Isolation and pharmacological activities of bromophenols from Rhodomela confervoides

Four bromophenols were isolated from the extract of marine red alga,Rhodomela confervoides by column chromatography and HPLC methods. By means of spectroscopic methods inclding IR, MS, 1D, and 2D-NMR techniques, their structures were elucidated as (1) 3-bromo-4,5-dihydroxy benzoic acid methyl ester; (2) bis (2,3-dibromo-4,5-dihydroxybenzyl) ether; (3) 3,4-dibromo-5-(methoxymethyl)-1,2-benzenediol and (4) 3-bromo-4,5-dihydroxy-benzaldehyde. Compound 1 was first isolated from the algae in nature, and 1, 4 were found to have selective cytotoxic activities against KB, Bel 7402 and A549 cells, 2 showed powerful antibacterial activities againstStaphylococcus aurens andPseudomonas aeruginosa. Supported by National “863” Program (No. 2004AA625030, 2001AA620503), Quingdao marine sciences project (No. 04-2-NN-26) and Key Knowledge Innovative Project of the Chinese Academy of Sciences (KZCX3-SW-215).     

南秦岭勉略蛇绿构造混杂带辉长辉绿岩类微量-稀土元素地球化学

应用元素地球化学方法．研究了勉略带中辉长辉绿岩的相关特征．结果表明．勉略蛇绿构造混杂带内的辉长岩属高铝强碱质辉长岩类，是地幔橄榄岩部分熔融的产物。辉绿岩墙群属强碱铝质基性岩类，过渡族元素蛛网图与辉长岩类几乎完全相同，其不相容元素与辉长岩类总体趋势相一致．反映了一种递进岩浆演化趋势。因此，本区辉长岩与辉绿岩墙群具同源岩浆分异演化的地球化学特征．其均为勉略蛇绿岩的重要组成端元。     

渤海湾盆地黄骅坳陷孔南地区古近系孔店组二段物源分析*

根据重力异常资料、地震资料,综合运用重矿物法、碎屑岩类分析法并结合砂体展布特征,基本明确了黄骅坳陷孔南地区孔店组二段的物源区位置及来源方向。区域布格重力异常场从宏观上勾绘出了孔南地区地势的起伏状况,对物源分析具有重要参考意义。在研究区湖盆周缘都发育砂体,在各物源口的砂体展布规律在平面上表现为呈扇形展布的特征,宏观上指示了物源的涉及范围。盆外下切沟槽能大致确定研究区周缘各物源口位置,前积反射结构也能指示出存在物源供给的地区。重矿物以锆石、电气石、金红石、石榴石、磁铁矿为主,不同的物源区具有不同的重矿组合特征,其变化规律指示了碎屑物质的搬运方向和搬运途径。碎屑岩组分以长石为主,其次为石英,岩屑含量较低,主要为岩浆岩岩屑,岩屑类型指示了物源区母岩类型主要为岩浆岩。该区孔店组二段沉积时期在东南、西南、西北、东北4个方向上都存在物源,进一步可识别出乌马营、叶三拔、舍女寺等10个子物源,它们共同控制了孔南地区孔店组二段沉积时期砂体的形成和分布,形成多物源环湖盆分布的特征。     

台湾海峡西南部海域春季悬浮体及沉积物来源与输运机制

台湾海峡作为连接东海和南海的重要通道,其悬浮体和沉积物的来源和输运格局非常复杂。2005年4~5月利用带有浊度传感器和荧光传感器的SD204型CTD对台湾海峡西南部海域627个站位的悬浮体特性进行了综合调查,并采集了底层沉积物。在室内分别利用英国Marlvern公司生产的Mastersizer 2000型激光粒度仪和德国ELEMENTOR公司生产的ELEMENTOR varioELIII型元素分析仪对表层沉积物进行了粒度分析和沉积物碳、氮含量测定,结果表明,台湾海峡西南部海域春季受粤东沿岸流、韩江冲淡水、九龙江冲淡水及台湾海峡混合水影响,其中粤东沿岸流在向北输运过程中影响强度逐渐减弱,韩江冲淡水影响范围较大,并且在西南季风的控制下向东北方向输运;长时间尺度的沉积物输运格局表明,近岸沉积物由岸向海输运,远海地区沉积物由海向岸输运,并且在汕尾南部海域、南澳岛东南部海域形成了沉积物的汇聚区,沉积物以陆源为主;表层沉积物的输运过程受控于区域内水团、悬浮体分布及运动格局;在春季上升流形成早期尽管叶绿素荧光值相对较低,但其对表层沉积物的输运过程起着非常重要的控制作用。     

洛坝铅锌矿床的构造演化分析

洛坝铅锌矿床位于黄诸关韧脆性变形带所波及的范围内,断裂、褶皱、劈理、节理等形态构造类型均很发育,经对小型构造的统计及应力场分析证明,矿区变形主要是在海西—印支期长期存在的南北向古应力场持续作用下形成的。     

