Fast and Interactive Editing Tools for Spatial Models

Mathematical Geosciences - Multiple point statistics (MPS) algorithms allow generation of random fields reproducing the spatial features of a training image (TI). Although many MPS techniques offer...     

Microstructural constraints on the mechanisms of the transformation to reidite in naturally shocked zircon

Zircon (ZrSiO₄) is used to study impact structures because it responds to shock loading and unloading in unique, crystallographically controlled manners. One such phenomenon is the transformation of zircon to the high-pressure polymorph, reidite. This study quantifies the geometric and crystallographic orientation relationships between these two phases using naturally shocked zircon grains. Reidite has been characterized in 32 shocked zircon grains (shocked to stages II and III) using a combination of electron backscatter diffraction (EBSD) and focused ion beam cross-sectional imaging techniques. The zircon-bearing clasts were obtained from within suevite breccia from the Nördlingen 1973 borehole, close to the center of the 14.4 Ma Ries impact crater, in Bavaria, Germany. We have determined that multiple sets (up to 4) of reidite lamellae can form in a variety of non-rational habit planes within the parent zircon. However, EBSD mapping demonstrates that all occurrences of lamellar reidite have a consistent interphase misorientation relationship with the host zircon that is characterized by an approximate alignment of a {100}_zircon with a {112}_reidite and alignment of a {112}_zircon with a conjugate {112}_reidite. Given the tetragonal symmetry of zircon and reidite, we predict that there are eight possible variants of this interphase relationship for reidite transformation within a single zircon grain. Furthermore, laser Raman mapping of one reidite-bearing grain shows that moderate metamictization can inhibit reidite formation, thereby highlighting that the transformation is controlled by zircon crystallinity. In addition to lamellar reidite, submicrometer-scale granules of reidite were observed in one zircon. The majority of reidite granules have a topotaxial alignment that is similar to the lamellar reidite, with some additional orientation dispersion. We confirm that lamellar reidite likely forms via a deviatoric transformation mechanism in highly crystalline zircon, whereas granular reidite forms via a reconstructive transformation from low-crystallinity ZrSiO₄ within the reidite stability field. The results of this study further refine the formation mechanisms and conditions of reidite transformation in naturally shocked zircon.     

Electrochemical Ozone Production as an Environmentally Friendly Technology for Water Treatment

Perspectives, advances and environmental aspects concerning electrochemical ozone production applied to water purification are presented and discussed in relation to the conventional corona process (silent electric discharge). Ozone generated using a laboratory‐made electrochemical reactor was applied for the discoloration/degradation of dyes used in the Brazilian textile industry and for degradation of endocrine disruptors. A constant ozone load of 0.35 ± 0.02 g/h was used throughout. The study, concerning color removal from dye solutions, revealed that total discoloration is rapidly achieved. The degradation rate of the textile dyes evaluated by TOC is little affected by the dye composition and considerably influenced by the pH and ozonation time. Analysis of the COD/TOC‐ratio indicates that ozonation increases oxidation feasibility of the organic matter (dye by‐products) when compared to the original compounds. Ozonation of mixed aqueous solutions containing different endocrine disruptors revealed these compounds are totally degraded with a very high removal rate.     

Relationships between hydrosedimentary processes and occurrence of mercury-resistant bacteria (merA) in estuary mudflats (Seine, France)

The Seine estuary (France) is one of the world's macrotidal systems that is most contaminated with heavy metals. To study the mercury-resistant bacterial community in such an environment, we have developed a molecular tool, based on competitive PCR, enabling the quantification of Gram-negative merA gene abundance. The occurrence of the Gram-negative merA gene in relation with the topology (erosion/deposit periods) and the mercury contamination of three contrasted mudflats was investigated through a multidisciplinary approach and compared with a non-anthropized site (Authie, France). The higher abundance of the Gram-negative merA gene in the Seine estuary mudflats indicates a relationship between the degree of anthropization and the abundance of the merA gene in the mudflat sediments. In the Seine mudflats, the maxima of abundance are always located in fresh sediment deposits. Therefore, the abundance is closely related with the hydrosedimentary processes, which thus seem to be determining factors in the occurrence of the Gram-negative merA gene in the surface sediments of the Seine's mudflat.     

Faecal-indicator bacteria and sedimentary processes in estuarine mudflats (Seine, France)

Over a three-year period, quantification of faecal indicators and the molecular detection of Escherichia coli and Salmonella were monitored in sediments from three contrasting mudflats of the Seine estuary (France). The elevation of the mudflat surface was monitored concurrently using a high-resolution altimeter. During the period of the study, estuarine mudflats were areas of deposition for faecal-indicator bacteria and were mainly controlled by sedimentary processes. In the intertidal freshwater and subtidal mudflats, the highest abundances of faecal-indicator bacteria were counted during a depositional period. Maximum levels were observed in the freshwater mudflats during periods of high flow: thermotolerant coliforms: 3.9 x 10(4) cfu cm(-2), enterococci: 1.2 x 10(4) cfu cm(-2), Clostridium perfringens spores: 9.8 x 10(5) spores cm(-2). Loss of culturability of enteric bacteria in sediment microcosms demonstrated the remediatory capacity of the mudflats, even if they might be a secondary source of bacteria-forming spores to the water column through erosion and resuspension events.     

