Photochemical characteristics of high and low ozone episodes observed in the Taehwa Forest observatory (TFO) in June 2011 near Seoul South Korea

We present a comprehensive discussion on what cause high ozone episodes at a suburban photochemical observation site of the Seoul Metropolitan Area (population ～23 million). The observational site, Taehwa Research Forest (TRF), is situated ～30 km from the center of Seoul. In June 2011, we observed two very distinctive ozone periods-high ozone (peak up to 120 ppbv) and low ozone (peak up to 60 ppbv) in the mid and early month, respectively. The trace gas measurement dataset, especially CO and NO _X clearly indicate that less anthropogenic influences during the high ozone period. Volatile organic compound (VOC) measurement results show that at the observational site, biogenic VOCs (mostly isoprene) contribute most of chemical reactivity towards OH, although toluene from anthropogenic activities was observed in higher concentrations. Back-trajectory analysis indicates that air-masses from the forest part of Korea Peninsula were dominant influences during the high ozone episode event. On the other hand, Aged air masses from China were the dominant influence during the low ozone episode event. Model calculations conducted using the University of Washington Chemical Mechanism (UWCM) box model, also consistently show that BVOC, especially isoprene photochemistry, can be the significantly contribution to local ozone formation in the given photochemical environments of TRF. These research results strongly suggest that ozone control strategy in the Eastern Asian megacities, mostly situated in surrounding forest areas should be based on the comprehensive scientific understanding in BVOC photochemistry and interplays between anthropogenic and biogenic interactions.     

Persistent high concentration of ozone during windstorm conditions in southern Korea

Summary Prior to and following the development of a windstorm in the mountainous coastal area of southern Korea, ground level ozone (O₃)-concentrations near Kangnung city, on the lee side of the mountains, show a maximum value at approximately 1300 LST, owing to a photolytic cycle of NO₂–NO–O₃ during the day and a minimum in concentrations at night as a result of the reverse cycle. During the development period of the windstorm, ozone concentrations are generally high all day, and slightly higher during the night. This distribution pattern of ozone is very different from the typical distribution of ozone in the absence of windstorms. High daytime concentrations of ozone during the windstorm are due to both the increase in the amount of ozone from photochemical reactions involving NO_x and the increase in O₃-concentration due to a decrease in the convective boundary layer thickness under the influence of downslope windstorm conditions on the lee-side of the mountains. At night, the windstorm increases in intensity as the westerly winds combine with a katabatic wind blowing downslope toward the surface at the coast. This causes momentum transport of air parcels in the upper levels toward the surface at the coast and the development of internal gravity waves, which generate a hydraulic jump directed upward over the coast and the East sea, thereby reducing to very thin the thickness of the nocturnal surface inversion layer (NSIL). The higher O₃-concentration at night depends mainly upon the shallow NSIL and on some O₃ being transported by the momentum transfer from the upper troposphere toward the ground in windstorm conditions.     

Retrieval of outgoing longwave radiation from COMS narrowband infrared imagery

Hourly outgoing longwave radiation(OLR) from the geostationary satellite Communication Oceanography Meteorological Satellite(COMS) has been retrieved since June 2010. The COMS OLR retrieval algorithms are based on regression analyses of radiative transfer simulations for spectral functions of COMS infrared channels. This study documents the accuracies of OLRs for future climate applications by making an intercomparison of four OLRs from one single-channel algorithm(OLR12.0using the 12.0 μm channel) and three multiple-channel algorithms(OLR10.8+12.0using the 10.8 and 12.0 μm channels; OLR6.7+10.8using the 6.7 and 10.8 μm channels; and OLR All using the 6.7, 10.8, and 12.0 μm channels). The COMS OLRs from these algorithms were validated with direct measurements of OLR from a broadband radiometer of the Clouds and Earth's Radiant Energy System(CERES) over the full COMS field of view [roughly(50°S–50°N, 70°–170°E)] during April 2011.Validation results show that the root-mean-square errors of COMS OLRs are 5–7 W m-2, which indicates good agreement with CERES OLR over the vast domain. OLR6.7+10.8and OLR All have much smaller errors(～ 6 W m-2) than OLR12.0and OLR10.8+12.0(～ 8 W m-2). Moreover, the small errors of OLR6.7+10.8and OLR All are systematic and can be readily reduced through additional mean bias correction and/or radiance calibration. These results indicate a noteworthy role of the6.7 μm water vapor absorption channel in improving the accuracy of the OLRs. The dependence of the accuracy of COMS OLRs on various surface, atmospheric, and observational conditions is also discussed.     

