Researches on the Internal Molecular Weight Uniformity of Chitosan Biomaterials

Uniform molecular weight(Mw)chitosan(CS)is highly demanded in medical biomaterial industry.This present article described heterogeneous degradation of CS in aqueous HCl/ethanol solution,in which progress uniform Mw CS was successfully prepared.The Mw distribution of CS was measured by gel permeation chromatography(GPC)analysis.Moreover,the structure and properties of degraded CS were characterized by Fourier transform infrared spectroscopy(FT-IR),nuclear magnetic resonance spectroscopy(^1H NMR),X-ray diffraction(XRD)and thermogravimetric(TG)analysis.In addition,the biocompatibility of degraded CS was also assessed by hemolysis rate(HR)measurement.The Mw of CS dramatically decreased from 246 KDa to 76 k Da at the initial 30 min,and stabilized at 18 kDa after 24 h.GPC analysis results showed that the degraded CS molecular become homogenization.FT-IR and 1 H NMR analysis confirmed the basic structure of CS molecular backbone was not destroyed during this progress.Besides,the water solubility of CS was not significantly influenced by this reaction.Moreover,the XRD analysis revealed that crystallinity of degraded CS increased from 70.32% to 99.25%with time.The TG analysis showed improved thermal stability of degraded CS.HR measurement demonstrated the degraded CS possessed excellent biocompatibility.This simple and efficient heterogeneous degradation would open up a new route to produce uniform Mw CS.     

Climate Change of 4°C Global Warming above Pre-industrial Levels

Using a set of numerical experiments from 39 CMIP5 climate models, we project the emergence time for 4°C global warming with respect to pre-industrial levels and associated climate changes under the RCP8.5 greenhouse gas concentration scenario. Results show that, according to the 39 models, the median year in which 4°C global warming will occur is 2084. Based on the median results of models that project a 4°C global warming by 2100, land areas will generally exhibit stronger warming than the oceans annually and seasonally, and the strongest enhancement occurs in the Arctic, with the exception of the summer season. Change signals for temperature go outside its natural internal variabilities globally, and the signal-to-noise ratio averages 9.6 for the annual mean and ranges from 6.3 to 7.2 for the seasonal mean over the globe, with the greatest values appearing at low latitudes because of low noise. Decreased precipitation generally occurs in the subtropics, whilst increased precipitation mainly appears at high latitudes. The precipitation changes in most of the high latitudes are greater than the background variability, and the global mean signal-to-noise ratio is 0.5 and ranges from 0.2 to 0.4 for the annual and seasonal means, respectively. Attention should be paid to limiting global warming to 1.5°C, in which case temperature and precipitation will experience a far more moderate change than the natural internal variability. Large inter-model disagreement appears at high latitudes for temperature changes and at mid and low latitudes for precipitation changes. Overall, the inter-model consistency is better for temperature than for precipitation.     

西藏雄村斑岩型铜(金)矿床Ⅰ、Ⅱ号矿体热液黑云母特征及地质意义

雄村铜(金)矿区位于西藏冈底斯成矿带中段南缘,由Ⅰ、Ⅱ、Ⅲ号矿体和多个矿化体组成。本文以Ⅰ、Ⅱ号矿体钾硅酸盐化蚀变带内的热液黑云母为研究对象,采用光薄片镜下鉴定、电子探针等分析方法,系统研究了热液黑云母的产状和成分特征。结果显示,雄村矿区Ⅰ号矿体黑云母类型主要为金云母和镁质黑云母;Ⅱ号矿体黑云母类型为镁质黑云母。两个矿体黑云母都具有低Ti(TiO_2 3%)、高Al(Al_2O_315%)的特点,且具有较高的MgO含量,Mg/Fe0.5,K/Na10,显示了与矿化良好的相关性。Ⅰ号矿体热液黑云母平均结晶温度470℃,氧逸度位于镍-氧化镍缓冲剂与磁铁矿-钛铁矿缓冲剂之间(NNO—HM);Ⅱ号矿体热液黑云母平均结晶温度234℃,氧逸度位于镍-氧化镍缓冲剂与铁橄榄石-石英-磁铁矿缓冲剂之间(NNO—FQM),说明Ⅰ号矿体形成于较高温、高氧逸度的热液系统,Ⅱ号矿体形成于相对较低温、低氧逸度的热液系统。此外,Ⅰ号矿体热液黑云母Ⅳ(F)值介于0.61～2.72之间,平均值1.26,Ⅳ(Cl)值介于-5.49～-4.53之间,平均值-5.03,Ⅳ(F/Cl)值介于5.63～7.89之间,平均值6.29;Ⅱ号矿体热液黑云母Ⅳ(F)值介于1.83～3.32之间,平均值2.66,Ⅳ(Cl)值介于-5.64～-4.89之间,平均值-5.31,Ⅳ(F/Cl)值介于7.14～8.68之间,平均值7.97,说明Ⅰ、Ⅱ号矿体都形成于富Cl的热液系统,且Ⅱ号矿体热液较Ⅰ号矿体更富Cl,贫F。富Cl流体易萃取流体中的Cu和Au等金属元素并以Cl的络合物形式运移,在沿构造裂隙向上运移的过程中,物理化学条件发生改变,使得流体中金属元素络合物溶解度降低,促使硫化物沉淀成矿。     

