Fluid flow, methane fluxes, carbonate precipitation and biogeochemical turnover in gas hydrate-bearing sediments at Hydrate Ridge, Cascadia Margin: numerical modeling and mass balances

A numerical model was applied to investigate and to quantify biogeochemical processes and methane turnover in gas hydrate-bearing surface sediments from a cold vent site situated at Hydrate Ridge, an accretionary structure located in the Cascadia Margin subduction zone. Steady state simulations were carried out to obtain a comprehensive overview on the activity in these sediments which are covered with bacterial mats and are affected by strong fluid flow from below. The model results underline the dominance of advective fluid flow that forces a large inflow of methane from below (869 μmol cm⁻² a⁻¹) inducing high oxidation rates in the surface layers. Anaerobic methane oxidation is the major process, proceeding at a depth-integrated rate of 870 μmol cm⁻² a⁻¹. A significant fraction (14%) of bicarbonate produced by anaerobic methane oxidation is removed from the fluids by precipitation of authigenic aragonite and calcite. The total rate of carbonate precipitation (120 μmol cm⁻² a⁻¹) allows for the build-up of a massive carbonate layer with a thickness of 1 m over a period of 20,000 years. Aragonite is the major carbonate mineral formed by anaerobic methane oxidation if the flow velocity of methane-charge fluids is high enough (≥10 cm a⁻¹) to maintain super-saturation with respect to this highly soluble carbonate phase. It precipitates much faster within the studied surface sediments than previously observed in abiotic laboratory experiments, suggesting microbial catalysis. The investigated station is characterized by high carbon and oxygen turnover rates (≈1000 μmol cm⁻² a⁻¹) that are well beyond the rates observed at other continental slope sites not affected by fluid venting. This underlines the strong impact of fluid venting on the benthic system, even though the flow velocity of 10 cm a⁻¹ derived by the model is relative low compared to fluid flow rates found at other cold vent sites. Non-steady state simulations using measured fluid flow velocities as forcing demonstrate a rapid respond of the sediments within a few days to changes in advective flow. Moreover, they reveal that efficient methane oxidation in these sediments prevents methane outflow into the bottom water over a wide range of fluid flow velocities (<80 cm a⁻¹). Only at flow rates exceeding approximately 100 cm a⁻¹, does dissolved methane break through the sediment surface to induce large fluxes of up to 5000 μmol CH₄ cm² a⁻¹ into the overlying bottom water.     

Auswirkungen des Extremhochwassers 1999 auf die Flächendynamik und Bestandsstruktur der Uferröhrichte des Bodensees

In consequence of the extreme flood at Lake Constance in 1999 the reed belts showed a severe loss in vitality so that a permanent damage could be expected. The monitoring project presented here focuses the documentation of the damage following the disturbance event, the identification of co-factors, and is designed to find out significant stressors that may impede the recovery of the reeds. The monitoring is based on CIR aerial photo interpretation, quantitative GIS-analyses and field data. The design of the study implies the definition of five degrees of damage using the interpretation of CIR aerial photo series from July 2000. The aquatic reed beds were digitised and areal sums were calculated. These data were compared with the corresponding data from 1999 and 1993. Stand structural and biomass attributes were investigated in 50 randomly distributed permanent plots covering all site types and damage degrees. The results showed a loss of about 24 hectares of aquatic reeds at Lake Constance Untersee alone. The stands which had survived showed a great patchiness in terms of culm density, shoot population composition, culm architecture, and aboveground biomass production. Severely damaged stands were mainly composed of secondary shoots, whereas primary and insect infested shoots dominated in less damaged stands. One co-factor which explained the patchiness was the vertical position of the stand, i.e. the probability of being severely damaged increased with increasing distance below mean water level. The monitoring programme will be continued till 2003.     

