Influence of salinity and fish species on PAH uptake from dispersed crude oil

The use of chemical oil dispersants to minimize spill impacts causes a transient increase in hydrocarbon concentrations in water, which increases the risk to aquatic species if toxic components become more bioavailable. The risk of effects depends on the extent to which dispersants enhance the exposure to toxic components, such as polycyclic aromatic hydrocarbons (PAH). Increased salinities can reduce the solubility of PAH and the efficiency of oil dispersants. This study measured changes in the induction of CYP1A enzymes of fish to demonstrate the effect of salinity on PAH availability. Freshwater rainbow trout and euryhaline mummichog were exposed to water accommodated fractions (WAF), and chemically-enhanced water accommodated fractions (CEWAF) at 0 per thousand, 15 per thousand, and 30 per thousand salinity. For both species, PAH exposure decreased as salinity increased whereas dispersant effectiveness decreased only at the highest salinity. Hence, risks to fish of PAH from dispersed oil will be greatest in coastal waters where salinities are low.     

Biomarker responses in flounder (Platichthys flesus) and mussel (Mytilus edulis) in the Klaipeda-Būtinge area (Baltic Sea)

During the EU project BEEP a battery of biomarkers was applied in flounder (Platichthys flesus) and the blue mussel (Mytilus edulis) collected at three locations off the Lithuanian coast (Baltic Sea) in June and September 2001 and 2002. The elevated biomarker responses in specimens sampled in September 2001 were apparently related to the extensive dredging activities in the Klaipeda port area and subsequent dumping of contaminated sediments. High concentrations of organic pollutants (organochlorines and PBDEs) were also measured in the tissues of both indicator species. In addition, response levels of genotoxicity, cytotoxicity, immunotoxicity as well as concentrations of PAH metabolites in the bile of flounder showed elevations in 2002 after an oil spill in the Būtinge oil terminal in November 2001. In flounder, biomarker measurements 10 months after the spill indicated recovery processes but in mussels a high level of genotoxicity could still be observed 22 months later. The present study illustrates the usefulness of the multi-biomarker approach in the detection of biological effects of pollution in this region of the Baltic Sea.     

The BEEP project in the Baltic Sea: overview of results and outline for a regional biological effects monitoring strategy

Field studies in the framework of the EU funded BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems, 2001-2004) aimed at validating and intercalibrating a battery of biomarkers of contaminant exposure and effects in selected indicator species in the Mediterranean, the North Atlantic and the Baltic Seas. Major strategic goals of the BEEP project were the development of a sensitive and cost-efficient biological effects monitoring approach, delivery of information and advice to end-user groups, and the implementation of a network of biomarker researchers around Europe. Based on the main results obtained in the Baltic Sea component of the BEEP the present paper summarises and assesses the applicability of biomarkers for different regions and species in this sea area. Moreover, a general strategy and some practical considerations for the monitoring of biological effects in the Baltic Sea are outlined.     

Liver histopathology in Baltic flounder (Platichthys flesus) as indicator of biological effects of contaminants

Results are presented of a study on liver histopathology in Baltic flounder (Platichthys flesus) carried out in 2001 and 2002 in four coastal sampling areas of the Baltic Sea: Kv?d?fj?rden (Swedish east coast, reference area), Klaipeda-Butinge (Lithuanian coast), Gulf of Gdansk (Polish coast), and Wismar Bay (German coast) within the framework of the EU-funded BEEP project. Liver lesions were diagnosed and categorised using standardised methodologies and, for a spatial and temporal assessment of the prevalence and types of lesions detected, a scoring system was applied, involving the calculation of mean histopathology lesion scores. 83.0% of the 436 female flounder examined (size range: 20-43 cm total length, age range: 2-8 years) were affected by liver lesions, out of which 74.3% were assigned to the category of non-specific, 3.4% to the category of early toxicopathic non-neoplastic, 4.6% to the category of pre-neoplastic and 0.7% to the category of neoplastic lesions. Mean lesions scores were highest in the areas at the Lithuanian and Swedish coast and there is indication of an impact of the age structure of the flounder populations studied, the sampling season as well as of contaminant effects.     

