PETROLOGY AND CLASSIFICATION OF THE GARRAF,SPAIN CHONDRITE

Microscopic and electron microprobe studies indicate that the Garraf meteorite is a highly-recrystallized chondrite of petrologic type 6. Olivine (Fa24.7; PMD 1.1) and low-Ca pyroxene (Fs20.9; PMD 1.1) compositions indicate that it belongs to the L-group. Based on contents of noble gases, pervasive fracturing of silicates, common undulose extinction of olivine and plagioclase, and the lack of melt pockets and maskelynite, we place Garraf into shock facies b. We conclude that Garraf is a highly recrystallized L6b chondrite that, after recrystallization, was cataclased and comminuted by shock.     

Flow exchange between the deep and shallow groundwaters in the Sbeϊtla synclinal basin (Tunisia): an isotopic approach

Stable (¹⁸O, ² H) and radiogenic (³H, ¹⁴C) isotopes of water have been used to constrain the source, origin, age, migration pathway and mixing processes in the Sbeïtla (Tunisia) system. The system is composed of an upper unconfined Middle Miocene aquifer with a variable thickness from 10–300 m, an intermediate confined/unconfined Lower Miocene aquifer about 100 m thick and a deeper confined Lower Cretaceous aquifer about 150 m thick separated by a thin clay layer. A total of 53 groundwater samples from the three aquifers and spring samples were collected during February and March 2000 and isotopically analysed using conventional methods. The stable isotopes composition of waters establishes that the deep groundwater (depleted as compared to present corresponding local rainfall) is ancient water recharged probably during the late Pleistocene and the early Holocene periods. The relatively recent water in the superficial aquifer is composed of mixed waters resulting presumably from upward leakage from the deeper groundwater. The radiogenic (³H, ¹⁴C) isotopes data confirm that the recent water, with a tritium content between 6.5 and 19 TU, represents post-nuclear recharge and the ancient groundwater with low carbon-14 contents between 7 and 26 pmC infiltrated between 8,000 to 20,000 years ago. When used in conjunction with the stable isotopes data, the mixing process can be clearly identified, especially in the Sbeïtla sill area. Groundwater of the upper aquifer exhibits isotopic signatures of both the old and recent waters. By using isotopic mass balance, the computed contribution of the deep groundwater in recharging the upper aquifer is up to 94%.     

MINERALOGY AND CHEMISTRY OF THE KYLE,TEXAS, CHONDRITE

The Kyle, Texas, U.S.A., chondrite was identified in 1965. Electron microprobe analyses and microscopic examination show the following mineralogy: olivine (Fa 26.2 mole %), orthopyroxene (Fs 21.0 mole %), clinopyroxene, plagioclase (An 10.3 mole %), chlorapatite, whitlockite, kamacite, taenite, troilite, chromite, and an iron-bearing terrestrial weathering product. Eutectic intergrowths of metaltroilite and a brecciated matrix indicate that the Kyle chondrite was shocked. Recrystallization and shock have obliterated chondrule-matrix boundaries. A chemical analysis of the meteorite shows the following results (in weight %): Fe 0.38, Ni 1.22, Co 0.05, FeS 5.98, SiO₂ 38.41, TiO₂ 0.11, Al₂O₃ 2.13, Cr₂O₃ 0.55, Fe₂O₃ 8.02, FeO 14.83, MnO 0.31, MgO 23.10, CaO 1.60, Na₂O 0.74, K₂O 0.08, P₂O₅ 0.19, H₂O⁺ 1.73, H₂O^? 0.37, C 0.03, Sum 99.83. On the basis of bulk chemistry, composition of olivine and orthopyroxene, and the recrystallized matrix, the Kyle meteorite is classified as an L6 chondrite.     

THE LANDES METEORITE

The Landes silicate-bearing octahedrite is a new find from Grant County, West Virginia. Minerals and their compositions are very similar to those in Odessa-type silicate inclusions. The angular nature of the inclusions, recrystallization textures, and mineral compositions indicate a “xenolithic” origin for the inclusions.     

Prototype development of GEOEXPLORER, a knowledge-based system for supergene deposits: Identification of favorable areas for bauxite

GEOEXPLORER is a knowledge-based system under development to support the prospecting and exploration of supergene deposits. As a new type of multi-stage expert systetn, GEOEXPLORER is not only able to deal with problems of searching for supergene deposits, but will also cover both the evaluation of the spatial occurrences and the economic values of the deposits considered. A first prototype of GEOEXPLORER has been developed for bauxite deposits. It is a rule-based system implemented in PROLOG and can be used to identify favorable areas for bauxite prospecting. This paper discusses this prototype of GEOEXPLORER.     

