—硫矿床发育上部层状矿体和下部脉状矿体。上部层状矿石重晶石的δ~(34)S值为+14.10‰～+18.90‰。上部层状矿石黄铁矿和方铅矿的δ~(34)S值为+3.50‰～+5.84‰,下部脉状矿石黄铁矿的δ~(34)S值为+4.80‰～+6.80‰。下部脉状矿石中脉石英的δ~(18)O值为+14.3‰～+1 8.5‰,δ~(30)Si值为-0.3%0～-0.2‰。下部脉状矿石黄铁矿Re/Os比值为78.342～175.540,上(顶)部层状矿石中黄铁矿Re/Os比值为62.298～169.545。从下部脉状矿石到上部层状矿石,δ~(34)S值、Re/Os比值和流体包裹体温度249 ℃→97 ℃逐渐降低,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb平均值和Os_总、Re、~(187)Re等含量逐渐增高。矿石黄铁矿Re-Os同位素等时线年龄303±33 Ma。地质地球化学特征反映峙门口铜—铁—金—硫矿床为海底热水喷流沉积成因。     

Some Fundamental Issues in Dynamic Compression and Tension Tests of Rocks Using Split Hopkinson Pressure Bar

Accurate characterizations of rock strengths under higher loading rates are crucial in many rock engineering applications. The split Hopkinson pressure bar (SHPB) system has been used to quantify the dynamic compressive strength of rocks using the short cylindrical specimen and the dynamic tensile strength of rocks using the Brazilian disc (BD) specimen. However, SHPB is a standard tool that is suitable for metal testing; there are some fundamental issues that need to be carefully visited in applying SHPB to rock dynamic tests. This paper addresses several such critical issues, including the choice of slenderness ratio of the compressive specimen, the effect of friction between the sample and bars on the measured results of compressive strength, the necessity of dynamic force balance on the dynamic BD test, and the validity of using the standard BD equation in the data reduction. We show that with proper experimental designs that address these issues, the dynamic compressive strength and dynamic tensile strength of rocks measured using SHPB are valid and reliable.     

Application of the stable-isotope system to the study of sources and fate of Hg in the environment: A review

With the improvement of analytical methods and the development of multiple-collector inductively coupled plasma-mass spectrometry (MC-ICP/MS), research on non-traditional stable isotope (Cu, Zn, Fe, Se, Mo, Cr, Hg) in geochemistry has made tremendous progress in the past decade. Recent studies have demonstrated that both organic and inorganic reactions may cause Hg isotope fractionation, and variations of Hg isotopic composition in the environment have been successfully employed to explain Hg pollution history, Hg sources and tracking Hg pathways in nature. Furthermore, Hg isotopic fractionation studies can be a powerful tool in the calibration of global Hg cycling models. Stable isotope geochemistry of Hg is therefore becoming a new frontier subject in earth sciences. Based on summarizing previous research, this paper outlines the main advances in the study of Hg stable isotopes with particular emphasis placed on a brief explanation of Hg isotope analytical techniques, possible Hg isotope fractionation mechanisms observed in both natural and experimental processes, Hg isotope composition variations in different environmental matrices, and the application prospects of the Hg stable isotopes in environmental geosciences.