Ultrahigh-pressure metamorphic rocks from the Chinese Continental Scientific Drilling Project: II Oxygen isotope and fluid inclusion distributions through vertical sections

In order to reconstruct the formation and exhumation mechanisms of UHP metamorphic terrains, the Chinese Continental Scientific Drilling Program (CCSD) has been carried out in Donghai of the Dabie-Sulu ultrahigh-pressure (UHP) metamorphic belt, East China. Eclogite, gneiss, amphibolite (retrograded from eclogite), ultramafic rocks, and minor schist and quartzite have been drilled. Aiming to reveal the fluid behaviour in a vertical sequence of an UHP slab, we investigated fluid inclusion and oxygen isotope characteristics of selected drillcores from the main hole and the pilot-holes PP2 and ZK 703 of the CCSD. More than 540 laser-ablation oxygen isotope analyses on garnet, omphacite, quartz, kyanite, amphibole, phengite, rutile, epidote, amphibole, plagioclase, and biotite from various rocks in the depth range of 0–3,000 m (mainly eclogite and gneiss) show that the investigated rocks can be divided into two groups: ¹⁸O-depleted rocks (as low as δ¹⁸O = −7.4‰ for garnet) indicate interaction with cold climate meteoric waters, whereas ¹⁸O-normal rocks (with bulk δ¹⁸O > +5.6‰) have preserved the O-isotopic compositions of their protoliths. Meteoric water/rock interaction has reached depths of at least 2,700 m. Oxygen isotope equilibrium has generally been achieved. Isotopic compositions of mineral phases are homogeneous on a mm to cm scale regardless of lithology, but heterogeneous on the scale of a few metres. Oxygen isotope distributions in the vertical sections favour an “in situ” origin of the UHP metamorphic rocks. The very negative δ¹⁸O eclogites usually have higher hydroxyl-mineral contents than the normal δ¹⁸O rocks, indicating higher water content during UHP metamorphism. Fluid inclusion data suggest that rocks with depleted ¹⁸O compositions have had different fluid histories compared to those with normal δ¹⁸O values. Rocks with depleted ¹⁸O mainly have primary medium-to-high salinity inclusions in omphacite, kyanite and quartz, and abundant secondary low-salinity or pure water inclusions in quartz, indicating a high-salinity-brine-dominated fluid system during peak UHP metamorphism; no carbonic inclusions have been identified in these rocks. By contrast, primary very high-density CO₂ inclusions are commonly found in the rocks with normal δ¹⁸O values. These observations suggest that fluid and oxygen isotope composition of minerals are related and reflect variable degrees of alterations of the Dabie-Sulu UHP metamorphic rocks.     

Late Hercynian polymetallic vein-type base-metal mineralization in the Iberian Pyrite Belt: fluid-inclusion and stable-isotope geochemistry (S–O–H–Cl)

Late Variscan vein-type mineralization in the Iberian Pyrite Belt, related to the rejuvenation of pre-existing fractures during late Variscan extensional tectonism, comprises pyrite–chalcopyrite, quartz–galena–sphalerite, quartz–stibnite–arsenopyrite, quartz–pyrite, quartz–cassiterite–scheelite, fluorite–galena–sphalerite–chalcopyrite, and quartz–manganese oxide mineral assemblages. Studies of fluid inclusions in quartz, stibnite, and barite as well as the sulfur isotopic compositions of stibnite, galena, and barite from three occurrences in the central part of the Iberian Pyrite Belt reveal compelling evidence for there having been different sources of sulfur and depositional conditions. Quartz–stibnite mineralization formed at temperatures of about 200 °C from fluids which had undergone two-phase separation during ascent. Antimony and sulfide are most probably derived by alteration of a deeper lying, volcanic-hosted massive sulfide mineralization, as indicated by δ³⁴S signatures from ?1.45 to ?2.74‰. Sub-critical phase separation of the fluid caused extreme fractionation of chlorine isotopes (δ³⁷Cl between ?1.8 and 3.2‰), which correlates with a fractionation of the Cl/Br ratios. The source of another high-salinity fluid trapped in inclusions in late-stage quartz from quartz–stibnite veins remains unclear. By contrast, quartz–galena veins derived sulfide (and metals?) by alteration of a sedimentary source, most likely shale-hosted massive sulfides. The δ³⁴S values in galena from the two study sites vary between ?15.42 and ?19.04‰. Barite which is associated with galena has significantly different δ³⁴S values (?0.2 to 6.44‰) and is assumed to have formed by mixing of the ascending fluids with meteoric water.     

