Mitigation of Oceanic Tidal Aliasing Errors in Space and Time Simultaneously Using Different Repeat Sub-Satellite Tracks from Pendulum-Type Gravimetric Mission Candidate

This contribution investigates two different ways for mitigating the aliasing errors in ocean tides. This is done, on the one hand, by sampling the satellite observations in another direction using the pendulum satellite mission configuration. On the other hand, a mitigation of the temporal aliasing errors in the ocean tides can be achieved by using a suitable repeat period of the sub-satellite tracks.The findings show, firstly, that it is very beneficial for minimizing the aliasing errors in ocean tides to use pendulum configuration; secondly, optimizing the orbital parameter to get shorter repeat orbit mode can be effective in minimizing the aliasing errors. This paper recommends the pendulum as a candidate for future gravity mission to be launched in longer repeating orbit mode with shorter “sub-cycle” repeat periods to improve the temporal resolution of the satellite mission.     

Hydration shell structures in a LiI solution at elevated temperature and pressure: a molecular dynamics study

Molecular dynamics simulations of a 0.55 molal aqueous LiI solution have been performed at 508 K and 308 K and a density of 1.05 g/cm³. The structural changes resulting from increased temperature and pressure are discussed.     

210Po and 210Pb distributions in ocean water profiles from the Eastern South Pacific

Two ocean profiles from the Peru Basin from regions with different surface productivities were analyzed for total²¹⁰Pb and²⁰¹Po to evaluate the influence of particulates in the water column on their distribution. Comparison with a published²²⁶Ra profile for the region was made. The profile closest to the coast, where upwelling and productivity are high, shows depletion of²¹⁰Pb relative to²²⁶Ra at all depths, with particularly marked excursions from radioactive equilibrium at the surface and in the bottom water.²¹⁰Po appears to be deficient relative to²¹⁰Pb at depth as well. Mean residence times in the deep water, relative to particulate removal from the water column to the sediments, of about 100 years for²¹⁰Pb and about two years for²¹⁰Po are indicated. The profile northwest of the upwelling region shows the²²⁶Ra²¹⁰Pb²¹⁰Po system close to equilibrium at all depths to 1500 m (except for the effect of atmospheric²¹⁰Pb input seen at the surface.     

Wassermilben aus dem Amazonasgebiet (Hydrachnellae,Acari)

Zusammenfassung Erstmalig aus dem Amazonasgebiet wurden nach den SammlungenSioli undBraun die Hydrachnellae untersucht. Von den 104 festgestellten Arten bzw. Unterarten waren 64 neu für die Wissenschaft; 5 neue Genera bzw. Subgenera wurden aufgestellt. Durch 171 ausgewertete F?nge wurden 1033 Individuen ermittelt, eine im Vergleich mit anderen Sammlungen geringe Menge sowohl im ganzen gesehen, als auch die Individuen pro Fang betrachtet, als auch im Hinblick auf die hohe Zahl der neuen Formen in der kleinen Individuenmenge. Als Ursache dieser Diskrepanz werden neben extensivem Sammelverfahren chemisch-physikalische Faktoren der Gew?sser vermutet. Die Amazonas-Wassermilben werden nach Biotopen-stehende und fliessende Gew?sser-untersucht; dazu kommen Angaben über Frequenz, über jahreszeitliche Verteilung und das Verh?ltnis der Geschlechter. Der besondere Chemismus der Amazonasgew?sser-die im allgemeinen niedrigen pH-Werte-, dazu die klimatisch bedingte inkonstanz mancher Faktoren scheint bei der wohl grossen Toleranz der Wassermilben diesen Faktoren gegenüber weniger direkt, vielleicht aber indirekt die Nahrungstiere und damit das zahlenm?ssige Auftreten der Hydrachnellae zu beeinflussen. Ein Vergleich der Wassermilben aus den bislang untersuchten tropischen Gebieten kann noch nicht zu allgemeinen Ergebnissen gelangen, weil einheitlich zutreffende Vergleichspunkte noch kaum gegeben sind.     

Time scale of hydrothermal water-rock reactions in Yellowstone National Park based on radium isotopes and radon

We have measured ²²⁴Ra (3.4 d), ²²⁸Ra (5.7 yr), and ²²⁶Ra (1620 yr) and chloride in hot spring waters from the Norris-Mammoth Corridor, Yellowstone National Park. Two characteristic cold-water components mix with the primary hydrothermal water: one for the travertine-depositing waters related to the Mammoth Hot Springs and the other for the sinter-depositing Norris Geyser Basin springs. The Mammoth Hot Springs water is a mixture of the primary hydrothermal fluid with meteoric waters flowing through the Madison Limestone, as shown by the systematic decrease of the (²²⁸Ra/²²⁶Ra) activity ratio proceeding northward. The Norris Geyser Basin springs are mixtures of primary hydrothermal water with different amounts of cold meteoric water with no modification of the primary hydrothermal (²²⁸Ra/²²⁶Ra) activity ratio. Using a solution and recoil model for radium isotope supply to the primary hydrothermal water, a mean water-rock reaction time prior to expansion at 350°C and supply to the surface is 540 years assuming that 250 g of water are involved in the release of the radium from one gram of rock. The maximum reaction time allowed by our model is 1150 years.     