Differential regional responses in drought length, intensity and timing to recent climate changes in a Mediterranean forested ecosystem

The Mediterranean area is one of the regions of the world where GCMs agree the most on precipitation changes due to climate change. In this study we aim to assess the impact of recent climate change on drought features of Mediterranean ecosystems in Southern France. Regional climatic trends for the 1971–2006 period are compared to drought trends based on a water balance model accounting for soil properties, vegetation structure and functioning. Drought, defined here as periods when soil water potentials drop below ??0.5 MPa, is described in terms of intensity, duration and timing, which are integrative of both climate variability and site conditions. Temporal trends in precipitation, temperature and solar radiation lead altogether to drier and warmer conditions over the region but with a high spatial heterogeneity; for similar climatic trends, a significant increase in drought intensity was detected in the wettest areas of the region, whereas drought intensity in the driest areas did not change. Indeed, in the wettest areas, we observed an earlier onset of drought by about 1 month, but a constant end of drought. In the driest areas of the region, we observed the same earlier onset of drought but combined with an earlier end of drought, thus leading to a shift of the dry season without increasing its duration. The definition of drought features both in terms of intensity but also of seasonal timing appears relevant to capture historical or forecasted changes in ecosystem functioning. Studies concerning climate change impacts on forested ecosystems should be interpreted with caution when using climate proxies alone.     

How well are daily intense rainfall events captured by current climate models over Africa?

The ability of state-of-the-art climate models to capture the mean spatial and temporal characteristics of daily intense rainfall events over Africa is evaluated by analyzing regional climate model (RCM) simulations at 90- and 30-km along with output from four atmospheric general circulation models (AGCMs) and coupled atmosphere–ocean general circulation models (AOGCMs) of the Climate Model Intercomparison Project 5. Daily intense rainfall events are extracted at grid point scale using a 95th percentile threshold approach applied to all rainy days (i.e., daily rainfall ≥1 mm day^?1) over the 1998–2008 period for which two satellite-derived precipitation products are available. Both RCM simulations provide similar results. They accurately capture the spatial and temporal characteristics of intense events, while they tend to overestimate their number and underestimate their intensity. The skill of AGCMs and AOGCMs is generally similar over the African continent and similar to previous global climate model generations. The majority of the AGCMs and AOGCMs greatly overestimate the frequency of intense events, particularly in the tropics, generally fail at simulating the observed intensity, and systematically overestimate their spatial coverage. The RCM performs at least as well as the most accurate global climate model, demonstrating a clear added value to general circulation model simulations and the usefulness of regional modeling for investigating the physics leading to intense events and their change under global warming.     

Automated Analyte Separation by Ion Chromatography Using a Cobot Applied to Geological Reference Materials for Li Isotope Composition

The demand for large and reliable data sets on isotopic composition has increased in geochemistry and environmental sciences over recent years. We present an automated ion chromatographic separation method using a robotic pipetting arm, termed ‘ChemCobOne’, to reduce sample separation time. Its performance was tested for lithium isotope separation in geological reference materials using a single‐step separation with HCl (0.2 mol l^?1) and a 2 ml resin volume. This refined lithium purification method does not forfeit precision, accuracy or purity compared with manual sample processing. In addition, a δ⁷Li value for NASS‐6 of 30.99 ± 0.50‰ (2s) (95% CI = 0.14‰, n = 44) was determined and the first δ⁷Li values for the granite rock reference material GS‐N (?0.57 ± 0.25‰ (2s), 95% CI = 0.15‰, n = 15), and for the soil reference material NIST SRM 2709a (?0.37 ± 0.67‰ (2s), 95% CI = 0.15‰, n = 63) are proposed.     

X-ray spectra produced by a hot plasma containing cold clouds

We compute the hard X-ray spectra from a hot plasma pervaded by small cold dense clouds. The main cooling mechanism of the plasma is Compton cooling by the soft thermal emission from the clouds. We compute numerically the equilibrium temperature of the plasma together with the escaping spectrum. The spectrum depends mainly on the amount of cold clouds filling the hot phase. The clouds covering factor is constrained to be low in order to produce spectra similar to those observed in Seyfert galaxies and X-ray binaries, implying that an external reflector is required in order to reproduce the full range of observed reflection amplitudes. We also derive analytical estimates for the X-ray spectral slope and reflection amplitude using an escape probability formalism.