A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

Holocene lake development and glacial-isostatic uplift at Lake Skallen and Lake Oyako,Lützow-Holm Bay,East Antarctica: Based on biogeochemical facies and molecular signatures

The paleolimnology of two lakes which were isolated as a result of the crustal uplift during the late Holocene along the Soya Coast, Lützow-Holm Bay, East Antarctica were studied. The focus was on temporal variations in the biogeochemical composition of sediment cores recovered from Lake Skallen at Skallen and Lake Oyako at Skarvsnes. Both sets of lake sediments record environmental changes associated with a transition from marine to lacustrine settings, as indicated by analyses of C and N contents, nitrogen isotopic compositions (δ¹⁵N), and major element concentrations. Changes in the dominant primary producers during the marine–lacustrine transition (marine diatom to cyanobacteria) at L. Skallen was clearly revealed by biogenic opal-A, diatom assemblages, and molecular signature from denaturing gradient gel electrophoresis (DGGE) with 16S ribosomal RNA (rRNA) gene analysis. Radiocarbon dating of acid-insoluble organic C suggested that the environmental transition from marine to fresh water occurred at 2940 ± 100 cal yr BP at L. Skallen and 1060 ± 90 cal yr BP at L. Oyako. Based on these data, a mean crustal uplift rate of 3.2 mm yr⁻¹ is inferred for the history of marine–lacustrine transition via brackish conditions. The geological setting causing glacio-isostatic uplift was the primary factor in controlling the transition event in sedimentary and biological facies.     

The structural behaviour of timber joints subjected to bi‐axial bending

This study investigates the structural performance of interior, exterior and corner traditional timber joints found in a traditional temple in Japan subjected to bi‐axial bending. A total of 36 half‐scale specimens were fabricated and tested under both uni‐axial and bi‐axial cyclic bending for comparison of their structural behaviour. The results show that the corner joints exhibit lower rotational stiffness than the interior and exterior joints. Further, connections subjected to only uni‐axial moments exhibit better performance with regard to moment resistance, energy dissipation and stiffness degradation as compared with those subjected to bi‐axial moments. Hence, this study suggests that if the timber joints are subjected to bi‐axial bending, this effect on timber joints should be considered during the design and evaluation process in the future. Copyright © 2009 John Wiley & Sons, Ltd.     

Structural controls on the 1998 volcanic unrest at Iwate volcano: Relationship between a shallow, electrically resistive body and the possible ascent route of magmatic fluid

Magnetotelluric (MT) measurements were conducted at Iwate volcano, across the entirety of the mountain, in 1997, 1999, 2003, 2006, and 2007. The survey line was 18 km in length and oriented E–W, comprising 38 measurements sites. Following 2D inversion, we obtained the resistivity structure to a depth of 4 km. The surface resistive layer (~ several hundreds of meters thick) is underlain by extensive highly conductive zones. Based on drilling data, the bottom of the highly conductive zone is interpreted to represent the 200 °C isotherm, below which (i.e., at higher temperatures) conductive clay minerals (smectite) are rare. The high conductivity is therefore mainly attributed to the presence of hydrothermally altered clay. The focus of this study is a resistive body beneath the Onigajo (West-Iwate) caldera at depths of 0.5–3 km. This body appears to have impeded magmatic fluid ascent during the 1998 volcanic unrest, as inferred from geodetic data. Both tectonic and low-frequency earthquakes are sparsely distributed throughout this resistive body. We interpret this resistive body as a zone of old, solidified intrusive magma with temperatures in excess of 200 °C. Given that a similar relationship between a resistive body and subsurface volcanic activity has been suggested for Asama volcano, structural controls on subsurface magmatic fluid movement may be a common phenomenon at shallow levels beneath volcanoes.     

Millennium‐scale recurrent uplift inferred from beach deposits bordering the eastern Nankai Trough,Omaezaki area,central Japan

A flight of Holocene marine terraces on the southwestern coast of Cape Omaezaki of central Japan provides evidence of recurrent millennium‐scale uplift events. We reconstructed the uplift history of these terraces by using facies analysis of drill core and geoslicer samples, environmental analysis of trace fossils, and ¹⁴C age determinations. Coastal uplift can be identified by the displacement of beach deposits such as foreshore deposits, which represent the intertidal swash zone of a wave‐dominated sandy coast. Three levels of former beach deposits facing the Nankai Trough were identified near the coast in the Omaezaki area. The highest of these, dated at about 3020–2880 BC, records a maximum of 2.2–2.7 m of emergence. The middle beach surface, of minimum age 370–190 BC, shows 1.6–2.8 m of emergence. The lowest beach surface, which is older than 1300–1370 AD, records 0.4–1.6 m of emergence. Our analysis of vertical crustal deformation data during the Holocene in this region suggests that rapid and strong uplift was restricted to the southwestern coast of the Omaezaki area and was probably caused by high‐angle thrusting on subsidiary faults branching from the underlying plate boundary megathrust.     

