Geochemical and petrological constraints on rear-arc magma genesis processes in Ecuador: The Puyo cones and Mera lavas volcanic formations

The Puyo scoria cones and the Mera lava flows, two newly recognized volcanic formations dated between Late Pliocene to Middle Pleistocene, extend the limits of the Ecuadorian rear-arc volcanic province some 100 km to the south. The Puyo scoria cones have erupted K-rich absarokites containing olivine, diopside and phlogopite, whereas the Mera lava flows display a basic andesite composition, with olivine and minor augite phenocrysts. In addition to high contents in LILE, LREE and HFSE, the Puyo absarokites exhibit many characteristics of primitive melts, namely high Cr (590–310 ppm) and Ni (330–154 ppm) contents, high Mg# (64–70) and they contain forsteritic olivine (Fo_82–89). The composition of the most primary Puyo absarokite was used in petrogenetic models, in order to constrain the genesis of these high-K magmas. Major and trace elements models, as well as isotopic data, indicate that the source of Puyo magmas is a hydrated phlogopite- and garnet-bearing lherzolite. Phlogopite crystallization in the mantle wedge is triggered by the metasomatism by 3–5% of a SiO₂-, H₂O-rich liquid generated by slab melting. Partial melting of the subducted oceanic crust beneath Ecuador is allowed by the subduction of the young and warm Carnegie Ridge, which modifies the thermal regime of the Benioff zone. A low degree (1–4%) of partial melting of the metasomatized mantle wedge, leaving a variable garnet (4–7%) ± phlogopite (0–4%) lherzolitic residual assemblage, leads to the compositions of the entire Puyo absarokite series and is consistent with previous petrogenetic models developed for the Ecuadorian volcanic arc. Indeed, the homogeneity of isotopic data across the arc suggests a similar source for the whole Ecuadorian magmas.     

The effect of seismic uplift on the shell stresses of liquid‐storage tanks

Previous theoretical studies have shown that tank uplift, that is, separation of the tank base from the foundation, generally reduces the base shear and the base moment. However, there is a paucity of experimental investigations concerning the effect of uplift on the tank wall stresses, which is the principal parameter that controls the seismic design of liquid‐storage tanks. This paper reports a series of shake table experiments on a polyvinyl chloride model tank containing water. A comparison of the seismic behaviour of the tank with and without anchorage is described. Stochastically generated ground motions, based on a Japanese design spectrum, and three tank aspect ratios (liquid‐height/radius) are considered. Measurements were made of the stresses at the outer shell of the tank, the tank wall acceleration and the horizontal displacement at the top of the tank. While the top displacement and the tank shell acceleration increased when uplift was allowed, axial compressive stresses decreased by between 35% and 64% with tank uplift. The effect of uplift on the hoop stresses was variable depending on the aspect ratio. A comparison of experimental values with a numerical model is provided. Copyright © 2015 John Wiley & Sons, Ltd.     

Observable Effects of Interplanetary Coronal Mass Ejections on Ground Level Neutron Monitor Count Rates

In this work, non-recurrent Forbush decreases (FDs) triggered by the passage of shock-driving interplanetary coronal mass ejections (ICMEs) have been analyzed. Fifty-nine ICMEs have been studied, but only 25 % of them were associated to a FD. We find that shock-driving magnetic clouds (MCs) produce deeper FDs than shock-driving ejecta. This fact can be explained regarding the observed growing trends between decreases in neutron monitor (NM) count rate and MC/ejecta speed and its associated rigidity. MCs are faster and have higher associated rigidities than ejecta. Also the deceleration of ICMEs seems to be a cause for producing FDs, as can be inferred from the decreasing trend between NM count rate and deceleration. This probably implies that the interaction between the ICME traveling from the corona to the Earth and the solar wind can play an important role in producing deeper FDs. Finally, we conclude that ejecta without flux rope topology are the ones less effective in unchaining FDs.     