SPOT5遥感影像在土地调查中的应用

本文结合SPOT5卫星影像在某地区土地利用调查中的应用,介绍了利用SPOT5卫星遥感影像进行室内判读、结合外业调查建立土地利用数据库,进行土地利用调查的技术方法和工作流程。     

3维块匹配小波变换的极化SAR非局部均值滤波

极化合成孔径雷达(SAR)图像受相干斑噪声的影响,难以很好地保持结构特性,针对这个问题提出了一种采用3维块匹配小波变换的非局部均值滤波算法NL-3DWT(Nonlocal Filter based on 3-D Patch Matching Wavelet Transform)。该算法使用块匹配的3维非抽样小波变换对极化总功率图进行预滤波,在此基础上使用边界对齐窗提取结构相似像素,同时使用Sigma范围选择极化SAR数据的散射相似像素,共同构成相似像素集合;构建结构保持权重函数增大图像结构信息在块相似性度量时的权重,最终实现极化SAR图像结构保持的相干斑抑制。该算法增强了图像结构特征的表达,提高了结构相似像素选择的准确性,机载极化SAR数据实验结果表明,NL-3DWT算法能够在抑制相干斑噪声的同时,更有效地保持极化SAR图像的结构特性和极化散射特性。     

应用核磁共振成像(NMRI)技术研究复合剂驱油特征

本文应用核磁共振成像技术,在均值、非均值模型中研究了复合剂驱油动态实验过程。观察及分析了复合剂驱油特征和效果,对复合剂驱油段塞前缘进行了实时跟踪,得到了复合剂驱油段塞前缘油墙的形成及剩余油分布与运移的二维图像,给出了复合剂驱油后,剩余油的饱和度分布曲线。实验表明:在层状非均值地层中,若渗透率差异大,复合剂段塞主要进入高渗层,而波及不到低渗层,即复合剂波及效率低。若渗透率差异小,复合剂段塞大部分进入高渗层,有少部分进入低渗层,即复合剂波及效率较高。     

星载微波散射计两种体制的比较

星载微波散射计可以提供全球、全天候、高精度、高分辨率和短周期的海面风场数据。根据雷达天线足印的形状,雷达散射计主要包括扇形波束体制与笔形波束体制两种形式。概述了两种体制微波散射计在设计结构及后期数据处理算法中的优缺点,并对两种不同体制散射计的系统仿真数据进行比较。分析结果表明:对于小型卫星平台,Ku波段的旋转扫描扇形波束散射计比笔形波束圆锥扫描散射计具有更优的风场反演性能。     

PTC管桩复合地基应力扩散效应研究

预应力混凝土薄壁（PTC）管桩复合地基作为常见的基础型式在软土地区具有良好的实用价值和应用前景。在实际工程中,复合地基下卧层附加应力的确定一直是重点和难点,因此对PTC管桩复合地基应力扩散效应的研究具有十分重要的意义。针对天津软土地区进行了3组不同垫层厚度的复合地基现场静载试验,基于现场试验建立并验证了数值模拟方法,对比研究了该型式复合地基的承载特性;通过已建立的数值模拟方法研究了不同工况下PTC管桩复合地基的应力扩散现象,结合复合地基应力扩散理论确定了扩散角的取值范围,分析了土质、加固深度和外荷载对扩散角的影响规律。计算结果可为工程设计提供依据。     

应用九层全球大气格点模式进行跨季度短期气候预测系统性试验

利用中国科学院大气物理研究所9层大气环流模式（IAP9L AGCM）对夏季气候进行了30年（ 1970～1999年）集合回报试验,并采用统计学分析方法对跨季度夏季短期气候的可预测性问 题进行了初步探讨. 结果表明,该模式对对流层中、高层大气环流的预测能力强于低层,位 势高度场和表面气温的可预测性最大,而降水的可预测性则相对较小. 对流层中、高层位势 高度场的可预测性基本呈带状分布,越靠近赤道可预测性越高;而降水的可预测性基本局限 于赤道东太平洋及热带个别区域. 由此可见,降水的预测极为困难和复杂,订正系 统的研究和寻找新的预报物理因子非常重要.      

东南极内陆格罗夫山地区冰厚及冰下地形特征

中国第30次南极科学考察队格罗夫山分队(CHINARE30, 2013-2014年)利用雪地车载深层探冰雷达在东南极格罗夫山地区开展了测线总长度超过200 km大范围、高分辨率的冰厚及冰下地形调查, 获得了哈丁山北部和萨哈罗夫岭与阵风悬崖之间详细的冰厚及冰下地形特征. 通过对雷达数据分析表明, 哈丁山北部区域平均冰厚为580 m, 最大冰厚超过1 000 m, 出现在该区域的东北方向, 而东南方向冰厚相对较小; 萨哈罗夫岭与阵风悬崖之间区域的平均冰厚为610 m, 最大冰厚超过1 100 m, 该区域槽谷发育十分成熟, 槽谷形态近似呈U型. 通过对雷达剖面影像的筛选和分析, 推测在格罗夫山地区可能存在2个液态冰下湖泊.