Mass concentrations of PM10, PM2.5, and black smoke (BS) were measured in April 2003 during a 3-week campaign in a small village and at a nearby background location in the central part of the Czech Republic. In a pilot analysis, concentrations of selected trace elements (Al, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Sr, Cd, Sb, Cs, Pb) in the collected aerosol were determined by means of ICP-MS. Average concentrations of both PM fractions and BS were higher in the village (37, 26 and 26 μg m−3) than at the background location (26, 19 and 11 μg m−3) for PM10, PM2.5 and BS, respectively. Both PM10 and PM2.5 were reasonably correlated in the village (r = 0.80) and also at the background location (r = 0.79). Correlation between same fractions from the village and from the background site were even higher (r = 0.97 and r = 0.95 for the PM10 and PM2.5, respectively) suggesting that most of the aerosol in both locations may be influenced by similar sources. The ratio between PM10 and PM2.5 showed that sources in the village contributed about 33% and 35% to local aerosol concentration for PM10 and PM2.5, respectively. When the data from the two rural locations were compared with corresponding 24-h averages of PM10 concentrations obtained for the period of the campaign from fixed site monitors situated near larger towns, the highest concentration was found in Prague the Czech capital (49 μg m−3) followed by a district town Beroun (41 μg m−3) and the village (37 μg m−3). The lowest PM10 concentration was found in the village background (26 μg m−3). Elemental analysis revealed higher concentrations for most of the elements characteristic of combustion aerosol (namely Zn, Pb, As, Mn and Ti) in the PM collected in the village. The results support the idea that traditional heating in villages may contribute a great extent to local air pollution and may represent an important problem. 相似文献
Gut content examination and trophic markers (fatty acids, stable isotopes of C and N) were combined to delineate the diet of the dominant species of amphipods from Mediterranean Posidonia oceanica seagrass meadows and to highlight trophic diversity among this community. Our results indicate that, although all dominant species heavily relied on macroalgal epiphytes, considerable interspecific dietary differences existed. Carbon stable isotope ratios notably showed that some of the amphipod species favored grazing on epiphytes from leaves or litter fragments (Apherusa chiereghinii, Aora spinicornis, Gammarus aequicauda), while others such as Dexamine spiniventris preferred epiphytes from rhizomes. The remaining amphipods (Caprella acanthifera, Ampithoe helleri and Gammarella fucicola) readily consumed both groups. In addition, SIAR modeling suggested that most species had a mixed diet, and relied on several food items. Fatty acid analysis and gut contents revealed that contributions of microepiphytic diatoms and of benthic and suspended particulate organic matter to the diet of amphipods were anecdotal. None of the examined species seemed to graze on their seagrass host [low 18:2(n‐6) and 18:3(n‐3) fatty acids contents], but Gammarus aequicauda partly relied on seagrass leaf detritus, as demonstrated by the lesser 13C‐depletion of their tissues. Overall, our findings suggest that amphipods, because of their importance in the transfer of organic matter from primary producers and detritus to higher rank consumers, are key items in P. oceanica‐associated food webs. 相似文献
The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast. 相似文献
The in situ (U-Th-Sm)/He and U/Pb laser-ablation double-dating procedure is a valuable method that can provide a large dataset relatively efficiently in contrast with conventional bulk helium thermochronometry. In this study, we evaluate the potential age error associated with the double ablation procedure and report the in situ (U-Th-Sm)/He double-ablation dating of 249 zircons from the Fish Canyon Tuff locality. With LA-ICP-MS pseudo-depth profiling and 3D numerical modelling, we show that the concentric double-ablation procedure in minerals with U-Th-Sm zoning can generate a significant (U-Th-Sm)/He age error (positive or negative), resulting in over-scattering and/or an offset of the mean age. Pseudo-depth profiling is insufficient to predict the individual age error, partly because of the superimposed ablations. To evaluate the consequence of this inherent bias, we confront a synthetic age distribution to the error expected for U-Th-Sm zoned zircons analysed with double-ablation (U-Th-Sm)/He thermochronometry. As expected, a strong age bias causes the spreading of peak ages, downgrading the original signal. Yet, the throughput of the ablation-based method can allow intra- and inter-sample peak age identification and comparison, and the coupling of (U-Th-Sm)/He and U/Pb ages extends our ability to deconvolute a multimodal age spectrum. 相似文献