Source and genesis of sulphate and phosphate–sulphate minerals in a quartz‐sandstone cave environment

Gypsum (CaSO₄·2H₂O), alunite (KAl₃(SO₄)₂(OH)₆), and rare phosphate–sulphate sanjuanite Al₂(PO₄)(SO₄)(OH) 9(H₂O) and rossiantonite (Al₃(PO₄)(SO₄) 2(OH)₂(H₂O)₁₄) have recently been identified as secondary mineral deposits in different quartz‐sandstone caves in the Gran Sabana region, Venezuela. Due to the extended time scale required for speleogenesis in the hard and barely soluble quartz‐sandstone lithology, these caves are considered to be as old as 20 to 30 My. The study of these peculiar secondary mineral deposits potentially reveals important insights for understanding the interaction between deep, superficial and atmospheric processes over thousands to perhaps millions of years. In this study, chemical and petrographic analyses of potential host rock sources, sulphur and oxygen isotope ratios, and meteorological, hydrological and geographical data are used to investigate the origin of sulphates and phospho–sulphates. The results suggest that the deposition of sulphates in these caves is not linked to the quartz‐sandstone host rock. Rather, these mineral deposits originate from an external atmospheric sulphate source, with potential contributions of marine non‐sea salt sulphates, terrestrial dimethyl sulphide and microbially reduced H₂S from the forests or peatbogs within the watershed. Air currents within the caves are the most plausible means of transport for aerosols, driving the accumulation of sulphates and other secondary minerals in specific locations. Moreover, the studied sulphate minerals often co‐occur with silica speleothems of biological origin. Although this association would suggest a possible biogenic origin for the sulphates as well, direct evidence proving that microbes are involved in their formation is absent. Nonetheless, this study demonstrates that these quartz‐sandstone caves accumulate and preserve allogenic sulphates, playing a yet unrecognized role in the sulphur cycle of tropical environments.     

Gamma-Ray Data Processing and Integration for Lode-Au Deposits Exploration

A large number of mineral deposits are associated with hydrothermal processes, especially auriferous deposits. In such processes, studies on percolating fluids may indicate the presence of potash (K), among other elements. In this study, aerogammaspectrometric data-processing methodologies are evaluated, especially those methods based on the suppression of the primary contribution of potassium, the result of lithological and soil variations, and to environmental conditions. Resulting maps point out the contribution of hydrothermal K. This processing procedure was used because of the association of hydrothermal K and auriferous mineralizations according to the deposit model defined for the studied region. Intensity maps locate the areas with great influence of hydrothermal K. Data integration required to improve a change in the gammaspectrometric data processing in order to positively correlate hydrothermalised areas. Data integration could distinguish high and medium favorable targets for mineral exploration of lode-Au deposits in the studied region.     

Tidal and Nontidal Oscillations in Elkhorn Slough,CA

Elkhorn Slough is a shallow, tidally forced estuary that is directly connected to Monterey Bay. It is ebb-dominated and, due to continued erosion, the tidal prism has tripled over the past 40 years. Water level measurements at four locations are used to examine tidal and nontidal oscillations in Elkhorn Slough. The tidal response of Elkhorn Slough differs from that of Monterey Bay primarily due to the generation of a relatively large number of shallow-water tidal constituents that are due to tidal distortion caused by friction along the bottom and lateral boundaries, intertidal storage, and nonlinear advection. The shallow-water constituents range from 3 to almost 15 cycles per day (cpd) and include a rich variety of overtides and compound tides, whose amplitudes generally increase toward the head of the slough. The tidal harmonics are seasonally dependent, with lower amplitudes during the fall and winter and higher amplitudes in summer. The tidal constituents were examined using two types of spectral decomposition, the conventional power spectrum and the more recent Hilbert spectrum. Unlike the power spectrum, the Hilbert spectrum does not reveal any harmonic structure in the data. Energy associated with tidal distortion in this case appears to be broadly distributed across the spectral continuum. At least four nontidal oscillations occur in Elkhorn Slough with frequencies of 26.0, 39.7, 52.7, and 66.9 cpd. The Hilbert spectrum reveals maxima at 26, 39.7, and 66.9 cpd, but not at 52.7 cpd, suggesting that it is harmonically related to the oscillation at 26.0 cpd. The nontidal oscillations fall into the range of frequencies associated with the natural oscillations of Monterey Bay. However, evolutionary power spectra indicate that they appear to be permanent features of the system and thus are not necessarily consistent with seiche-like oscillations that are often transient and subject to damping. These oscillations could be caused by several factors including edge waves along the coast of Monterey Bay, long-period surface waves of atmospheric origin that enter the bay from offshore, or breaking internal waves in and around the Monterey Submarine Canyon. In conclusion, detailed hydrodynamic models are needed to provide a better understanding of how tidal harmonics are generated and preserved in Elkhorn Slough, and to determine the origin of the natural oscillations in Monterey Bay.     