Distribution,sediment magnetism and geochemistry of the Saksunarvatn (10 180 ± 60 cal. yr BP) tephra in marine,lake, and terrestrial sediments,northwest Iceland

In 1997, seismic surveys in the troughs off northwest and north Iceland indicated the presence of a major, regional sub‐bottom reflector that can be traced over large areas of the shelf. Cores taken in 1997, and later in 1999 on the IMAGES V cruise, penetrated through the reflector. In core MD99‐2269 in Húnaflóaáll, this reflector is shown to be represented by a basaltic tephra with a geochemical signature and radiocarbon age correlative with the North Atlantic‐wide Saksunarvatn tephra. We trace this tephra throughout northwest Iceland in a series of marine and lake cores, as well as in terrestrial sediments; it forms a layer 1 to 25 cm thick of fine‐ to medium‐grained basaltic volcanic shards. The base of the tephra unit is always sharp but visual inspection and other measurements (carbonate and total organic carbon weight %) indicate a more diffuse upper boundary associated with bioturbation and with sediment reworking. Off northwest Iceland the Saksunarvatn tephra has distinct sediment magnetic properties. This is evident as a dramatic reduction in magnetic susceptibility, an increase in the frequency dependant magnetic susceptibility and ‘hard’ magnetisation in a −0.1T IRM backfield. Geochemical analyses from 11 sites indicate a tholeiitic basalt composition, similar to the geochemistry of a tephra found in the Greenland ice‐core that dates to 10 180 ± 60 cal. yr BP, and which was correlated with the 9000 ¹⁴C yr BP Saksunarvatn tephra. We present accelerator mass spectrometry ¹⁴C dates from the marine sites, which indicate that the ocean reservoir correction is close to ca. 400 yr at 9000 ¹⁴C yr BP off northwest Iceland. Copyright © 2002 John Wiley & Sons, Ltd.     

The relationship between dissolved hydrogen and nitrogen fixation in ocean waters

Fixed nitrogen is a key nutrient involved in regulating global marine productivity and hence the global oceanic carbon cycle. Oceanic nitrogen (N₂) fixation is estimated to supply 8×10¹² moles N y^?1 to the ocean, approximately equal to current riverine and the atmospheric inputs of fixed N, and between 50 and 100% of current estimates of oceanic denitrification. However, the spatial and temporal variability of N₂ fixation remains uncertain, mostly because of the normal low resolution sampling for diazotroph distribution and fixation rates. It is well established that N₂ fixation, mediated by the enzyme nitrogenase, is a source of hydrogen (H₂), but the extent to which it leads to supersaturation of H₂ in oceanic waters is unresolved. Here, we present simultaneous measurements of upper ocean dissolved H₂ concentration (nmol L^?1), and rates of N₂ fixation (μmol N m^?3 d^?1), determined using ¹⁵N₂ tracer techniques (at 7 or 15 m), on a transect from Fiji to Hawaii. We find a significant correlation (r=0.98) between dissolved H₂ and rates of N₂ fixation, with the greatest supersaturation of H₂ and highest rates of N₂ fixation being observed in the subtropical gyres at the southern (～18°S) and northern (18°N) reaches of the transect. The lowest H₂ saturation and N₂ fixation were observed in the equatorial region between 8°S and 14°N. We propose that an empirical relationship between H₂ supersaturations and N₂ fixation measurements could be used to guide sampling for ¹⁵N fixation measurements or to aid the spatial interpolation of such measurements.     

Dissolved oxygen as an indicator of bioavailable dissolved organic carbon in groundwater

Concentrations of dissolved oxygen (DO) plotted vs. dissolved organic carbon (DOC) in groundwater samples taken from a coastal plain aquifer of South Carolina (SC) showed a statistically significant hyperbolic relationship. In contrast, DO-DOC plots of groundwater samples taken from the eastern San Joaquin Valley of California (CA) showed a random scatter. It was hypothesized that differences in the bioavailability of naturally occurring DOC might contribute to these observations. This hypothesis was examined by comparing nine different biochemical indicators of DOC bioavailability in groundwater sampled from these two systems. Concentrations of DOC, total hydrolysable neutral sugars (THNS), total hydrolysable amino acids (THAA), mole% glycine of THAA, initial bacterial cell counts, bacterial growth rates, and carbon dioxide production/consumption were greater in SC samples relative to CA samples. In contrast, the mole% glucose of THNS and the aromaticity (SUVA(254)) of DOC was greater in CA samples. Each of these indicator parameters were observed to change with depth in the SC system in a manner consistent with active biodegradation. These results are uniformly consistent with the hypothesis that the bioavailability of DOC is greater in SC relative to CA groundwater samples. This, in turn, suggests that the presence/absence of a hyperbolic DO-DOC relationship may be a qualitative indicator of relative DOC bioavailability in groundwater systems.