The addition of the agent of treatment allows to obtain a better traficability and improves the capacity of the soil to compaction while assuring a correct implementation. Besides, the binder provides to the soil a direct, maintained, or increasing lift at the same time. The choice of the agent of treatment and its dosage is determined by the type of soil, its moisture content at the time of the treatment, and by the aimed characteristics. The technique of treatment of soil in place in the hydraulic binders consists in valuing the natural soil (existing at the site of construction) by mixing them with a hydraulic binder and some water. It allows to avoid the transport and implies their stabilization in very interesting costs before the implementation of the superficial layers. In this context, this paper presents the results of the shear strength parameters of a study in laboratory with the aim of using the fine soil, in particular an Algerian western resulting silt, after a treatment with the cement by dry mixing method. Our goal is to realize pavement structures (base layer and subgrade layer) with this material. This type of treatment requires to know well the material which we wish to treat. A geotechnical complete characterization before treatment is approached on samples compacted in different water content, followed by the study of the influence of the addition of 2, 4, and 6 % cement on the characteristics of portance and of strength to shearing. Shear test was performed after curing the samples for 24 h to evaluate the shear strength parameters. The obtained results highlight a clearly better and marked improvement of the characteristics such as the lift and the strength to shearing. 相似文献
The size of the stable region around the Lagrangian point L4 in the elliptic restricted three-body problem is determined by numerical integration as a function of the mass parameter and eccentricity of the primaries. The size distribution of the stable regions in the mass parameter-eccentricity plane shows minima at certain places that are identified with resonances between the librational frequencies of motions around L4. These are computed from an approximate analytical equation of Rabe relating the frequency, mass parameter and eccentricity. Solutions of this equation are determined numerically and the global behaviour of the frequencies depending on the mass parameter and eccentricity is shown and discussed. The minimum sizes of the stable regions around L4 change along the resonances and the relative strength of the resonances is analysed. Applications to possible Trojan exoplanets are indicated. Escape from L4 is also investigated. 相似文献
One of the main objectives of land-use change models is to explore future land-use patterns. Therefore, the issue of addressing uncertainty in land-use forecasting has received an increasing attention in recent years. Many current models consider uncertainty by including a randomness component in their structure. In this paper, we present a novel approach for tuning uncertainty over time, which we refer to as the Time Monte Carlo (TMC) method. The TMC uses a specific range of randomness to allocate new land uses. This range is associated with the transition probabilities from one land use to another. The range of randomness is increased over time so that the degree of uncertainty increases over time. We compare the TMC to the randomness components used in previous models, through a coupled logistic regression-cellular automata model applied for Wallonia (Belgium) as a case study. Our analysis reveals that the TMC produces results comparable with existing methods over the short-term validation period (2000–2010). Furthermore, the TMC can tune uncertainty on longer-term time horizons, which is an essential feature of our method to account for greater uncertainty in the distant future. 相似文献
The purpose of this study is to revaluate the changing spatial and temporal trends of precipitation in Turkey. Turkey is located in one of the regions at greatest risk from the potential effects of climate change. Since the 1970s, a decreasing trend in annual precipitation has been observed, in addition to an increasing number of precipitation-related natural hazards such as floods, extreme precipitation, and droughts. An understanding of the temporal and spatial characteristics of precipitation is therefore crucial to hazard management as well as planning and managing water resources, which depend heavily on precipitation. The ordinary kriging method was employed to interpolate precipitation estimates using precipitation records from 228 meteorological stations across the country for the period 1976–2010. A decreasing trend was observed across the Central Anatolian region, except for 1996–2000 which saw an increase in precipitation. However, this same period is identified as the driest year in Eastern and South Eastern Anatolia. The Eastern Black Sea region has the highest precipitation in the country; after 1996, an increase in annual precipitation in this region is observed. An overall reduction is also seen in southwest Turkey, with less variation in precipitation.