Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.     

A topological approach to understand a multiple-loop solar flare

We analyze the UV and X-ray data obtained by the SMM satellite for the flare starting at 02:36 UT on November 12, 1980 in AR 2779. From a detailed revision of the Ov emission, we find that the observations are compatible with energy being released in a zone above the magnetic inversion line of the AR intermediate bipole. This energy is then transported mainly by conduction towards the two distant kernels located in the AR main bipole. One of these kernels is first identified in this paper. Accelerated particles contribute to the energy transport only during the impulsive phase.We model the observed longitudinal magnetic field by means of a discrete number of subphotospheric magnetic poles, and derive the magnetic field overall topology. As in previous studies of chromospheric flares, the Ov kernels are located along the intersection of the computed separatrices with the photosphere. Especially where the field-line linkage changes discontinuously, these kernels can be linked in pairs by lines that extend along separatrices. Our results agree with the hypothesis of magnetic energy released by magnetic reconnection occurring on separatrices.     

Kleť minor planet discovery frequency by months (comparison)

Abstrakt The Kle search programme for minor planets using 0,63m Maksutov camera of Kle Observatory was begun in 1977 as a long-term project continuing up to the present day. The discovery frequency according to seasons in the year shows multiple differences between particular months.The comparison with the number of observing nights and obtained search plates; weather conditions and other influences will be discussed. The Kle minor planet discovery frequency also will be compared with the data base of all numbered minor planets.     

Dynamical evolution of NEAs: Close encounters, secular perturbations and resonances

We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v ₆ (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some fast-track dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.On leave from the Department of Mathematics, University of Pisa, Via Buonarroti 2, 56127 Pisa, Italy, thanks to the G. Colombo fellowships of the European Space Agency.     

A multivariate statistical and geostatistical study on the geochemistry of allochtonous karst bauxite deposits in Hungary

A geochemical evaluation of the Szc-Halimba-Kisld area, Hungary, covering an area of more than 200 km² is presented using different statistical and geostatistical methods. The study area is a representative example of allochtonous karst bauxite accumulation. The three groups of deposits studied here have been explored and mined since 1950. Several thousand boreholes have been drilled, and bauxite cores were analyzed for the five main chemical components. A total of 80,000 pleces of analytical data were processed, followed by a geological examination of borehole logs and of mining excavations.The quantitative geochemical evaluation of the data set led to both geochemical and practical results: The geochemical behavior of the allochtonous, clastic karst bauxite deposits differs essentially from that of the autochtonous and parautochtonous ones, as well as that of the lateritic bauxite deposits. The deposits of the study area can be split into several subsequent geochemical-sedimentological units, each representing an event of bauxite transport and accumulation. Clear regional patterns can be revealed in the composition of these units. The geostatistically measured chemical variability of the geochemical units is rather different, the lowest units showing the smallest variability. The interrelations of the main chemical components are weaker and more irregular in the studied deposits than in the autochtonous lateritic bauxite deposits. Additional local genetic features, such as transport routes, can be delineated by the methods applied. Within each deposit, local changes of chemical composition and of its variability can be determined more precisely. These results can be used in bauxite prospecting and exploration, because areas of high or low bauxite quality can be predicted.     

Jupiter: New retrieved thermal profiles and ammonia distributions

New thermal profiles of Jupiter are retrieved from recent far infrared spectral measurements and for H₂ mixing ratios varying from 0.8 to 0.94. The effective temperature corresponding to the inferred thermal profile is 123.15 ± 0.35°K. Far-infrared brightness temperature spectra computed from these profiles are compared to experimental data including measurements made at high spectral resolution in the NH₃ν₂ band at 10 μm and in NH₃ pure rotational bands between 40 and 110 μm. It is found that a strong depletion of NH₃ does occur in the Jovian stratosphere and that ammonia seems to be undersaturated in the upper troposphere.     

Motions in the solar atmosphere associated with the white light flare of 11 July 1978

Series of white light heliograms and oft- and on-band H filtergrams have been obtained, with an average spatial resolution of 1, to study the flare active McMath region 15403 on 11 July, 1978. A great number of accurate heliographic positions were determined for the umbrae, the white light flare patches and several bright H flare knots, as well as along the principal zero filament and an arch prominence. Using the measured heliographic coordinates of these objects their motions could be analyzed in some detail. The velocities of several different objects could be deduced from the coordinates. Since the heliocentric angle of the region was about 45°, the variation in apparent heliographic coordinates also enabled some variations in heights to be determined.It is pointed out that the flare when fully developed, consisted almost entirely of loops. The zero filament which was activated prior to the flare ran between two umbrae of common penumbra and opposite polarity, one belonging to an old, the other to a new spot group. The white light flare developed on both sides of the filament where it passed between these two umbrae; it was also the place where the flare started. Observational evidence appears to indicate that the erupted filament re-formed from below.An indication has been found that there was a link between the motion of some umbrae and the major flare occurrence.     

X-ray imaging of three flares during the impulsive phase

The impulsive phases of three flares that occurred on April 10, May 21, and November 5, 1980 are discussed. Observations were obtained with the Hard X-ray Imaging Spectrometer (HXIS) and other instruments aboard SMM, and have been supplemented with Hα data and magnetograms. The flares show hard X-ray brightenings (16–30 keV) at widely separated locations that spatially coincide with bright Hα patches. The bulk of the soft X-ray emission (3.5–5.5 keV) originates from in between the hard X-ray brightenings. The latter are located at different sides of the neutral line and start to brighten simultaneously to within the time resolution of HXIS. Concluded is that:

1. The bright hard X-ray patches coincide with the footpoints of loops.
2. The hard X-ray emission from the footpoints is most likely thick target emission from fast electrons moving downward into the dense chromosphere.
3. The density of the loops along which the beam electrons propagate to the footpoints is restricted to a narrow range (10⁹ < n < 2 × 10¹⁰ cm^-3), determined by the instability threshold of the return current and the condition that the mean free path of the fast electrons should be larger than the length of the loop.
4. For the November 5 flare it seems likely that the acceleration source is located at the merging point of two loops near one of the footpoints.

It is found that the total flare energy is always larger than the total energy residing in the beam electrons. However, it is also estimated that at the time of the peak of the impulsive hard X-ray emission a large fraction (at least 20%) of the dissipated flare power has to go into electron acceleration. The explanation of such a high acceleration efficiency remains a major theoretical problem.     

Spatial and temporal evolution of soft and hard X-ray emission in a solar flare

We study the spatial and temporal characteristics of the 3.5 to 30.0 keV emission in a solar flare on April 10, 1980. The data were obtained by the Hard X-ray Imaging Spectrometer aboard the Solar Maximum Mission Satellite. It is complemented in our analysis with data from other instruments on the same spacecraft, in particular that of the Hard X-ray Burst Spectrometer.Key results of our investigation are: (a) Continuous energy release is needed to substain the increase of the emission through the rising phase of the flare, before and after the impulsive phase in hard X-rays. The energy release is characterized by the production of hot (5 × 10⁷ T 1.5 × 10⁸ K) thermal regions within the flare loop structures. (b) The observational parameters characterizing the impulsive burst show that it is most likely associated with non-thermal processes (particle acceleration). (c) The continuous energy release is associated with strong chromospheric evaporation, as evidenced in the spectral line behavior determined from the Bent Crystal Spectrometer data. Both processes seem to stop just before flare maximum, and the subsequent evolution is most likely governed by the radiative cooling of the flare plasma.