OSL dating of southeast Australian quartz: A preliminary assessment of luminescence characteristics and behaviour

Australian quartz has been widely considered particularly suitable for OSL dating of sediments. We present the results of a preliminary investigation into the luminescence characteristics and behaviour of quartz from various regions and depositional contexts across southeastern Australia. In doing so, we find that quartz from this region is generally well suited to the SAR protocol, although individual sample behaviour should nevertheless be assessed to confirm this. Furthermore, luminescence sensitivity appears to relate to depositional context, with aeolian samples exhibiting the highest sensitivity values, and lacustrine and periglacial sediments the lowest. The extent of a sample's sedimentary history, which in many cases is characteristic of the region from which it is derived, may also influence quartz sensitisation through repeated cycles of burial and reworking.     

Quadrupole ICP‐MS: Introduction to Instrumentation,Measurement Techniques and Analytical Capabilities

The low detection limits and multi‐element capability of inductively coupled plasma‐mass spectrometry (ICP‐MS) makes it an attractive option in a wide range of environmental, medical, biological, industrial and archaeological applications. Quadrupole ICP‐MS is used to determine element concentrations in a diverse range of sample types, often very different from the geological applications for which ICP‐MS was originally developed. Whilst modern instruments are robust and capable of a high degree of automation, it is essential that users of both instrumentation and data are aware of the strengths and limitations of the technique. Many people who are now involved with the operation and application of ICP‐MS instruments are not specialists in the field, as was usually the case amongst early operators. This back‐to‐basics review is aimed at the novice user and includes a guide to ICP‐MS instrumentation and performance. Whilst solids, liquids and gases can all be measured by ICP‐MS, discussion of sample introduction is limited to liquids. Requirements for producing good quality data, including aspects of sample preparation, calibration, and methods of interference limitation are also discussed.     

Stability of ice on Mars and the water vapor diurnal cycle: Experimental study of the sublimation of ice through a fine-grained basaltic regolith

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×¹⁰⁻⁴, 2.05±0.82×¹⁰⁻⁴, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×¹⁰⁴, 1.7±0.3×¹⁰⁴, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl₂. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.     

The assessment of vitellogenin as a biomarker of exposure to estrogenic compounds in two Australian perciformes

Vitellogenin (Vtg) is a yolk protein precursor that has been identified as a sensitive biomarker for exposure to estrogenic compounds. We evaluated specific monoclonal and polyclonal antibodies for reactivity with plasma Vtg from two Australian Perciformes, the tropical barramundi (Lates calcarifer) and the temperate black bream (Acanthopagrus butcheri). Blood plasma from 17beta-estradiol exposed (E2) male barramundi (20 mg kg(-1)) and male black bream (2.5-5.0 mg kg(-1)) were sent to Biosense Laboratories (Norway) for cross-reactivity testing using their extensive anti-Vtg antibody selection. Indirect ELISA results determined barramundi plasma displayed the highest binding affinities to ND-3G2 (monoclonal-Mab) and PO-1 (polyclonal-Pab). Black bream was most cross-reactive with ND-1C8 (Mab) and PO-2 (Pab). Next, plasma was assessed for Vtg induction in E2-dosed (5 mg kg(-1)), hatchery-reared barramundi and black bream versus a non-injected control group. Vtg production was assessed by Western blot and indirect ELISA using ND-3G2 and ND-1C8 Mabs, respectively. A prominent band was identified in the range of 100-200 kDa for all female black bream and for all E2-treated barramundi and black bream males, which was confirmed as Vtg by Western blot. Indirect ELISA results for barramundi demonstrated highly significant differences in E2-dosed fish as compared to control fish (Student t, P<0.001). E2 male black bream were significantly different than control males (Student t, P<0.001) and control and E2 females displayed highly significant differences (Student t, P<0.001). These results indicate that exposure to 17beta-estradiol induces significant Vtg production in males of the two Australian Perciformes, with potential use as a biomarker for exposure to estrogenic compounds.     

GCM Hindcasts of SST Forced Climate Variability over Agriculturally Intensive Regions

The NASA/Goddard Institute for Space Studies (GISS) climatemodel is forced with globally observed sea-surfacetemperatures (SST) in five simulations, 1969–1991,with individual runs beginning from altered initialatmospheric conditions. The interannual variability ofmodeled anomalies of the Southern Oscillation Index,mid-tropospheric temperatures, 850 mb zonal winds andOutgoing Longwave Radiation over the tropical PacificOcean, which has the largest SST anomaly forcing, arestrongly correlated with observed trends which reflectENSO cycles. The model's rainfall variability overthree agriculturally intensive regions, two tropicaland one mid-latitude, is investigated in order toevaluate the potential usefulness of GCM predictionsfor agricultural planning. The correct sign ofZimbabwe seasonal precipitation anomalies was hindcastwithin a useful range of consensus only for selectseasons corresponding to extreme ENSO events for whichanomalous circulation patterns were ratherrealistically simulated. The correlation betweenhindcasts of Nordeste monthly precipitation andobservations increases with time smoothing, reaching0.64 for 5-month running means. Consensus betweenindividual runs is directly proportional to theabsolute value of Niño3 SST so that during ElNiño and La Niña years most simulations agreeon the sign of predicted Nordeste rainfall anomalies.We show that during selected seasons the uppertropospheric divergent circulation and near surfacemeridional displacements of the ITCZ are realisticallyrepresented by the ensemble mean of the simulations.This realistic simulation of both the synopticmechanisms and the resulting precipitation changesincreases confidence in the GCM's potential forseasonal climate prediction.     

