Earthquakes in Switzerland and surrounding regions during 2012

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with M_L ≥ 2.5, the seismic activity in the year 2012 was far below the average over the previous 37 years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of M_L 3.3 and 3.5, the M_L 4.2 and M_L 3.5 earthquakes at a depth of 32 km below Zug in February and the M_L 3.6 event near Vallorcine in October. The epicentral intensity of the M_L 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effects.     

Cathodoluminescence,fluid inclusion and stable C–O isotope study of tectonic breccias from thrusting plane of a thin-skinned calcareous nappe

Basal hydraulic breccias of alpine thin-skinned Muráň nappe were investigated by means of cathodoluminescence petrography, stable isotope geochemistry and fluid inclusions analysis. Our study reveals an unusual dynamic fluid regime along basal thrust plane during final episode of the nappe emplacement over its metamorphic substratum. Basal thrusting fluids enriched in ¹⁸O, silica, alumina, alkalies and phosphates were generated in the underlying metamorphosed basement at epizonal conditions corresponding to the temperatures of 400–450°C. The fluids fluxed the tectonized nappe base, leached evaporite-bearing formations in hangingwall, whereby becoming oversaturated with sulphates and chlorides. The fluids further modified their composition by dedolomitization and isotopic exchange with the host carbonatic cataclasites. Newly formed mineral assemblage of quartz, phlogopite, albite, potassium feldspar, apatite, dravite tourmaline and anhydrite precipitated from these fluids on cooling down to 180–200°C. Finally, the cataclastic mush was cemented by calcite at ambient anchizonal conditions. Recurrent fluid injections as described above probably enhanced the final motion of the Muráň nappe.     

Production and Certification of a Unique Set of Isotope and Delta Reference Materials for Boron Isotope Determination in Geochemical,Environmental and Industrial Materials

Isotopic reference materials are essential to enable reliable and comparable isotope data. In the case of boron only a very limited number of such materials is available, thus preventing adequate quality control of measurement results and validation of analytical procedures. To address this situation a unique set of two boron isotope reference materials (ERM‐AE102a and ‐AE104a) and three offset δ¹¹B reference materials (ERM‐AE120, ‐AE121 and ‐AE122) were produced and certified. The present article describes the production and certification procedure in detail. The isotopic composition of all the materials was adjusted by mixing boron parent solutions enriched in ¹⁰B or ¹¹B with a boron parent solution having a natural isotopic composition under full gravimetric control. All parent solutions were analysed for their boron concentration as well as their boron isotopic composition by thermal ionisation mass spectrometry (TIMS) using isotope dilution as the calibration technique. For all five reference materials the isotopic composition obtained on the basis of the gravimetric data agreed very well with the isotopic composition obtained from different TIMS techniques. Stability and homogeneity studies that were performed showed no significant influence on the isotopic composition or on the related uncertainties. The three reference materials ERM‐AE120, ERM‐AE121 and ERM‐AE122 are the first reference materials with natural δ¹¹B values not equal to 0‰. The certified δ¹¹B values are ?20.2‰ for ERM‐AE120, 19.9‰ for ERM‐AE121 and 39.7‰ for ERM‐AE122, each with an expanded uncertainty (k = 2) of 0.6‰. These materials were produced to cover about three‐quarters of the known natural boron isotope variation. The ¹⁰B enriched isotope reference materials ERM‐AE102a and ERM‐AE104a were produced for industrial applications utilising ¹⁰B for neutron shielding purposes. The certified ¹⁰B isotope abundances are 0.29995 for ERM‐AE102a and 0.31488 for ERM‐AE104a with expanded uncertainties (k = 2) of 0.00027 and 0.00028, respectively. Together with the formerly certified ERM‐AE101 and ERM‐AE103 a unique set of four isotope reference materials and three offset δ¹¹B reference materials for boron isotope determination are now available from European Reference Materials.     

