Stream response to subsidence from underground coal mining in central Utah

 Short-term geomorphic and hydrologic effects of subsidence induced by longwall mining under Burnout Creek, Utah were evaluated. During the year after longwall mining, 0.3–1.5 m of subsidence was measured near impacted reaches of the mountain stream channel. The major channel changes that occurred in a 700-m reach of Burnout Creek that was subsided from 1992 to 1993 were: (1) increase in lengths of cascades and to a lesser extent glides; (2) increases in pool length, numbers and volumes; (3) increase in median particle diameter of bed sediment in pools; and (4) some constriction in channel geometry. Most of the changes appeared short-lived, with channel recovery approaching pre-mining conditions by 1994. In a 300-m reach of the South Fork that was subsided from 1993 to 1994, only channel constriction was observed, although any impacts on pool morphology may have been confounded by heavy grazing in the riparian reaches during the dry summer of 1994. Similar near-channel sedimentation and loss of pool volume between 1993 and 1994 were noted throughout Burnout Creek and in adjacent, unmined James Creek. Subsidence during the 3-year period had no effect on baseflows or near-channel landslides. Received: 10 April 1998 · Accepted: 21 September 1998     

Degradation of an Azo Dye with Homogeneous and Heterogeneous Catalysts by Sonophotolysis

This study illustrates the degradation of an azo dye, Reactive Yellow 81 (RY81), by the combined irradiation of UV‐C and ultrasound in the presence of homogeneous (Fe²⁺) and heterogeneous (TiO₂, ZnO) catalysts. The efficiency of homogeneous and heterogeneous oxidation systems was evaluated in regard of the decolorization and mineralization of RY81. Decolorization followed pseudo‐first‐order kinetics with homogeneous and heterogeneous catalysts. Complete color removal was accomplished by homogeneous sonocatalytic and sonophotocatalytic oxidation processes with apparent rate constants of 0.96 × 10^?3 and 46.77 × 10^?3 s^?1, respectively, in the presence of Fe²⁺. However, partial color removal was obtained by heterogeneous sonocatalytic, photocatalytic, and sonophotocatalytic oxidation processes with apparent rate constants of 2.32 × 10^?3, 3.60 × 10^?3, and 3.67 × 10^?3 s^?1, respectively, in the presence of ZnO. TiO₂ had the worst catalytic effect of all of the oxidation processes. The addition of hydrogen peroxide increased the rate constants of the heterogeneous oxidation processes and decreased the rate constants of the homogeneous oxidation processes. RY81 mineralization was 62.8% for the US/UV/Fe²⁺ homogeneous oxidation process, which was the best oxidation process, whereas it was 43.5% for the US/UV/ZnO/H₂O₂ heterogeneous oxidation process within 2 h reaction time.     

Spectral Decomposition Using the CEEMD Method: a Case Study from the Carpathian Foredeep

The purpose of this work is to select the optimal spectral decomposition (SD) method for channel detection in the Miocene strata of the Carpathian Fordeep, SE Poland. For analysis, two spectral decomposition algorithms were tested on 3D seismic data: the first, based on Fast Fourier Transform (FFT), and second, on Complete Ensemble Empirical Mode Decomposition (CEEMD). Additionally the results of instantaneous frequency (IF) were compared with the results of peak frequency (PF) computed after the CEEMD. Both algorithms of SD enabled us to interpret channels, but the results are marginally different, i.e. the FFT shows more coarse, linear structures, that are desirable for channel interpretation, whereas the CEEMD does not highlight these structures as clearly and shows more, what the authors believe to be, noise.     

Geochemical heterogeneity and isotope geochemistry of natural attenuation processes in a gasoline-contaminated aquifer at the Hnevice site,Czech Republic

The geochemical processes, water–rock interactions and stable isotopes distribution (δ¹³C of DIC and δ¹⁸O and δ³⁴S of \({\text{SO}}^{{{\text{2 - }}}}_{{\text{4}}} \)) were investigated in the gasoline-contaminated aquifer at the Hnevice site, 50  km northwest of Prague, Czech Republic. Diesel, gasoline and oil leaks originate from a large fuel storage area causing heavy contamination of the saturated and unsaturated zones in an area of about 0.7  km². Groundwater investigations were conducted using five multilevel sampler wells with emphasis on redox parameters and degradation by-products and a solid-phase study focused on iron speciation and determination of principal and secondary minerals. Based on the study of groundwater and solid-phase geochemistry, four different geochemical zones were described. Zone I is thought to be background consisting of an aerobic aquifer and the absence of reduced species in significant concentrations. Zone II is situated in the plume core with methanogenic, sulphate and iron-reducing conditions accompanied by ankerite and kutnahorite precipitates and significant depletion of the oxidation capacity of the aquifer. Zone III is a mixing (corona) zone, situated at the fringe of the plume with high biodegradation rates and Fe(III)-precipitants. In zone IV, reoxidation of Fe(II) minerals (with e.g. the occurrence of psilomelane and cornelite) is typical.     

A Forearc (Guleman, Elaziğ) Ophiolite: Evidence from Peridotite Mineral Geochemistry

The Guleman ophiolite,one of the most important ophiolitic massifs of the Southeast Anatolian Ophiolitic Belt,consists of a core of serpentinized mantle rocks overlain by an ultramafic sequence,layered and isotropic gabbro,and sheeted dykes.The ophiolite structurally overlies the Lower Miocene Lice Formation and is overlain by young sandstones and shales of the Upper Maashtrichtian-Lower Eocene Hazar Complex and Middle Eocene Maden Complex.The Guleman ophiolite tectonically overlain by Precambrian to Upper Triassic Bitlis metamorphic massif.The mantle peridotites compose mainly of fresh and in place serpentinized harzburgite tectonite with local bands and lenses of dunites with large-sized chromitite pods.The Guleman peridotites commonly show porphyroclastic texture,high-temperature fabrics such as kink-bands in olivines.According to microprobe analyses,the harzburgite and dunite have low Ca O and Al2O3 abundance similar to Mariana forearc,and their average Cr-(=Cr/(Cr+Al)atomic)ratio of Cr-spinelsis surprisingly high(0.63)besides Fo content of olivine is between 90.9 to 92.3 in peridotites.According to Mg#(Mg/(Mg+Fe2+))versus Cr#in spinel diagram,the degree of partial melting is higher than 35%and spinel values plot in the forearc peridotites field.The Gulemanharzburgites have low Ca O,Al2O3 and Ti O2 contents in orthopyroxene and clinopyroxene lammelles,resembling those of depleted harzburgites from modern forearcs and different from moderately depleted abyssal peridotites.Consequently,we propose that the Guleman peridotites form in a forearc setting during the subduction initiation that developed as a result of northward subduction of the southern branch of the Neo-Tethys in response to the convergence between Arabian and Anatolian plates.