Application of the chemometric approach to evaluate the spatial variation of water chemistry and the identification of the sources of pollution in Langat River, Malaysia

The current study presents the application of selected chemometric techniques—hierarchical cluster analysis (HCA) and principal component analysis (PCA)—to evaluate the spatial variation of the water chemistry and to classify the pollution sources in the Langat River. The HCA rendered the sampling stations into two clusters (group 1 and group 2) and identified the vulnerable stations that are under threat. Group1 (LY 1 to LY 14) is associated with seawater intrusion, while group 2 (LY 15 to LY 30) is associated with agricultural and industrial pollution. PCA analysis was applied to the water datasets for group 1 resulting in four components, which explained 85 % of the total variance while group 2 extracted six components, explaining 88 % of the variance. The components obtained from PCA indicated that seawater intrusion, agricultural and industrial pollution, and geological weathering were potential sources of pollution to the study area. This study demonstrated the usefulness of the chemometric techniques on the interpretation of large complex datasets for the effective management of water resources.     

Integrative assessment of sediment quality in terms of chemical contamination in Jinhae Bay,South Korea

The assessment of sediment quality by considering chemical contaminants is required for the effective management of coastal environments. In this study, complex data sets of heavy metals and organic pollutants were integrated to evaluate sediment quality. Thirty-two target pollutants were quantitatively determined in surface sediments from 80 stations in Jinhae Bay, South Korea. A sediment quality index (SQI) was derived by combining the functions of “scope” (the number of variables that do not meet guideline objectives) and “amplitude” (the magnitude by which these variables exceed the guideline objective). The SQI reflects the spatial gradient and differences in the contamination status with regard to heavy metals and organic pollutants in Jinhae Bay. Fifty-nine out of eighty stations surveyed (74%) were classified as being in “excellent” or “good” condition according to the SQI, and no stations were in a “poor” condition. The mean sediment quality guideline quotient (mSGQq) ranged from 0.06 to 0.31 (from nontoxic to marginally toxic). Acute sediment toxicity leading to amphipod mortality was recorded at 17 stations (21%) of the 80 surveyed, where the mortality rate was slightly over 20%. No significant relationship was observed between sediment toxicity and the concentration of each toxicant or mSQGq.     

Total Suspended Sediments Mapping by Using ALOS Imagery Over the Coastal Waters of Langkawi Island, Malaysia

Remote sensing has been extensively used for water delineation and has played an important role in water quality evaluation and environmental management strategies. Suspended sediments are important determinants of water quality in coastal zones. Remote sensing enables the effective monitoring of total suspended sediments (TSS) and the detection of areas with critical water quality issues. This study aims to develop and implement regression models for estimating and mapping TSS concentrations from Advanced Land Observation Satellite (ALOS) images over the coastal waters of Langkawi Island, Malaysia. The algorithm was developed based on the water reflectance model, which is a function of the inherent optical properties of water. Such properties can then be linked to TSS concentration. In this study, an ALOS Advanced Visible and Near Infrared Radiometer type 2 device was used as the imaging sensor system. Concurrent complementary in-situ water samples were collected within the area coverage of the sensor, and digital numbers (DN) for each band corresponding to the sea-truth locations were determined. The extracted DN values were converted into reflectance values and then regressed with their respective sea-truth data. An algorithm was proposed to obtain the regression coefficient. This algorithm can estimate TSS concentrations with a high correlation coefficient (R²?=?0.96) and low root-mean-square error (RMSE?=?1.98 mg/l). Finally, a map of the TSS concentration was generated by using the proposed algorithm. This study found that TSS mapping can be conducted by using ALOS data over the coastal waters of Langkawi Island, Malaysia.     

Effects of Lime‐Based Waste Materials on Immobilization and Phytoavailability of Cadmium and Lead in Contaminated Soil

Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.     

Historical record of metal accumulation and lead source in the southeastern coastal region of Korea

Concentrations of heavy metals and Pb isotopes were measured in the 1-M HCl leaching fraction of core sediments spanning the last 400 years. This sedimentary record of pollution history in metal concentrations shows a good correlation with the increases in industrialization, urbanization, and energy consumption since 1901s. Notably, the Pb concentration and the ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios were constant before the 1910s (16.7 μg/g, 0.844, and 2.098, respectively), whereas they increased steadily up to 21.9 μg/g, 0.848, and 2.101 after the 1910s. The correlations between Pb isotope ratios (²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb) showed different linear regression trends for core sediments before and after the 1910s, indicating differences in Pb sources. Our interpretation suggests that the source of anthropogenic Pb in Korean coastal region and the Yellow Sea shelf was presumed to be Chinese coals or ores, which have also played a major role as sources of atmospheric particulate Pb.     