Vertical structure variability and equatorial waves during central Pacific and eastern Pacific El Ni?os in a coupled general circulation model

Recent studies report that two types of El Ni?o events have been observed. One is the cold tongue El Ni?o or Eastern Pacific El Ni?o (EP El Ni?o), which is characterized by relatively large sea surface temperature (SST) anomalies in the eastern Pacific, and the other is the warm pool El Ni?o (a.k.a. ‘Central Pacific El Ni?o’ (CP El Ni?o) or ‘El Ni?o Modoki’), in which SST anomalies are confined to the central Pacific. Here the vertical structure variability of the periods during EP and CP is investigated based on the GFDL_CM2.1 model in order to explain the difference in equatorial wave dynamics and associated negative feedback mechanisms. It is shown that the mean stratification in the vicinity of the thermocline of the central Pacific is reduced during CP El Ni?o, which favours the contribution of the gravest baroclinic mode relatively to the higher-order slower baroclinic mode. Energetic Kelvin and first-meridional Rossby wave are evidenced during the CP El Ni?o with distinctive amplitude and propagating characteristics according to their vertical structure (mostly first and second baroclinic modes). In particular, the first baroclinic mode during CP El Ni?o is associated to the ocean basin mode and participates to the recharge process during the whole El Ni?o cycle, whereas the second baroclinic mode is mostly driving the discharge process through the delayed oscillator mechanism. This may explain that the phase transition from warm to neutral/cold conditions during the CP El Ni?o is delayed and/or disrupted compared to the EP El Ni?o. Our results have implications for the interpretation of the variability during periods of high CP El Ni?o occurrence like the last decade.     

Synoptic characteristics of heavy snowfalls at Busan of Korea caused by polar lows over the East/Japan Sea

Theoretical and Applied Climatology - The results of the present study prove that snowfall occurred due to the polar low (PL) in the Korean Peninsula and six cases of snowfall exceeding a snow...     

Freeze thaw cycles in Toronto, Canada in a changing climate

Summary Freeze thaw cycles are examined in Toronto Canada. Using data from 1960 to 1989 for three Toronto area weather stations, trends in freeze thaw activity, the relationship to mean monthly temperature and projections of freeze thaw activity are examined. For downtown Toronto the annual frequency of freeze thaw cycles is decreasing significantly, most notably in the shoulder months of October and April. At the Pearson International Airport and the Toronto Island Airport similar annual trends were not found, however there was evidence of decreased freeze thaw activity in April and October. Polynomial curve fitting provided functional relationships between mean monthly temperature and freeze thaw activity. These relationships enabled the assessment of freeze thaw activity under synthetic warming conditions. The results of this analysis show that the warming of the magnitude typically projected for the rest of this century will not likely generate a significant change in the freeze thaw activity although there are indications that the freeze thaw season will contract.     

Quantitative Analysis of Micro-structural Changes in a Bituminous Coal After Exposure to Supercritical CO2 and Water

Natural Resources Research - High-volatile bituminous coal samples were reacted in deionized water with supercritical CO2 (ScCO2–water) under simulated in situ pressure and temperature...     

Comparison of radiocarbon and OSL dating methods for a Late Quaternary sediment core from Lake Ulaan,Mongolia

Both radiocarbon and optically stimulated luminescence (OSL) dating methods were applied to test their suitability for establishing a chronology of arid-zone lacustrine sediments using a 5.88-m-long core drilled from Lake Ulaan, southern Mongolia. Although the radiocarbon and OSL ages agree in some samples, the radiocarbon ages are older than the corresponding OSL ages at the 550-cm depth horizon (late Pleistocene) and in the 100–300-cm interval (early to late Holocene). In the early to late Holocene, radiocarbon ages are consistently older than OSL ages by 4,100–5,800 years, and in the late Pleistocene by 2,700–3,000 years. Grain-size analysis of early to late Holocene sediments and one late Pleistocene sediment sample (550-cm depth) indicates that eolian processes were the dominant sediment-transport mechanism. Also, two late Pleistocene sediments samples (from 400- to 500-cm depths) are interpreted to have been deposited by both eolian and glaciofluvial processes. Accordingly, the radiocarbon ages that were older than the corresponding OSL ages during the Holocene seem to have been a consequence of the influx of ¹⁴C-deficient carbon delivered from adjacent soils and Paleozoic carbonate rocks by the westerly winds, a process that is also active today. In addition to the input of old reworked carbon by eolian processes, the late Pleistocene sediments were also influenced by old carbon delivered by deglacial meltwater. The results of this study suggest that when eolian sediment transport is suspected, especially in lakes of arid environments, the OSL dating method is superior to the radiocarbon dating method, as it eliminates a common ‘old-carbon’ error problem.     

Characterization of hydrogeologic properties for a multi-layered alluvial aquifer using hydraulic and tracer tests and electrical resistivity survey

A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties. The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt, sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10⁻² cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10⁻⁴ cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10⁻³ and 2.44×10⁻² cm/s with a geometric mean of 6.89×10⁻³ cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests, and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties of the multi-layered alluvial aquifer.