Dolomite Versus Calcite Weathering in Hydrogeochemically Diverse Watersheds Established on Bedded Carbonates (Sava and So?a Rivers, Slovenia)

The relative contributions of dolomite to calcite weathering related to riverine fluxes are investigated on a highly resolved spatial scale in the diverse watersheds of Slovenia, which previous work has shown have some of the highest carbonate-weathering intensities in the world and suggests that dolomite weathering is favored over limestone weathering in mixed carbonate watersheds. The forested Sava and So?a River watersheds of Slovenia with their headwaters in the Julian Alps drain alpine regions with thin soils (<30 cm) and dinaric karst regions with thicker soils (0 to greater than 70 cm) all developed over bedded Mesozoic carbonates (limestone and dolomite), and siliclastic sediments is the ideal location for examining temperate zone carbonate weathering. This study extends previous work, presenting geochemical data on source springs and documenting downstream geochemical fluctuations within tributaries of the Sava and So?a Rivers. More refined sampling strategies of springs and discrete drainages permit directly linking the stream Mg²⁺/Ca²⁺ ratios to the local bedrock lithology and the HCO₃ ^? concentrations to the relative soil depths of the tributary drainages. Due to differences in carbonate source lithologies of springs and tributary streams, calcite and dolomite weathering end members can be identified. The Mg²⁺/Ca²⁺ ratio of the main channel of the Sava River indicates that the HCO₃ ^? concentration can be attributed to nearly equal proportions by mass of dolomite relative to calcite mineral weathering (e.g., Mg²⁺/Ca²⁺ mole ratio of 0.33). The HCO₃ ^? concentration and pCO₂ values increase as soil thickness and alluvium increase for discrete spring samples, which are near equilibrium with respect to calcite. Typically, this results in approximately 1.5 meq/l increase in HCO₃ ^? from the alpine to the dinaric karst regions. Streams in general do not change in HCO₃ ^?, Mg²⁺/Ca²⁺, or Mg²⁺/HCO₃ ^? concentrations down course, but warming and degassing of CO₂ produce high degrees of supersaturation with respect to calcite. Carbonate-weathering intensity (mmol/km²-s) is highest within the alpine regions where stream discharge values range widely to extreme values during spring snowmelt. Overall, the elemental fluxes of HCO₃ ^?, Ca²⁺, and Mg²⁺ from the tributary watersheds are proportional to the total water flux because carbonates dissolve rapidly to near equilibrium. Importantly, dolomite weathers preferentially over calcite except for pure limestone catchments.     

Organic biomarkers to describe the major carbon inputs and cycling of organic matter in the central Great Barrier Reef region

Controversy surrounds the sources and transport of land derived pollutants in the Great Barrier Reef ecosystem because there is insufficient knowledge of the mechanism of movement of organic contaminants and the cycling of organic matter in this dynamic system. Thus a sediment and sediment trap study was used to describe the composition of resuspended and surface sediments in the south central Great Barrier Reef and its lagoon. This region is characterised by strong tides (6–8 m at Mackay) and trade winds regularly about 15–20 knots. A series of organic biomarkers detailed the cyclical processes of sediment resuspension, recolonising with marine algae and bacteria, packaging into zooplankton faecal pellets and resettlement to sediments where the organics undergo further diagenesis. With each cycle the inshore sediments are diluted with CaCO₃ reef sediments and moved further offshore with the strong ebb tide currents. This results in transport of land derived materials offshore and little storage of organic materials in the lagoon or reef sediments. These processes were detailed by inorganic measurements such as %CaCO₃ and Al/Ca ratios, and by the compositions of hydrocarbon, sterol, alcohol, and fatty acid lipid fractions. Persistent contaminants such as coal dust from a coastal loading facility can be detected in high concentration inshore and decreasing out to the shelf break at 180 m approximately 40 nautical miles offshore. The normal processes would likely be amplified during cyclonic and other storms. The lipids show the sources of carbon to include diatoms and other phytoplankton, creanaerchaeota, sulfate reducing and other bacteria, land plants including mangrove leaves, plus coal dust and other petroleum contaminants.     

Origin and characteristics of the Mars north polar basal unit and implications for polar geologic history

Building upon previous studies, we have used Mars Orbiter Camera and Mars Orbiter Laser Altimeter data to characterize in detail the newly discovered north polar basal unit. Lying stratigraphically between the polar layered deposits, from which it is likely separated by an unconformity, and the Vastitas Borealis Formation, this unit has introduced new complexity into north polar stratigraphy and has important implications for polar history. Exposures of the basal unit in Olympia Planitia and Chasma Boreale reveal relatively dark layers which exhibit differential erosion. Eroded primarily by wind, the basal unit may be the major if not sole source for the north polar dunes and ergs and has contributed material to the lower polar cap layers. We investigate four possible origins for the basal unit (outflow channel/oceanic deposits, basal ice, paleopolar deposits, and eolian deposits). The patchy layering within the unit, its likely sandy grain size, and presence only in the north polar basin suggest that it is primarily an eolian deposit, supporting Byrne and Murray's 2002 earlier conclusion. This implies that at some time during the Early to Late Amazonian, migrating sand was mixed with water ice, forming a relatively dark, sandy deposit. During this time, either no classic polar layered deposits were forming or smaller caps were growing and shrinking, possibly adding material to the basal unit.     