Trace Element Determination by ICP‐AES and ICP‐MS: Developments and Applications Reported During 2006 and 2007

This review describes developments in trace element determination using inductively coupled plasma‐atomic emission spectrometry (ICP‐AES) and inductively coupled plasma‐mass spectrometry (ICP‐MS) that were reported in 2006 and 2007. It focuses on the application of ICP techniques to geological and environmental samples; fundamental studies in ICP‐MS and ICP‐AES instrumentation have largely been ignored. New advances in ICP‐MS and ICP‐AES were incremental over this period, partly because both techniques are now well‐established. A continuing shift towards the hyphenation of low‐flow separation techniques has sparked activity in the development of appropriate low‐flow interfaces, and papers discussing interference removal also contribute significantly to the volume of research for both ICP‐AES and ICP‐MS. Whereas the majority of new ICP publications concerned advances in ICP‐MS analysis rather than ICP‐AES, development for ICP‐AES still occurs in almost all areas, particularly in sample introduction and hyphenated techniques.     

Assessing changes in nutrient status in the Richmond River estuary,Australia, using paleolimnological methods

Eutrophication from nutrient over-enrichment is a serious problem for the coastal zone and the estuarine environment globally. Australian estuaries are generally oligotrophic, but assessing whether they are becoming more eutrophic over time is inhibited by a lack of long-term monitoring data. The Richmond River, Australia, provided an ideal example of an estuary under anthropogenic pressure where the use of paleoecological techniques may potentially be used to reconstruct changes in nutrient status over time. Five cores were extracted from depositional areas in the Richmond River, and subjected to paleo-magnetic profiling and loss-on-ignition testing to ensure the core of greatest integrity was selected for further analytical work. Results from diatom and stable isotope analyses combined with ²¹⁰Pb and AMS ¹⁴C dating show a strong indication that the total phosphorus levels in the Richmond River have fluctuated since 1940. Evidence also suggests that these fluctuations are most likely a function of climate. This study has successfully applied paleolimnological techniques to the estuarine environment to produce information that can be used by environmental managers to aid decision making in relation to nutrient control for the Richmond River. Further work using paleolimnological techniques should be aimed at the extraction of a core containing diatoms that pre-date European settlement and include analyses of specific lipids and fatty acid biomarkers.     

Observations and analysis of the Southern binary R Arae

This paper investigates the nature of the relatively bright ( 7th magnitude) eclipsing variable R Arae (HD 149730A), which has an orbital period of 4^d.42509, from the analysis of photometricUBV observations. The main objective behind such an analysis is to determine whether the system qualifies for a classical Algol of semi-detached status.An analysis has been performed twice on each of theUBV curves as well as the light curve due to Gaposchkin, utilising a light curve optimisation procedure. In the first analysis the presence of the visual companion (HD 1497330B) to R Arae (angular separation = 3'.6), whose light was present in all observations, was not accounted for. The second analysis attempts to account for this third light source.All the analyses indicate the relative radius of the secondary star, is of the order of 0.20. This value is well below the limit which would classify the system as a semi-detached binary.These results do, however, seem to be somewhat discordant with the spectroscopic and general photometric nature of the system, all of which suggest mass transfer processes to be occuring (therefore a possible semi-detached status). This is seen in several features, especially a marked increase in the system's mean orbital period, which tends to corroborate mass transfer from the secondary star.     

Lake Winnipeg sediment physical properties: interpretation, composite stratigraphic sections and calibration of acoustic reflection profiles

High resolution sediment physical properties, measured on gravity and piston cores collected during cruises to Lake Winnipeg, include bulk density, acoustic velocity, magnetic susceptibility, shear strength and colour reflectance. The high resolution data are used here to construct complete stratigraphic (composite) sections of Lake Winnipeg sediments from a series of individual, discontinuous cores for the North and South Basins. These composite sections are used to evaluate basin-wide glacial and post-glacial depositional histories and to compare the northern and southern basin histories. In addition, these sections provide a baseline depth reference for interpretation of the biostratigraphy, paleomagnetic record and rock magnetic stratigraphy. Some of the data (density and shear strength) are also be used to estimate sediment stress history for the two major lithostratigraphic units and their variations across the basin.