Genesis of the IIICD iron meteorites: Evidence from silicate-bearing inclusions

Abstract— Our studies of the silicate-bearing inclusions in the IIICD iron meteorites Maltahöhe, Carlton and Dayton suggest that their mineralogy and mineral compositions are related to the composition of the metal in the host meteorites. An inclusion in the low-Ni Maltahöhe is similar in mineralogy to those in IAB irons, which contain olivine, pyroxene, plagioclase, graphite and troilite. With increasing Ni concentration of the metal, silicate inclusions become poorer in graphite, richer in phosphates, and the phosphate and silicate assemblages become more complex. Dayton contains pyroxene, plagioclase, SiO₂, brianite, panethite and whitlockite, without graphite. In addition, mafic silicates become more FeO-rich with increasing Ni concentration of the hosts. In contrast, silicates in IAB irons show no such correlation with host Ni concentration, nor do they have the complex mineral assemblages of Dayton. These trends in inclusion composition and mineralogy in IIICD iron meteorites have been established by reactions between the S-rich metallic magma and the silicates, but the physical setting is uncertain. Of the two processes invoked by other authors to account for groups IAB and IIICD, fractional crystallization of S-rich cores and impact generation of melt pools, we prefer core crystallization. However, the absence of relationships between silicate inclusion mineralogy and metal compositions among IAB irons analogous to those that we have discovered in IIICD irons suggests that the IAB and IIICD cores/metallic magmas evolved in rather different ways. We suggest that the solidification of the IIICD core may have been very complex, involving fractional crystallization, nucleation effects and, possibly, liquid immiscibility.     

Asteroid Differentiation: Pyroclastic Volcanism to Magma Oceans

Abstract— Asteroid differentiation was driven by a complex array of magmatic processes. This paper summarizes theoretical and somewhat speculative research on the physics of these processes. Partial melts in asteroids migrate rapidly, taking < 10⁶ years to reach surface regions. On relatively small (<100 km) asteroids with sufficient volatiles in partial melts (<3000 ppm), explosive volcanism accelerated melts to greater than escape velocity, explaining the apparent lack of basaltic components on the parent asteroids of some differentiated meteorites. Partial melting products include the melts (some eucrites, angrites), residues (lodranites, ureilites), and unfractionated residues (acapulcoites). The high liquidus temperatures of magmatic iron meteorites, the existence of pallasites with only olivine, and the fact that enstatite achondrites formed from ultramafic magmas argue for the existence of magma oceans on some asteroids. Asteroidal magma oceans would have been turbulently convective. This would have prevented crystals nucleated at the upper cooling surface (the only place for crystal nucleation in a low-pressure body) from settling until the magma became choked with crystals. After turbulent convection slowed, crystals and magma would have segregated, leaving a body stratified from center to surface as follows: a metallic core, a small pallasite zone, a dunite region, a feldspathic pyroxenite, and basaltic intrusions and lava flows (if the basaltic components had not been lost by explosive volcanism). The pallasite and dunite zones probably formed from coarse (0.5–1 cm) residual olivine left after formation of the magma ocean at >50% partial melting of the silicate assemblage. Iron cores crystallized dendritically from the outside to the inside. The rapid melt migration rate of silicate melts suggests that ²⁶Al could not be responsible for forming asteroidal magma oceans because it would leave the interior before a sufficient amount of melting occurred. Other heat sources are more likely candidates. Our analysis suggests that if Earth-forming planetesimals had differentiated they were either small (<100 km) and poor in volatiles (<1000 ppm) or they were rich in volatiles and large enough (>300 km) to retain the products of pyroclastic eruptions; if these conditions were not met, Earth would not have a basaltic component.     

Distribution of dissolved molybdenum,uranium and vanadium in baltic sea waters

This study presents dissolved molybdenum, uranium and vanadium profiles from eight stations in the main Baltic subregions. The elements were analysed by a new analytical procedure based on total-reflection X-ray fluorescence (TXRF). Mo and U reveal a strong, positive correlation with salinity (with r = 0.95 and 0.93, respectively). The estimated end-member concentrations (for S = 35 × 10^?3) are consistent with North Atlantic Ocean water values, indicating conservative mixing with Baltic river waters as the dominating process. In contrast, dissolved V shows relatively low levels, with mean surface and deep layer values of 2.7 and 1.7 nmol kg^?1, respectively. Compared with recently investigated Atlantic Ocean waters (normalized to S = 35 × 10^?3), Baltic waters are deplated in dissolved V by more than 60%. The removal is attributed to scavenging processes by terrigenous and/or biogenic material during the course of mixing. However, the data did not indicate that precipitation or other removal processes were significant in the anaerobic waters.     

Database of Comet Polarimetry: Analysis and Some Results

We present the electronic database (EAR-C-COMPIL-5-DB-COMET-POLARIMETRY-V1.0, NASA Planetary Data System) involving published and some unpublished results of cometary polarimetry. The database contains more than 2600 measurements of linear and circular polarization for 64 comets since 1940s. The narrow-band and wide-band measurements within the spectral region 0.3–2.2 micron are presented. The ranges of phase angles, helio- and geocentric distances of comets are 0.4–122°, 0.6–4.8 AU, 0.03–4.9 AU, respectively. We have comprised more than 60 references to the published papers and unpublished sources. The data we included are presented in a tabular format in the ASCII codes. The database can be used as the observational basis for detailed theoretical modeling, interpretation of the phase-angle and spectral dependence of polarization, classification of comets, laboratory simulating, and for selecting future space-mission targets. Analysis of the available data allowed us to summarize some observed characteristics of linearly and circularly polarized light and their phase-angle, heliocentric, spectral, and spatial dependencies.     

Classification of five new ordinary chondrites (RC 073, 074, 076–078) from Roosevelt County,New Mexico

Abstract— Five new ordinary chondrites from Roosevelt County, New Mexico, USA, have been assigned to a chemical group, petrologic type and shock stage. All five are moderately to heavily weathered. They are: RC 073, H5(S2); RC 074, L5(S3); RC 076, L4(S3); RC 077 , L4(S2); RC 078, L4(S2).