Dissolution kinetics of biogenic silica from the water column to the sediments

Stirred flow-through experiments were conducted for the first time with planktonic biogenic silica (BSi). We investigated the dissolution kinetics of uncleaned and chemically cleaned BSi collected in ocean surface water, sediment traps, and sediments from the Norwegian Sea, the Southern Ocean, and the Arabian Sea. The solubility at 2°C is rather constant (1000 to 1200 μM). The dissolution rates are, however, highly variable, declining with water depth, and phytoplankton reactivity is two to three orders of magnitude higher than pure siliceous oozes. The reactivity decrease correlates well with an increase in the integrated peak intensity ratios of Si-O-Si/Si-OH measured by Fourier transform infrared (FTIR) spectroscopy. The removal of organic or inorganic coatings enhance the reactivity by at least an order of magnitude. Atomic Al/Si ratios of 0.03 to 0.08 in sedimentary diatom frustules decrease significantly to 0.02 as a result of removal of inorganic coatings and detritals present. Near equilibrium, the dissolution rates exhibit a linear dependence on the degree of undersaturation. At higher degrees of undersaturation—that is, at low concentrations of dissolved silica—the dissolution rates of uncleaned samples define a nonlinear trend.The nonlinear kinetics imply that the dissolution of natural BSi is strongly accelerated in silica-depleted surface waters. The FTIR results suggest that internal condensation reactions reduce the amount of surface reaction sites and are partly responsible for the reactivity decrease with depth. The high content of Al in sedimentary BSi is likely caused by precipitation of dissolved silica with Al dissolved from minerals in sediment. Nonbiogenic silica as coatings or detritals are partly responsible for the solubility and reactivity decrease of BSi in sediments. One order of magnitude different rate constants measured in Norwegian Sea and Southern Ocean sediment trap material support the so-called opal paradox—that is, high BSi accumulation rates in sediments in spite of low BSi production rates in surface waters of the Southern Ocean.     

Design and analysis of the Sydney deepwater ocean outfall environmental monitoring programme: a critique

The Sydney Environmental Monitoring Programme (EMP) measured the environmental performance of Sydney's new deepwater sewage outfalls against a wide range of criteria related to impacts on marine ecosystems and on human use of marine resources. It consisted of a number of interacting studies conducted during the period 1989 to 1993. Given that all the studies have now been finalized and the data analysed and presented (see papers in this volume), it is appropriate to review the program as a whole and identify, with the benefit of hindsight, where things could have been done better. This paper focuses mainly on the experimental design and statistical treatment of the studies conducted, although management problems are also briefly addressed. Overall it is concluded that the studies making up the EMP contributed greatly to enhancing our understanding of the marine environment of the coastal shelf off Sydney, an area which had previously received only limited attention. Most of the studies, however, suffered from deficiencies in experimental design, which was difficult to overcome when analysing the data. It will be important, in designing future integrated monitoring studies, to draw on the experience of programs such as this to avoid some of the pitfalls which appear to be inherent in these types of large programs.     

Silurian-Devonian and Jurassic Thermal Events in the Ordos Basin, China: Indications from K-Ar Dating on Illites

In the Ordos basin, two distinct thermal events of different ages have been identified for the first time by means of K-Ar dating combined with illite crystallinity analysis. For the Late Triassic and Late Permian samples, the K-Ar ages of the < 0.2μm fractions (159-173 Ma) reflect an illitization age related to the Yanshanian movement and indicate a short thermal event in the Middle Jurassic; the K-Ar ages of the <2 μm fractions (210-308 Ma) are interpreted as mixed ages of detrital material and authigenic illites. The K-Ar ages of both < 0.2μm and < 2μm fractions of a Middle Cambrian sample (368 Ma and 419 Ma) correspond to the ages of the metamorphism and earliest granite intrusion in the northern Caledonian Qinling fold zone (380-420 Ma) and show a thermal event during Silurian-Devonian time.     

Plastic velocity vector diagrams applied to indentation and transpression in the Alps

Alpine collision tectonics has affected the European Alps for more than 110 Ma and is probably still active today. The cumulative large-scale convergence in the Alps adds up to 1100 km. About 500 km of this convergence can be budgeted by escape tectonics, 300 km by continental and oceanic subduction, and an equal amount by crustal thickening. Considerable uncertainty still exists as to the kinematics of the collision; a transpressive indentation of a more or less rigid “Italy/Adria” block into a deformable European plate appears likely. In recent surveys of horizontal mass transfer in the Alps, as inferred from structural analyses, a dominant westwards directed flow regime has been recognized. Theoretical indentation models have been applied to explain the palaeo-flow field. The flow can be explained by: Case I normal indentation without transpression but a space restriction to the east. A palinspastic space restriction did not exist, on the contrary, remnant oceanic terrain survived longest in the east; Case II dextral transpression with no significant indentation. This would require an age progression of westward flow from the east (oldest) to the west (youngest) which is not observed; and Case III transpressive indentation with a sinistral shear component. This seems to be the most satisfactory solution as it explains large-scale sinistral lineaments, and leaves palinspastic space for the rapid rotation of Corsica and Sardinia.