A multi-method approach to quantify groundwater/surface water-interactions in the semi-arid Hailiutu River basin,northwest China

Identification and quantification of groundwater and surface-water interactions provide important scientific insights for managing groundwater and surface-water conjunctively. This is especially relevant in semi-arid areas where groundwater is often the main source to feed river discharge and to maintain groundwater dependent ecosystems. Multiple field measurements were taken in the semi-arid Bulang sub-catchment, part of the Hailiutu River basin in northwest China, to identify and quantify groundwater and surface-water interactions. Measurements of groundwater levels and stream stages for a 1-year investigation period indicate continuous groundwater discharge to the river. Temperature measurements of stream water, streambed deposits at different depths, and groundwater confirm the upward flow of groundwater to the stream during all seasons. Results of a tracer-based hydrograph separation exercise reveal that, even during heavy rainfall events, groundwater contributes much more to the increased stream discharge than direct surface runoff. Spatially distributed groundwater seepage along the stream was estimated using mass balance equations with electrical conductivity measurements during a constant salt injection experiment. Calculated groundwater seepage rates showed surprisingly large spatial variations for a relatively homogeneous sandy aquifer.     

Petrogenesis of UHP metamorphic rocks from Qinglongshan, southern Sulu, east-central China

Five kinds of UHP metamorphic rocks, including eclogite, orthogneiss, paragneiss, schist and quartzite are exposed in the Qinglongshan roadcut, southern Sulu orogenic belt of eastern central China. They comprise metamorphic supracrustal rocks with bimodal volcanic characteristics and continental affinity, and granitic intrusive associations. The preservation of coesite inclusions and/or its pseudomorphs in eclogite and other rocks indicate that they have been subjected to in-situ UHP metamorphism. Four stages of metamorphism were recognized by combining petrographic observations and compositions of minerals from various UHP rocks. Prograde epidote-amphibolite facies, UHP coesite–eclogite facies, post UHP quartz–eclogite facies, and retrograde amphibolite facies assemblages delineate an inferred P–T path with a clockwise trajectory and a retrograde event characterized by the coupling of decompression with a temperature decrease. Garnet porphyroblasts in UHP eclogites display a complex growth zoning and mineral distribution, and record a crucial segment of the prograde and retrograde metamorphic evolution. The preservation of growth zoning in eclogitic and gneissic garnets suggests that the UHP rocks had a short residence time before retrograde metamorphism and a very high uplift rate in order to preserve the prograde growth zoning.     

Geology of the Niederlausitz Lignite district, Germany

One of the largest brown coal producing districts in the world is the Miocene of Niederlausitz Lignite area in the southeastern part of Germany. Production is in a range of 320 million t/yr. The resources of the first (shallowest) Miocene seam have nearly been exhausted and it is now mainly the second seam which is being mined. A fourth is being explored. The third Miocene and the Oligocene seam, Calau, are unminable. All brown coal is mined in open pits. The rank of brown coal of the second Miocene seam ranges from fuel coal to coking coal. Its heat value (dry) from 22.2 to 23.5 MJ, its ash content (dry) from 6% to 13%, its moisture from 57% to 59%, and its seam thickness from 10 to 12 m. Due to the close relationship between swamp facies and the main coal quality parameters, the coal quality can be directly determined from the drill log.The Oligocene and Miocene brown coal formation was synchronous with the alpine orogenesis and the seafloor spreading of the North Atlantic Ocean, which both caused north and east oriented migrations of the labile basement of central Europe. Periods of compression alternated with longer periods of isostatic subsidence and sedimentation. Additionally, the trends of thickness and facies of sediments were controlled by a block system in the basement of the brown coal district of Niederlausitz, uplifting, subsiding, collapsing, rotating or spreading.The second Lower Miocene seam is situated at sea level in the north of the Niederlausitz area and rises to the south to +150 to +180 m above sea level, due to considerable widespread subsidence and uplifting since the Lower Miocene. Horizontal tectonic movements were caused by the collapse of asymmetric grabens with slight tendency to rotation. Regional shear movements led to block faulting followed by volcanism. Counter-clockwise rotation of the basement blocks is assumed, a hypothesis supported by recent tension measurements and seismic observations. Ice cover in the Pleistocene caused wide destruction zones, narrow and deep channels and intensively folded or imbricated seam structures. Some gravity-induced plastic structures were also formed.