The Galileo star scanner observations at Amalthea

In November of 2002, the Galileo spacecraft passed within 250 km of Jupiter's moon Amalthea. An onboard telescope, the star scanner, observed a series of bright flashes near the moon. It is believed that these flashes represent sunlight reflected from 7 to 9 small moonlets located within about 3000 km of Amalthea. From star scanner geometry considerations and other arguments, we can constrain the diameter of the observed bodies to be between 0.5 m to several tens of kilometers. In September of 2003, while crossing Amalthea's orbit just prior to Galileo's destruction in the jovian atmosphere, a single additional body seems to have been observed. It is suspected that these bodies are part of a discrete rocky ring embedded within Jupiter's Gossamer ring system.     

Plio-Pleistocene palaeoceanography of the tropical Indian Ocean (ODP Hole 709C): Radiolarian and CaCO3 evidence

Sediments spanning the Olduvai subchron (1.79–1.95 Ma) of ODP Hole 709C in the tropical Indian Ocean were sampled at 5-cm intervals. High-resolution quantitative radiolarian and CaCO₃% data have been used as proxies in interpreting palaeoceanographical conditions, an a comparison made with previously obtained oxygen isotope data. Radiolarian data were subjected to principal components analysis, resulting in four varimax factors. Factor 1 accounted for the greatest variation and comprised well-know warm-water and cold-water taxa, with high +ve and - ve scores respectively, which were used in the construction of a temperature index. Results indicate a tripartite temporal division of Olduvai palaeoceanography. In the early Olduvai, prior to 1.895 Ma, and the late Olduvai, approximating the Plio-Pleistocene boundary at 1.81 Ma, divergence-driven equatorial upwelling and high-productivity coincide with isotope-defined ‘interglacials’, and with generally low CaCO₃%. However, during the mid-Olduvai, upwelling, productivity and sedimentation rates were all reduced. These changes in palaeoceanography are thought to be linked directly to eccentricity modulated variations in the precession of the Earth's orbit. The early and late Olduvai coincide with periods of minimum eccentricity, when precessional reinforcemnet of the southwest monsoon is weakest, coastal upwelling along the Oman margin is reduced, and zonal wind-driven equatorial divergence upwelling is increased. The mid-Olduvai, however, corresponds with an eccentricity maximum, during which monsoonal activity is stronger and equatorial divergence upwelling weak.     

Chemical partitioning of trace and major elements in soils contaminated by mining and smelting activities

Soils from historical Pb mining and smelting areas in Derbyshire, England have been analysed by a 5-step sequential extraction procedure, with multielement determination on extraction solutions at each step by ICP-AES. Each of the chemical fractions is operationally defined as: (i) exchangeable; (ii) bound to carbonates or specifically adsorbed; (iii) bound to Fe–Mn oxides; (iv) bound to organic matter and sulphides; (v) residual. The precision was estimated to be about 5%, and the overall recovery rates were between 85 and 110%. The carbonate/specifically adsorbed and Fe–Mn oxide phases are the largest fractions for Pb in soils contaminated by both mining and smelting. Most of the Zn is associated with Fe–Mn oxide and the residual fractions. Cadmium is concentrated in the first 3 extraction steps, particularly in the exchangeable phase. The most marked difference found between soils from the mining and smelting sites is the much higher concentrations and proportions of metals in the exchangeable fraction at the latter sites. This indicates greater mobility and potential bioavailability of Pb, Zn and Cd in soils at the smelting sites than in those in the mining area. The most important fraction for Fe and Al is the residual phase, followed by the Fe–Mn oxide forms. In contrast, the Fe–Mn oxide fraction is the dominant phase for Mn in these soils. In the mining area, most of the Ca is in the carbonate fraction (CaCO₃), while the exchangeable and residual phases are the main fractions for Ca at the smelting sites. Phosphorus is mainly in the residual and organic fractions in both areas. The exchangeable fractions of Pb, Zn and Cd in soils were found to be significantly related to the concentrations of these metals in pasture herbage.     

Temporal englacial water content variability associated with a rapidly retreating glacier

This study uses a combination of evidence from ground penetrating radar, borehole, video, and wireless probe data to assess temporal changes in englacial water content associated with Briksdalsbreen, a rapidly retreating Norwegian glacier. Over a 13 day period in 2006, ice radar‐wave velocity varied between 0·135 m/ns (± 0·009) and 0·159 m/ns (± 0·003), and water content from 7·8% (+2·6, ?2·8) to 2·5% (+0·9, ?1·1) [derived from the Looyenga (Physica 31 (3): 401–406, 1965) formula]. It is suggested that during warm precipitation free days, void spaces within the glacier become filled with water, resulting in low radar‐wave velocity. This stored water then drained during cold, high precipitation days, allowing the radar‐wave velocity to rise. These changes in englacial storage were caused by the enhanced crevassing generated by the newly floating ice margin, and were associated with accelerated glacier retreat. Copyright © 2011 John Wiley & Sons, Ltd.