Geographical differences and influencing factors of rural energy consumption in Southwest mountain areas in China: A case study of Zhaotong City

China is a mountainous country,and Southwest mountain areas cover the most mountain areas in China and have the most serious problems.Taking Zhaotong city as the study area,based on 902 rural household questionnaires of 11 villages in 2 counties and Tobit model,this paper analyzes the geographical differences and influencing factors of energy consumption for non-production purposes of rural households living in different terrain conditions.This research finds that:(1) Coal takes up the main part of energy consumption in valley areas and coal consumption is mainly affected by per capita cultivated land area,household income,proportion of rural household energy expenditure in total expenditure,coal price,and family population size.Firewood takes up the main part of energy consumption in high mountain areas and firewood consumption is mainly affected by per capita firewood forest area,distance to purchase coal,household income,electricity price,and coal price.(2) Only when the distance is greater than 20 kilometers,that is the average distance of rural households living in middle mountain areas(1,600m~1,800m) to purchase coal,the transportation condition has a significant impact on coal consumption.(3) In high mountain areas,prices of coal and electricity are the main factors influencing energy consumption choice of rural households.Too high prices of coal and electricity would to some extent lead rural households to choose firewood as the main energy consumption type.Compared to coal,rural households prefer to choose electricity.     

四川省小麦条锈病春季流行的农业气候风险区划

针对当前从气象风险角度开展小麦条锈病与气象关系研究甚少的状况,从农业气象灾害风险分析理论出发,采用相关分析、层次分析和极差正规化等方法,建立了包含气候条件和寄主存在数量两个环境因子的四川省小麦条锈病春季流行农业气候风险模型,并划分了高、中、低风险等级的指标.在此基础上,利用GIS技术对四川省小麦条锈病春季流行的农业气候风险进行了区划.结果表明,四川省的川西高原地区、川西南山地和盆地西南部是小麦条锈病春季流行低风险区,盆地大部地区是中、高风险的集中区.区划结果为进一步做好四川省小麦条锈病的分区预报和综合防治方面提供科学依据.     

GPS气象预报的可行性分析

基于中国区域5个IGS跟踪站的实测GPS数据,利用Bernese 4.2软件反演了部分典型测站上空的可降水量,并分析了该降水量变化与降雨之间的关系,探讨了将GPS应用于气象预报的可行性.     

Geochemistry,petrogenesis and tectonic implication of Early Cretaceous A-type rhyolites in Hailar Basin,NE China

Early Cretaceous A-type rhyolites of the Shangkuli Formation in the Hailar Basin of NE China exhibit geochemical characteristics of high silicon, alkali, Fe/Mg, Ga/Al, Zr, Pb, HFSEs, and REE contents but low Ca, Ba, Sr and Eu, which meet the criteria of typical reduced A-type granite.The A-type rhyolites are most probably derived from magmatic underplating and partial melting of quartz-feldspathic lower crust, with the lithospheric mantle material involved, due to the extensional deformation of the Erguna-Hulun Fault.Although the A-type rhyolites show A1-type trace elements characteristics, they were formed in a post-orogenic extension-al background together with the coeval widespread bimodal volcanic rocks, metamorphic core complexes, vol-canic fault basins and metallogenic province in the Sino-Russia-Mongolia border tract.This extension event was related to the collapse of thickened region of the continental crust after the closure of the Mongol-Okhotsk Ocean.     

川西北塔公石英闪长岩地球化学特征和岩石成因

川西北塔公地区位于青藏高原东部,属于松潘—甘孜造山带的东南部边缘。塔公石英闪长岩侵位于晚三叠世地层中,岩体的K-Ar同位素年龄为134~136Ma,形成于早白垩世。岩石SiO2质量分数为61.37%~62.25%,铝饱和指数为0.93~0.95,全碱质量分数为5.46%~5.77%,里特曼指数为1.62~1.74,样品属于亚碱性准铝质高钾钙碱系列石英闪长岩。岩石Mg#值较高,总体具有高Sr含量、低Nd含量的同位素地球化学特征。N(87Sr)/N(86Sr)值为0.712 589~0.713 009,初始N(87Sr)/N(86Sr)值为0.709 503~0.709 878,N(143 Nd)/N(144 Nd)值为0.512 135~0.512 196,εNd(t)值均为负(-8.6~-7.5),Nd模式年龄为1.33~1.41Ga,Hf模式年龄为1.13~1.37Ga。该岩体是早白垩世期间,川西北地区陆缘-陆内造山环境下由松潘—甘孜造山带古老的下地壳镁铁质物质局部熔融形成的晚碰撞-碰撞后非分异Ⅰ型花岗岩类。