Numerical study on wave dynamics and wave-induced bed erosion characteristics in Potter Cove, Antarctica

Wave generation, propagation, and transformation from deep ocean over complex bathymetric terrains to coastal waters around Potter Cove (King George Island, South Shetland Islands, Antarctica) have been simulated for an austral summer month using the Simulating Waves Nearshore (SWAN) wave model. This study aims to examine and understand the wave patterns, energy fluxes, and dissipations in Potter Cove. Bed shear stress due to waves is also calculated to provide a general insight on the bed sediment erosion characteristics in Potter Cove.A nesting approach has been implemented from an oceanic scale to a high-resolution coastal scale around Potter Cove. The results of the simulations were compared with buoy observations obtained from the National Data Buoy Center, the WAVEWATCH III model results, and GlobWave altimeter data. The quality of the modelling results has been assessed using two statistical parameters, namely the Willmott’s index of agreement D and the bias index. Under various wave conditions, the significant wave heights at the inner cove were found to be about 40–50 % smaller than the ones near the mouth of Potter Cove. The wave power in Potter Cove is generally low. The spatial distributions of the wave-induced bed shear stress and active energy dissipation were found to be following the pattern of the bathymetry, and waves were identified as a potential major driving force for bed sediment erosion in Potter Cove, especially in shallow water regions. This study also gives some results on global ocean applications of SWAN.     

Numerical study on wave dynamics and wave-induced bed erosion characteristics in Potter Cove,Antarctica

Wave generation, propagation, and transformation from deep ocean over complex bathymetric terrains to coastal waters around Potter Cove (King George Island, South Shetland Islands, Antarctica) have been simulated for an austral summer month using the Simulating Waves Nearshore (SWAN) wave model. This study aims to examine and understand the wave patterns, energy fluxes, and dissipations in Potter Cove. Bed shear stress due to waves is also calculated to provide a general insight on the bed sediment erosion characteristics in Potter Cove.A nesting approach has been implemented from an oceanic scale to a high-resolution coastal scale around Potter Cove. The results of the simulations were compared with buoy observations obtained from the National Data Buoy Center, the WAVEWATCH III model results, and GlobWave altimeter data. The quality of the modelling results has been assessed using two statistical parameters, namely the Willmott’s index of agreement D and the bias index. Under various wave conditions, the significant wave heights at the inner cove were found to be about 40–50 % smaller than the ones near the mouth of Potter Cove. The wave power in Potter Cove is generally low. The spatial distributions of the wave-induced bed shear stress and active energy dissipation were found to be following the pattern of the bathymetry, and waves were identified as a potential major driving force for bed sediment erosion in Potter Cove, especially in shallow water regions. This study also gives some results on global ocean applications of SWAN.

     

Predictors of urban variable source area: a cross‐sectional analysis of urbanized catchments in the United States

Many studies have empirically confirmed the relationship between urbanization and changes to the hydrologic cycle and degraded aquatic habitats. While much of the literature focuses on extent and configuration of impervious area as a causal determinant of degradation, in this article, I do not attribute causes of decreased watershed storage on impervious area a priori. Rather, adapting the concept of variable source area (VSA) and its relationship to incremental storage to the particular conditions of urbanized catchments, I develop a statistically robust linear regression‐based methodology to detect evidence of VSA‐dominant response. Using the physical and meteorological characteristics of the catchments as explanatory variables, I then use logistic regression to statistically analyze significant predictors of the VSA classification. I find that the strongest predictor of VSA‐type response is the percent of undeveloped area in the catchment. Characteristics of developed areas, including total impervious area, percent‐developed open space and the type of drainage infrastructure, do not add to the explanatory power of undeveloped land in predicting VSA‐type response. Within only developed areas, I find that total impervious area and percent‐developed open space both decrease the odds of a catchment exhibiting evidence of VSA‐type response and the effect of developed open space is more similar to that of total impervious area than undeveloped land in predicting VSA response. Different types of stormwater management infrastructure, including combined sewer systems and infiltration, retention and detention infrastructure are not found to have strong statistically significant effects on probability of VSA‐type response. VSA‐type response is also found to be stronger during the growing season than the dormant season. These findings are consistent across a national cross‐section of urbanized watersheds, a higher resolution dataset of Baltimore Metropolitan Area watersheds and a subsample of watersheds confirmed not to be served by (combined sewer systems). Copyright © 2016 John Wiley & Sons, Ltd.     

Detrital zircon geochronology of the Cretaceous Sindong Group,Southeast Korea: Implications for depositional age and Early Cretaceous igneous activity

The Sindong Group forms the lowermost basin‐fill of the Gyeongsang Basin, the largest Cretaceous nonmarine basin located in southeastern Korea, and comprises the Nakdong, Hasandong, and Jinju Formations with decreasing age. The depositional age of the Sindong Group has not yet been determined well and the reported age ranges from the Valanginian to Albian. Detrital zircons from the Sindong Group have been subjected to U–Pb dating using laser ablation inductively coupled plasma mass spectrometry. The Sindong Group contains noticeable amounts of detrital magmatic zircons of Cretaceous age (138–106 Ma), indicative of continuous magmatic activity prior to and during deposition of the Sindong Group. The youngest detrital zircon age of three formations becomes progressively younger stratigraphically: 118 Ma for the Nakdong Formation, 109 Ma for the Hasandong Formation, and 106 Ma for the Jinju Formation. Accordingly, the depositional age of the Sindong Group ranges from the late Aptian to late Albian, which is much younger than previously thought. Lower Cretaceous magmatic activity, which supplied detrital zircons to the Sindong Group, changed its location spatially through time; it occurred in the middle and northern source areas during the early stage, and then switched to the middle to southern source areas during the middle to late stages. This study reports first the Lower Cretaceous magmatic activity from the East Asian continental margin, which results in a narrower magmatic gap (ca 20 m.y.) than previously known.