Paleoindication of acidification in Kleiner Arbersee (Federal Republic of Germany,Bavarian Forest) by chydorids,chrysophytes, and diatoms

In a sediment core of Lake Kleiner Arbersee, located in the Bavarian Forest on gneiss bedrock and with spodosolic soils in the catchment, acidification was reconstructed using assemblages of chydorids, scaled chrysophytes, and diatoms as paleoindicators. All paleoindicators demonstrated acidification of Kleiner Arbersee. There were marked differences, however, in the extent of the indicated acidification: In lower layers, where scaled chrysophytes and chydorids clearly indicate beginning acidification, pH-decline inferred by diatoms lies within the standard deviation, and is statistically not significant until the 7 cm layer. We conclude that mallomonadaceans reflect the acidification of the water body and strongly respond to the lowest seasonal pH, as their indicated rate of acidification is higher than that of diatoms, which appear to more closely indicate the pH of the sediment/water interface, especially when the pH of the water column has dropped below ca. 5.5. Chydorids may additionally be influenced by proton release of dense Sphagnum-stands, which cover the littoral of Kleiner Arbersee completely.We dedicate this paper to Prof. Dipl.-Ing. L. Strobel, who encouraged new perspectives in limnological water management, on the occasion of his 65^th anniversary.     

Flow directions of stream-groundwater exchange in a headwater catchment during the hydrologic year

Understanding near-stream groundwater dynamics and flow directions is important for predicting hillslope-stream connectivity, streamflow generation, and hydrologic controls of streamwater quality. To determine the drivers of groundwater flow in the stream corridor (i.e., the stream channel and the adjacent groundwater in footslopes and riparian areas), we observed the water levels of 36 wells and 7 piezometers along a headwater stream section over a period of 18 months. Groundwater dynamics during events were controlled by the initial position of the groundwater table relative to the subsurface structure. The near-stream groundwater table displayed a fast and pronounced response to precipitation events when lying in fractured bedrock with low storage capacity, and responded less frequently and in a less pronounced way when lying in upper layers with high storage capacity. Precipitation depth, intensity, regolith thickness above the fractured bedrock, and proximity to and elevation above the stream channel also had an effect on the groundwater dynamics, which varied with hydrologic conditions. Our high-frequency and spatially dense measurements highlight the competing influence of groundwater inflow from upslope locations, streamwater level and bedrock properties on the spatiotemporal dynamics of flowpaths in the stream corridor. Near-stream groundwater pointed uniformly towards the stream channel when the stream corridor was hydrologically connected to upslope groundwater. However, local interruptions of the water inflow from upslope locations caused flow reversals towards the footslopes. The direction of near-stream groundwater followed the local fractured bedrock topography during dry hydrologic conditions on a few occasions after events. The outcomes of this research contribute to a better understanding of the drivers controlling spatiotemporal changes in near-stream groundwater dynamics and flow directions in multiple wetness states of the stream corridor.     

Testing the ‘two water worlds’ hypothesis under variable preferential flow conditions

Widespread observations of ecohydrological separation are interpreted by suggesting that water flowing through highly conductive soil pores resists mixing with matrix storage over periods of days to months (i.e., two ‘water worlds’ exist). These interpretations imply that heterogeneous flow can produce ecohydrological separation in soils, yet little mechanistic evidence exists to explain this phenomenon. We quantified the separation between mobile water moving through preferential flow paths versus less mobile water remaining in the soil matrix after free-drainage to identify the amount of preferential flow necessary to maintain a two water world's scenario. Soil columns of varying macropore structure were subjected to simulated rainfall of increasing rainfall intensity (26 mm h⁻¹, 60 mm h⁻¹, and 110 mm h⁻¹) whose stable isotope signatures oscillated around known baseline values. Prior to rainfall, soil matrix water δ²H nearly matched the known value used to initially wet the pore space whereas soil δ¹⁸O deviated from this value by up to 3.4‰, suggesting that soils may strongly fractionate ¹⁸O. All treatments had up to 100% mixing between rain and matrix water under the lowest (26 mm h⁻¹) and medium (60 mm h⁻¹) rainfall intensities. The highest rainfall intensity (110 mm h⁻¹), however, reduced mixing of rain and matrix water for all treatments and produced significantly different preferential flow estimates between columns with intact soil structure compared to columns with reduced soil structure. Further, artificially limiting exchange between preferential flow paths and matrix water reduced bypass flow under the most intense rainfall. We show that (1) precipitation offset metrics such as lc-excess and d-excess may yield questionable interpretations when used to identify ecohydrological separation, (2) distinct domain separation may require extreme rainfall intensities and (3) domain exchange is an important component of macropore flow.     

