The direct reduction of astronomical x-ray spectra

A matrix method is outlined for the reduction of astronomical X-ray spectral data which includes the effects of detector resolution and fluorescent escape phenomena. The differences between this method and the ‘backward reduction’ or multiple grid methods presently employed are discussed.     

Marine regions and regionalism in South-east Asia

If problems of ocean management are to be solved the seas must be divided up into appropriate regions. Regional boundaries can be based on factors of physical geography or on economic, political or management principles. South-east Asia, with complicated land-sea boundaries, provides a number of examples of different types of marine regions, which can be used as case study examples of problems and solutions in regionalizing the oceans. Eight regional types and locations are described and discussed, and it is concluded that regional arrangements for management or the solution of problems are at present limited to three: the Malacca-Singapore Straits, Andaman Sea and Celebes Sea.     

The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

Nickel, Copper, Zinc and Cadmium Cycling with Manganese in Lake Vanda (Wright Valley, Antarctica)

Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.     

Salinity-induced survival strategy of Vibrio cholerae associated with copepods in Cochin backwaters

The occurrence of Vibrio cholerae in water, sediment and copepods was studied over a wide range of salinity using conventional and polymerase chain reaction (PCR) techniques in the Cochin backwaters. V. cholerae occurred either as culturable or non-culturable form in this tropical estuary. During the pre monsoon period when high salinity prevailed (35.5psu) V. cholerae was associated with copepods only in non-culturable form, but with the onset of monsoon when lower salinity prevailed, copepod-associated-V. cholerae reverted back to culturable form. The optimum salinity range for culturability was found to be 15-20psu. This points to the fact that salinity is a major factor that which influences V. cholerae's culturability and its association with copepods in Cochin backwaters.     

Biological effects and subsequent economic effects and losses from marine pollution and degradations in marine environments: Implications from the literature

This paper serves as the missing piece in a more fuller understanding about economic losses from marine pollution, and demonstrates what losses have been estimated in the literature. Biological effects from marine pollution are linked with resulting economic effects and losses. The merging of these two areas is usually absent in studies of marine pollution losses. The literature has examined several effects due to marine pollution: damages due to harvest closures-restrictions, damages from consumption of unsafe seafood, damages due to decreased recreational activity, and damages related to waterfront real estate adjacent to contaminated water. Overall, marine pollution can and has resulted in sizable economic effects and losses. On the basis of the literature there is adequate justification for public policy actions to curb marine pollution, require inspection of seafood for toxic substances, and preserve marine water quality and sensitive marine environments.     

The thermal evolution of Corsica as recorded by zircon fission-tracks

New zircon fission-track (ZFT) ages from Corsica record multiple thermal events that can be tied to the structural evolution of the western Mediterranean region. The Corsican zircons have a wide scatter of ZFT grain ages (243–14 Ma), which together define several age domains. Western Corsica consists largely of stable Hercynian basement characterized by ZFT ages in the range 161–114 Ma. We interpret these ages (Late Jurassic–Early Cretaceous) as the product of a long-lived Tethyan thermal event related to continental rifting and subsequent drifting during the separation of the European and African plates and the formation of the Liguro–Piemontese ocean basin. In contrast to Hercynian Corsica, Alpine Corsica (northeast Corsica) experienced widespread deformation and metamorphism in Late Cretaceous(?)–Tertiary time. Dated samples from Alpine Corsica range in age from 112 to 19 Ma and all are reset or partially reset by one or more Alpine thermal events. The youngest ZFT grain ages are from the northernmost Alpine Corsica and define an age population at  24 Ma that indicates cooling after Tertiary thermal events associated with the Alpine metamorphism and the opening of the Liguro–Provençal basin. A less well-defined ZFT age population at  72 Ma is present in both Alpine Corsica and Hercynian basement rocks. The thermal history of these rocks is not clear. One interpretation is that the ZFT population at  72 Ma reflects resetting during a Late Cretaceous event broadly synchronous with the early Alpine metamorphism. Another interpretation is that this peak is related to variable fission-track annealing and partial resetting during the Tertiary Alpine metamorphic event across central to north-eastern Corsica. This partial age resetting supports the presence of a fossil ZFT partial annealing zone and limits the peak temperature in this area below 300 °C, for both the affected pre-Alpine and Alpine units.     

Climate change and crop yields in the Indian Cardamom Hills, 1978–2007 CE

In this study we analyzed climate and crop yields data from Indian cardamom hills for the period 1978–2007 to investigate whether there were significant changes in weather elements, and if such changes have had significant impact on the production of spices and plantation crops. Spatial and temporal variations in air temperatures (maximum and minimum), rainfall and relative humidity are evident across stations. The mean air temperature increased significantly during the last 30?years; the greatest increase and the largest significant upward trend was observed in the daily temperature. The highest increase in minimum temperature was registered for June (0.37°C/18?years) at the Myladumpara station. December and January showed greater warming across the stations. Rainfall during the main monsoon months (June–September) showed a downward trend. Relative humidity showed increasing and decreasing trends, respectively, at the cardamom and tea growing tracts. The warming trend coupled with frequent wet and dry spells during the summer is likely to have a favorable effect on insect pests and disease causing organisms thereby pesticide consumption can go up both during excess rainfall and drought years. The incidence of many minor pest insects and disease pathogens has increased in the recent years of our study along with warming. Significant and slight increases in the yield of small cardamom (Elettaria cardamomum M.) and coffee (Coffea arabica), respectively, were noticed in the recent years.; however the improvement of yield in tea (Thea sinensis) and black pepper (Piper nigrum L.) has not been seen in our analysis.