A Biogeochemical View of Estuarine Eutrophication: Seasonal and Spatial Trends and Correlations in the Delaware Estuary

The Delaware River and Bay Estuary is one of the major urbanized estuaries of the world. The 100-km long tidal river portion of the estuary suffered from major summer hypoxia in the past due to municipal and industrial inputs in the urban region; the estuary has seen remarkable water quality improvements from recent municipal sewage treatment upgrades. However, the estuary still has extremely high nutrient loading, which appears to not have much adverse impact. Since the biogeochemistry of the estuary has been relatively similar for the past two decades, our multiple year research database is used in this review paper to address broad spatial and seasonal patterns of conditions in the tidal river and 120 km long saline bay. Dissolved oxygen concentrations show impact from allochthonous urban inputs and meteorological forcing as well as biological influences. Nutrient concentrations, although high, do not stimulate excessive algal biomass due to light and multiple nutrient element limitations. Since the bay does not have strong persistent summer stratification, there is little potential for bottom water hypoxia. Elevated chlorophyll concentrations do not exert much influence on light attenuation since resuspended bottom inorganic sediments dominate the turbidity. Dissolved inorganic carbon and dissolved and particulate organic carbon distributions show significant variability from watershed inputs and lesser impact from urban inputs and biological processes. Ratios of dissolved and particulate carbon, nitrogen, and phosphorus help to understand watershed and urban inputs as well as autochthonous biological influences. Owing to the relatively simple geometry of the system and localized anthropogenic inputs as well as a broad spatial and seasonal database, it is possible to develop these biogeochemical trends and correlations for the Delaware Estuary. We suggest that this biogeochemical perspective allows a revised evaluation of estuarine eutrophication that should have generic value for understanding other estuarine and coastal waters.     

Rheological properties and structural changes in different sections of boiled abalone meat

1　Introduction　AbaloneHaliotisdiscusisaverypopularfoodthrough outtheworld .WhenAsianpeoples ,notablyJapaneseandChinese ,eatabalonedishes ,theyenjoythefirmtextureoftherawmeatandthetendernessoftheboiledmeat .InJapan ,thetoughervarietiesoftherawabalonemeatareenjoyedandtheabaloneisoftenthin lyslicedandservedraw (sashimi) ,whileinchina ,thetendernessandsoftervarietiesoflesscollagenofboiledmeatareconsideredsuitableforeating ,sotheabaloneisoftenservedbyheating .Infoodscience ,manyreportshavebeen …     

Strong Updraft at a Sea-Breeze Front and Associated Vertical Transport of Near-Surface Dense Aerosol Observed by Doppler Lidar and Ceilometer

To study the wind field within the atmospheric boundary layer over the Tokyo metropolitan area, Doppler lidar observations were made 45 km north of Sagami Bay and 30 km west of Tokyo Bay, from 14 May to 15 June 2008. Doppler lidar on 27 May 2008 observed the vertical and horizontal wind structure of a well-developed sea-breeze front (SBF) penetrating from Sagami Bay. At the SBF, a strong updraft (maximum w approximately equal to 5 m s⁻¹) was formed with a horizontal scale of about 500 m and vertical scale of 2 km. The spatial relationship between the strong updraft over the nose of the SBF and prefrontal thermal suggests that the strong updraft was triggered by interaction between the SBF and the thermal. After the updraft commenced, a collocated ceilometer observed an intense aerosol backscatter up to 2 km above ground level. The observational results suggest that the near-surface denser aerosols trapped in the head region of the SBF escaped from the nose of the SBF and were then vertically transported up to the mixing height by the strong updraft at the SBF. This implies that these phenomena occurred not continuously but intermittently. The interaction situations between the SBF and prefrontal thermal can affect the wind structure at the SBF and the regional air quality.     

A flare model deduced from Hinotori and millimeterwave interferometer observations

The -ray and white-light flare of 13 May, 1981 is used for a study of spatial distributions of energetic electrons and high-temperature plasma.