Chaotic three-dimensional distribution of Ba,Rb, and Sr in feldspar megacrysts grown in an open magmatic system

As has been demonstrated in recent years, the heterogeneities of coeval magmas can be more successfully revealed by zoned megacrysts rather than by analysis of the whole rocks hosting them. Here, the geochemical heterogeneities of feldspar megacrysts from the Karkonosze granite, Poland, are investigated by LA-ICP-MS. The crystals are the product of migration and growth in regions of poorly mixed magmas. 3D-modeling of the Ba, Sr, and Rb distributions emphasizes the importance of micro-domain growth morphologies. Two models of element behavior—a relative concentration model and a composition gradient model—provide a potentially effective tool for tracking the mixing process on a microscale. Measured concentrations of elements of different mobilities do not agree with what might be expected from the mixing of two end-member magmas. If mixing was the only process occurring, linear correlations between the concentrations of any two elements should be observed; this, however, is not the case. For combinations of any two of the three elements, modeling reveals differing non-linear correlations between concentrations. The megacryst heterogeneities provide an insight into how mixing magmas are chaotically advected to growing crystals and the degree of inter-magma element exchange between the magmas.     

Long-term spatio-temporal social vulnerability variation considering health-related climate change parameters particularly affecting elderly

For assessing the social dimension of vulnerability, population exposure mapping is usually considered the essential starting point. Integration of social structure then further differentiates situation-specific vulnerability patterns on a local scale. Census data available in heterogeneous spatial reference units are still considered the standard information input for assessing potentially affected people, for example, in case of an emergency. There is a strong demand for population data in homogeneous spatial units that are independent from administrative areas. Raster representations meet this demand but are not yet available for all European countries. In this paper, we present an approach of spatial disaggregation of population data for a European transect referring to current population statistics and anticipated future prospects. Recently published data providing the degree of soil sealing are applied as basic proxy for population density in the spatial disaggregation model. In order to assess future patterns of climate change-related vulnerability, results of a European regional climate model are considered for projecting the situation in the 2030s. “Heat wave frequency” is accounted for as climate variable featuring conditions regarded as especially strenuous for elderly or physically weak persons. Integrated analysis of the population and climate prospects enables identification of hot spots in the European transect examined, that is, regions of particularly demanding projected climatic patterns as well as high population density and case-specific vulnerable structure (elderly people). Integrated and consistent spatial analyses on European scale are essential for decision support in the context of climate change impact mitigation as well as for risk communication and future safety and security considerations.     

Carboniferous–Permian volcanic evolution in Central Europe—U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic)

Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300–290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.     

COSMO-CLM (CCLM) climate simulations over CORDEX-Africa domain: analysis of the ERA-Interim driven simulations at 0.44° and 0.22° resolution

We present the results of the application of the COSMO-CLM Regional Climate Model (CCLM) over the CORDEX-Africa domain. Two simulations were performed driven by the ERA-Interim reanalysis (1989–2008): the first one with the standard CORDEX spatial resolution (0.44°), and the second one with an unprecedented high resolution (0.22°). Low-level circulation and its vertical structure, the geographical and temporal evolution of temperature and precipitation are critically evaluated, together with the radiation budget and surface energy fluxes. CCLM is generally able to reproduce the overall features of the African climate, although some deficiencies are evident. Flow circulation is generally well simulated, but an excessive pressure gradient is present between the Gulf of Guinea and the Sahara, related to a marked warm bias over the Sahara and a cold bias over southern Sahel. CCLM underestimates the rainfall peak in the regions affected by the passage of the monsoon. This dry bias may be a consequence of two factors, the misplacement of the monsoon centre and the underestimation of its intensity. The former is related to the northern shift of the West African Heat Low. On the other hand, the underestimation of precipitation intensity may be related to the underestimation of the surface short-wave radiation and latent heat flux. The increase of the model resolution does not bring evident improvements to the results for monthly means statistics. As a result, it appears that 0.44° is a suitable compromise between model performances and computational constrains.     

Mobilisation and transport of dissolved organic carbon and iron in peat catchments—Insights from the Lehstenbach stream in Germany using generalised additive models

During the last decades, increasing exports of both dissolved organic carbon (DOC) and iron were observed from peat catchments in North America and Europe with potential consequences for water quality of streamwater and carbon storages of soils. As mobilisation and transport processes of DOC and iron in peat catchments are only partly understood, the purpose of this study was to elucidate these processes in an intensively monitored and studied system. Specifically, it was hypothesised that dissimilatory iron reduction in riparian peatland soils mobilises DOC initially adsorbed to iron minerals. During stormflow conditions, both DOC and iron will be transported into the stream network. Ferrous iron may be reoxidised at redox interfaces on its way to the stream, and subsequently, ferric iron could be transported together with DOC as complexes. To test these hypotheses, generalised additive models (GAMs) were applied to 14 years of weekly time series of discharge and concentrations of selected solutes measured in a German headwater stream called Lehstenbach. This stream drains a 4.19‐km² forested mountain catchment; one third of which is covered by riparian peatland soils. We interpreted results of different types of GAM in the way that (a) iron reduction drove the mobilisation of DOC from peatland soils and that (b) both iron and DOC were transported as complexes after their joint mobilisation to and within the steam. It was speculated that low nitrate availability in the uppermost wetland soil layer, particularly during the growing season, promoted iron reduction and thus the mobilisation of DOC. However, the influence of nitrate on the DOC mobilisation remains relatively uncertain. This influence could be further investigated using methods similar to the GAM analysis conducted here for other catchments with long‐term data as well as detailed measurements of the relevant species in riparian wetland soils and the adjacent stream network.