Thermodynamic modelling of diffusion-controlled garnet growth

Numerical thermodynamic modelling of mineral composition and modes for specified pressure-temperature paths reveals the strong influence of fractional garnet crystallisation, as well as water fractionation, on garnet growth histories in high pressure rocks. Disequilibrium element incorporation in garnet due to the development of chemical inhomogeneities around porphyroblasts leads to pronounced episodic growth and may even cause growth interruptions. Discontinuous growth, together with pressure- and temperature-dependent changes in garnet chemistry, cause zonation patterns that are indicative of different degrees of disequilibrium element incorporation. Chemical inhomogeneities in the matrix surrounding garnet porphyroblasts strongly affect garnet growth and lead to compositional discontinuities and steep compositional gradients in the garnet zonation pattern. Further, intergranular diffusion-controlled calcium incorporation can lead to a characteristic rise in grossular and spessartine contents at lower metamorphic conditions. The observation that garnet zonation patterns diagnostic of large and small fractionation effects coexist within the same sample suggests that garnet growth is often controlled by small-scale variations in the bulk rock chemistry. Therefore, the spatial distribution of garnet grains and their zonation patterns, together with numerical growth models of garnet zonation patterns, yield information about the processes limiting garnet growth. These processes include intercrystalline element transport and dissolution of pre-existing grains. Discontinuities in garnet growth induced by limited element supply can mask traces of the thermobarometric history of the rock. Therefore, thermodynamic modelling that considers fractional disequilibrium crystallisation is required to interpret compositional garnet zonation in terms of a quantitative pressure and temperature path of the host rock.     

Organochlorine and heavy metal concentrations in blubber and liver tissue collected from Queensland (Australia) dugong (Dugong dugon)

Tissue samples of liver and blubber were salvaged from fifty-three dugong (Dugong dugon) carcasses stranded along the Queensland coast between 1996 and 2000. Liver tissue was analysed for a range of heavy metals and blubber samples were analysed for organochlorine compounds. Metal concentrations were similar in male and female animals and were generally highest in mature animals. Liver concentrations of arsenic, chromium, iron, lead, manganese, mercury and nickel in a number of individual animals were elevated in comparison to concentrations previously reported in Australian dugong. Dieldrin, DDT (and its breakdown products) and/or heptachlor epoxide were detected in 59% of dugong blubber samples. In general, concentrations of organochlorines were similar to those reported in dugong 20 years earlier, and were low in comparison to concentrations recorded from marine mammal tissue collected elsewhere in the world. With the exception of lead, the extent of carcass decomposition, the presence of disease or evidence of animal starvation prior to death did not significantly affect dugong tissue concentrations of metals or organochlorines. The results of the study suggest that bioaccumulation of metals and organochlorine compounds (other than dioxins) does not represent a significant risk to Great Barrier Reef dugong populations, particularly in the context of other pressures associated with coastal development and other anthropogenic activities.     

Synergy of satellite remote sensing and numerical modeling for monitoring of suspended particulate matter

Monitoring and modeling of the distribution of suspended particulate matter (SPM) is an important task, especially in coastal environments. Several SPM models have been developed for the North Sea. However, due to waves in shallow water and strong tidal currents in the southern part of the North Sea, this is still a challenging task. In general there is a lack of measurements to determine initial distributions of SPM in the bottom sediment and essential model parameters, e.g., appropriate exchange coefficients. In many satellite-borne ocean color images of the North Sea a plume is visible, which is caused by the scattering of light at SPM in the upper ocean layer. The intensity and length of the plume depends on the wave and current climate. It is well known that the SPM plume is especially obvious shortly after strong storm events. In this paper a quasi-3-D and a 3-D SPM transport model are presented. Utilizing the synergy of satellite-borne ocean color data with numerical models, the vertical exchange coefficients due to currents and waves are derived. This results in models that for the first time are able to reproduce the temporal and spatial evolution of the plume intensity. The SPM models consist of several modules to compute ocean dynamics, the vertical and horizontal exchange of SPM in the water column, and exchange processes with the seabed such as erosion, sedimentation, and resuspension. In the bottom layer, bioturbation via benthos and diffusion processes is taken into account.Responsible Editor: Jörg-Olaf Wolff     

