Images of Jupiter from the pioneer 10 and pioneer 11 infrared radiometers: A comparison with visible and 5-μm images

All of the data acquired at Jupiter by the Infrared Radiometers on board Pioneers 10 and 11 are presented in the form of images with geometric control. The images are compared with 5-μm and visible images taken in the same time frame. The association of dark (blue or brown) and light (white or red) areas with warm and cool areas (at 5, 20, and 45 μm) respectively, extends to nearly all features observed on the planet. Where the normal association of light and dark visible markings with the zonal velocity breaks down (e.g., at the latitude of the South Equatorial Belt during the Pioneer encounters), the infrared emission seems to follow the visible cloud structure rather than the zonal velocity structure. Exceptions to the general rule involve 20-μm radiation, which reflects conditions in the altitude range 0.1–0.3 bar. For example, a comparison between Pioneer 10 and 11 images suggests that the South Equatorial Belt became brighter at 20 μm, but remained constant at other wavelengths between the two encounters.     

Infrared polar brightening on Jupiter: III. Spectrometry from the Voyager 1 IRIS experiment

Spectra from the Voyager 1 IRIS experiment confirm the existence of enhanced infrared emission near Jupiter's north magnetic pole in March 1979. The spectral characteristics of the enhanced emission are consistent with a Planck source function. A temperature-pressure profile is derived for the region near the north magnetic pole, from which quantitative abundance estimates of minor species are made. Some species previously detected on Jupiter, including CH₃D, C₂H₂ and C₂H₆, have been observed again near the pole. Newly discovered species, not previously observed on Jupiter, include C₂H₄, C₃H₄, and C₆H₆. All of these species except CH₃D appear to have enhanced abundances at the north polar region with respect to midlatitudes. Upper limits are determined for C₄H₂ and C₃H₈. The quantitative results are compared with model calculations based on ultraviolet results from the IUE satellite. The plausibility of the C₆H₆ identification in discussed in terms of the literature on C₂H₂ polymerization. The relation of C₆H₆ to cuprene is also discussed.     

HAPPY CANYON: A NEW TYPE OF ENSTATITE ACHONDRITE

Happy Canyon [found: 1971, 34° 46.5′N, 101° 33.6′W, Texas] consists of about 85 vol. % enstatite (Fs 0.4%), 5 to 10 vol % plagioclase (An 26%), and 5 vol % diopside (Fs 0.9%). In addition, there are minor remnants of metal (Ni 6.35 wt %, Si-free) and troilite (with 5.10 wt % Cr and 1.15 wt % Ti) that have survived extensive terrestrial weathering. The meteorite has a cumulate texture, uniform-size euhedral, prismatic crystals of enstatite (0.3 to 0.4 mm long) with interstitial plagioclase, diopside, troilite, and metal. The enstatite crystals are dominantly disordered and occur in alignments that suggest flow. There are no chondrules or remnants of chondrules. The enstatite crystals contain internal negative crystal voids, which are charactieristic of enstatite achondrites, as well as internal branching submicron rivulet dislocations. The bulk composition is that of an E6 enstatite chondrite, however, it has the texture of a crystal cumulate; achondritic, but unlike that of enstatite achondrites. Glass of a granitic composition occurs mainly in the mesostasis and is compositionally like the glass found inside pyroxene crystals in the Cumberland Falls enstatite achondrite. Happy Canyon is most simply explained as an E6 composition that has melted and reprecipitated at a slightly higher oxidation state, at some depth (> 7 km), possibly in the core volume of a small, asteroidal-size parent body. In terms of classification, it occupies the gap between the recrystallized enstatite chondrites and the igneous, crystalline, unbrecciated enstatite achondrites like Shallowater. Happy Canyon is a new type of enstatite achondrite     

WAS THE FORMATION OF LUNAR CRATER GIORDANO BRUNO WITNESSED IN 1178? LOOK AGAIN.

The assumption that five men witnessed the formation of the lunar crater Giordano Bruno on June 18, 1178, is analyzed. The difficulties inherent in this interpretation are discussed. The only tenable solution — that of a meteor passing before the moon — is presented.     

Two forsterite-bearing FUN inclusions in the Allende meteorite

We have discovered two FUN inclusions, CG-14 and TE, among a group of five forsterite-rich inclusions in Allende, two of which are described for the first time herein. All five consist of euhedral forsterite and spinel crystals poikilitically enclosed by fassaite. Forsterite and spinel are usually segregated from one another, sometimes into a spinel-rich mantle and a forsterite-rich core. Some inclusions contain vesicles, indicating that they were once molten. The crystallization sequence inferred from textures is: spinel, forsterite, fassaite and, finally, Mg-rich melilite. One concentrically-zoned inclusion contains melilite in its mantle whose composition lies on the opposite side of the liquidus minimum in the melilite binary from that in its core. This suggests that segregation of forsterite from spinel in all of these inclusions could be due to volatilization of MgO and SiO₂ relative to Al₂O₃ and CaO from the outsides of droplets. CG-14 is relatively uniformly enriched in refractory elements relative to Cl chondrites by a factor similar to that for Ca-, Al-rich coarse-grained inclusions except for Ca, Al and Hf which are unusually low. No Ce anomaly such as found in FUN inclusions Cl and HAL is present in CG-14. Whole-rock samples of CG-14 and TE are more strongly mass-fractionated in oxygen relative to “normal” Allende inclusions than the FUN inclusion EK 1-4-1 and less so than Cl. Relative to bulk Allende, both inclusions have strongly massfractionated magnesium and silicon and ²⁵Mg excesses or deficits of ²⁴Mg or ²⁶Mg. CG-14 has a ²⁹Si excess or a deficit of ²⁸Si or ³⁰Si. Volatilization loss cannot be responsible for the magnesium and silicon isotope fractionations, as this would require prohibitively large mass loss from these magnesium-rich inclusions. The remarkable similarity in textures between FUN and non-FUN inclusions implies similar thermal histories, arguing against different rates of evaporative loss of major elements. Sputtering alone may be insufficient to account for the magnitude and direction of oxygen isotope fractionation in FUN inclusions.     

X-ray absorption spectroscopic studies of silicate glasses and minerals

Selected results of x-ray absorption spectroscopy (XAS) studies of amorphous silicates and minerals are presented in order to show their utility in providing short-and, in certain cases, medium-range structural and bonding information for cations and anions. EXAFS and XANES studies of amorphous silicates are reviewed with the objective of illustrating variations in structural environments of the various types of glass-forming cations, including Si, Al, Na, K, Ca, Ti, Fe, Yb, and U. Al is shown to occur in tetrahedral coordination in all aluminosilicate glasses examined, including peraluminous compositions. The weakly bonded Na and Ca cations are shown to occur in sites with observed coordination numbers (ranging from 6 to 7) and distances similar to those predicted by molecular dynamics simulations. Elements like Ti, which form bonds of intermediate strength, may show some order beyond the first coordination shell at low concentrations in silicate glasses. EXAFS studies of Yb and U in silicate glasses at trace to minor concentration levels provide unique structural information about the environments of these cations. K-edges and XANES of transition element sulfides, third-row tetrahedral oxyanions, and oxygen in minerals are interpreted in terms of band theory or molecular orbital theory.