Contamination of Caribbean coastal waters by the antifouling herbicide Irgarol 1051

Irgarol 1051 is a s-triazine herbicide used in popular slime-resistant antifouling paints. It has been shown to be acutely toxic to corals, mangroves and sea grasses, inhibiting photosynthesis at low concentrations (>50 ng l(-1)). We present the first data describing the occurrence of Irgarol 1051 in coastal waters of the Northeastern Caribbean (Puerto Rico (PR) and the US Virgin Islands (USVI)). Low level contamination of coastal waters by Irgarol 1051 is reported, the herbicide being present in 85% of the 31 sites sampled. It was not detected in water from two oceanic reference sites. In general, Irgarol 1051was present at concentrations below 100 ng l(-1), although far higher concentrations were reported at three locations within Benner Bay, USVI (223-1,300 ng l(-1)). The known toxicity of Irgarol 1051 to corals and sea grasses and our findings of significant contamination of the Northeastern Caribbean marine environment by this herbicide underscore the importance of understanding, more fully, local and regional exposure of reef and sea grass habitats to Irgarol 1051 and, where necessary, implementing actions to ensure adequate protection of these important ecosystems.     

Improving multimodel weather forecast of monsoon rain over China using FSU superensemble

In this paper we present the current capabilities for numerical weather prediction of precipitation over China using a suite of ten multimodels and our superensemble based forecasts. Our suite of models includes the operational suite selected by NCARs TIGGE archives for the THORPEX Program. These are: ECMWF, UKMO, JMA, NCEP, CMA, CMC, BOM, MF, KMA and the CPTEC models. The superensemble strategy includes a training and a forecasts phase, for these the periods chosen for this study include the months February through September for the years 2007 and 2008. This paper addresses precipitation forecasts for the medium range i.e. Days 1 to 3 and extending out to Day 10 of forecasts using this suite of global models. For training and forecasts validations we have made use of an advanced TRMM satellite based rainfall product. We make use of standard metrics for forecast validations that include the RMS errors, spatial correlations and the equitable threat scores. The results of skill forecasts of precipitation clearly demonstrate that it is possible to obtain higher skills for precipitation forecasts for Days 1 through 3 of forecasts from the use of the multimodel superensemble as compared to the best model of this suite. Between Days 4 to 10 it is possible to have very high skills from the multimodel superensemble for the RMS error of precipitation. Those skills are shown for a global belt and especially over China. Phenomenologically this product was also found very useful for precipitation forecasts for the Onset of the South China Sea monsoon, the life cycle of the mei-yu rains and post typhoon landfall heavy rains and flood events. The higher skills of the multimodel superensemble make it a very useful product for such real time events.     

Modeling the Contemporary Stress Field and Deformation Pattern of Eastern Mediterranean

The contemporary stress field in the earth's crust is important and provides insights into mechanisms that drive plate motions.In this study,elastic plane stress finite element modeling incorporating realistic rock parameters was used to calculate the stress field,displacement field,and deformation of the plate interactions in the eastern Mediterranean.Modeled stress data for the African-Arabian-Anatolian plate interactions with fixed European platform correlate well with observed contemporary stress indica...     

Hydrogeochemistry and Water Quality Evaluation along the Flow Path in the Unconfined Aquifer of the Düzce Plain,North-western Turkey

The Düzce Plain has a multi-aquifer system, which consists of a near surface unconfined aquifer, along with first and second deeper confined aquifers. Hydrochemical evolution and water quality are related to infiltration of the precipitation, recharge from the formations surrounding the plain, flow path of groundwater and the relationship between surface and groundwater. The groundwater in the unconfined aquifer flows towards the Efteni Lake and the Büyük Melen River. Surface waters are divided into two main hydrochemical facies in the study area: (a) Ca2+–HCO3?; and (b) Ca2+, Mg2+–HCO3-, SO42-. The groundwater has generally three main hydrochemical facies: (a) Ca2+–HCO3-; (b) Ca2+, Mg2+–HCO3-; and (c) Ca2+, Mg2+–HCO3-, Cl-. The hydrochemical facies "a" and "b" dominate within shallow depths in recharge areas under rapid flow conditions, while hydrochemical facies "c" characterizes shallow and mixed groundwater, which dominate intermediate or discharge areas (near Efteni Lake and Büyük Melen River) during low flow conditions and agricultural contamination. Calcium and bicarbonate ions, total hardness and electrical conductivity of total dissolved solids (EC–TDS) values increase along the groundwater flow path; but these parameters remain within the limits specified by the standards set for industrial and agricultural usages.