Recent tectonics of the Blanco Ridge,eastern blanco transform fault zone

Bathymetric, hydro-acoustic, seismic, submersible, and gravity data are used to investigate the active tectonics of the eastern Blanco Transform Fault Zone (BTFZ). The eastern BTFZ is dominated by the 150 km long transform-parallel Blanco Ridge (BR) which is a right-lateral strike-slip fault bordered to the east and west by the Gorda and Cascadia Depressions. Acoustic locations, fault-parameter information, and slip vector estimates of 43 earthquakes (M _w3.8) that occurred along the eastern BTFZ over the last 5 years reveal that the Blanco Ridge is a high-angle right-lateral strike-slip fault, with a small component of dip-slip motion, where the Juan de Fuca plate is the hanging wall relative to the Pacific plate. Furthermore, the Cascadia and Gorda basins are undergoing normal faulting with extension predominantly oblique to the transform trend. Seafloor submersible observations agree with previous hypotheses that the active transform fault trace is the elongate basin that runs the length of the BR summit. Brecciated and undeformed basalt, diabase, and gabbro samples were collected at the four submersible survey sites along the Blanco Ridge. These petrologic samples indicate the Blanco Ridge is composed of an ocean crustal sequence that has been uplifted and highly fractured. The petrologic samples also appear to show an increase in elevation of the crustal section from east to west along the Blanco Ridge, with gabbros exposed at a shallower depth farther west along the southern (Pacific plate side) BR ridge flank. Further supporting evidence for BR uplift exists in the seismic reflection profiles across the BR showing uplift of turbidite sequences along the north and south ridge base, and gravity and magnetics profiles that indicate possible basement uplift and a low-density zone centered on the ridge's Pacific plate side. The BR formation mechanism preferred here is first, uplift achieved partially through strike-slip motion (with a small dip-slip component). Second, seawater penetration along the fault into the lower crust upper mantle, which then enhanced formation and intrusion of a mantle-derived serpentinized-peridotite diapir into the shallow ocean crust, causing further uplift along the fault.     

增强的温盐成层现象为白垩纪大洋缺氧事件的可能成因

大洋缺氧事件为高碳埋藏期 ,可导致大气层二氧化碳减少、底层水氧浓度降低以及生物灭绝。多数大洋缺氧事件被认为是由碳的高生产力和从表层水中输出引起的 ,然后保存在富有机质沉积物（黑色页岩）中 ,但还不清楚引发这些事件的因素。这里我们提供了发生于１１２Ｍａ之前的白垩纪中期大洋缺氧事件的稳定同位素数据 ,表明增强的温盐成层现象为该事件的可能成因。大洋缺氧事件ｌｂ与表层水温上升和导致西特提斯洋和北大西洋的隔离盆地中的底层水减少以及碳埋藏量提高的径流量有关。这个事件在很大程度上类似于上新世 -更新世地中海腐泥形成的事…     

Heterozoan carbonates from the equatorial rocky reefs of the Galápagos Archipelago

Strongly influenced by seasonal and interannual (i.e. El Niño‐Southern Oscillation) upwelling, the equatorial setting of the Galápagos Archipelago is divided into well‐defined temperature, nutrient and calcium carbonate saturation (Ω_aragonite) regions. To understand the relationship between oceanographic properties and sediment grain associations, grain size, carbonate content and components from sea floor surface samples were analysed, representing the main geographical regions of the Galápagos Archipelago. The shallow‐water rocky reefs of the Galápagos Archipelago are characterized by mixed carbonate–siliciclastic slightly gravelly sands. Despite minor differences in carbonate content, major differences exist in the distribution and composition of key carbonate producing biota. Halimeda is absent and benthic foraminifera occur in extremely low abundance. The western side of the Galápagos Archipelago is strongly influenced by nutrient‐rich, low‐Ω_aragonite, subtropical water, which generates a heterozoan carbonate biofacies in a tropical realm resembling cold‐water counterparts (i.e. serpulid, echinoderm, gastropod, barnacle and bryozoan‐rich facies). The Central East region is composed of a transitional‐heterozoan biofacies. Biofacies observed in the northern region have an increased occurrence of tropical corals, albeit with a minor overall contribution to the carbonate components. Although the temperature gradient would allow for a broader distribution of photozoan biofacies, the increased nutrient concentration and related reduced light penetration from the upwelled waters favour heterozoan carbonate factories, mimicking cool‐water, deeper or higher latitude environments. The recent sedimentary record of the Galápagos Archipelago presents a range of tropical heterozoan carbonate communities, responding to more than simply latitude or temperature but a much more complex mixture of physical, evolutionary and geological processes.     

Meteorites from the United Arab Emirates: Description,weathering, and terrestrial ages

We report on the first meteorite search campaign in the United Arab Emirates (UAE). The geology and proximity of our search region suggest that it is the north‐western extension of the Oman meteorite fields. We found 26 ordinary chondrites, bringing the total number of official meteorites from the UAE to 28. The campaign was organized and conducted in close cooperation with the UAE government and the main masses of the meteorites remained in the country where they will become part of an exhibition. The bulk composition of five meteorite and three soil samples indicates an uptake of U, Mo, Sr, Ba, Li, and Pb from the soil into the meteorites during terrestrial weathering. Terrestrial ages determined from ¹⁴C decay of 21 meteorites range from recent falls to 24.4 ka, with two meteorites having >37 ka and approximately 39 ka, respectively. Weak correlations between weathering degree, meteorite bulk chemical composition, and terrestrial age suggest highly localized weathering conditions, possibly related to abundant occurrences of sabkhas in the search region.