Long-term TNT and DNT contamination: 1-D modeling of natural attenuation in the vadose zone: case study,Portugal

The vadose zone of a trinitrotoluene (TNT) and dinitrotoluene (DNT) contaminated site was investigated to assess the mobility of those explosives under natural conditions. Located in the left margin of the River Tejo Basin, Portugal, the site is located on unconsolidated sediments. Wastewaters associated with the 50-year explosives production were disposed in excavated ponds, from where water would infiltrate and pollute the unsaturated and saturated parts of the local aquifers. Two boreholes were drilled to 9 m depth in such a former waste pond to investigate the contaminant’s fate in the vadose zone. Sediment samples were taken every 1–2 m for analysis of the poly-nitroaromatics (p-NACs) and organic volatile compounds, pH, organic carbon content, cation exchange capacity and grain size analysis. The main contaminant was TNT representing >70 % of the total p-NACs concentration that peaked approximately 7 mg/kg in one borehole, even if the median in both boreholes was of ~1 mg/kg. DNT was 4–30 % of the total p-NACs and nitrotoluene (NT), up to 5 %. No other (volatile) organic compound was detected. The predominance of TNT as the main contaminant implies that any natural mass reduction has been inefficient to clean the site. Several 1-D model simulations of p-NACs cleaning of the vadose zone under natural conditions indicated that the most probable scenario of combined advection and partitioning will only remove TNT after 10’s of years, whereas DNT and NT will hardly be removed. Such low concentrations and long times for the p-NACs removal, suggest that by now those compounds have been washed-out to a level below standard limits.     

Benthic input rates predict seagrass (Posidonia oceanica) fish farm-induced decline

Fish farms represent a growing source of anthropogenic disturbance to benthic communities, and efficient predictors of such impacts are urgently needed. We explored the effects of fish farm benthic organic and nutrient inputs on the population dynamics of a key seagrass species (Posidonia oceanica) in four Mediterranean deep meadows adjacent to sea bream and sea bass farms. We performed two annual plant censuses on permanent plots at increasing distance from farms and measured benthic sedimentation rates around plots. High shoot mortality rates were recorded near the cages, up to 20 times greater than at control sites. Recruitment rates increased in variability but could not compensate mortality, leading to rapid seagrass decline within the first 100 m from cages. Seagrass mortality increased with total sedimentation rates (K=0.55, p<0.0002), and with organic matter (K=0.50, p=0.001), total nitrogen (K=0.46, p=0.002) and total phosphorus (K=0.56, p<3.10(-5)) inputs. P. oceanica decline accelerated above a phosphorus loading threshold of 50mg m(-2)day(-1). Phosphorus benthic sedimentation rate seems a powerful predictor of seagrass mortality from fish farming. Coupling direct measurements of benthic sedimentation rates with dynamics of key benthic species is proposed as an efficient strategy to predict fish farm impacts to benthic communities.     

Physical models of rifting and transform faulting, due to ridge push in a wedge-shaped oceanic lithosphere

By scaled physical modelling, we have investigated the mechanical response to gravitational forces in an oceanic lithosphere, overlying a less dense asthenosphere. In the models, an upper wedge-shaped layer of sand represented an oceanic lithosphere (0–35 Ma old, with a half-spreading velocity of 3 cm/yr), and a lower layer of polydimethylsiloxane (PDMS), mixed with dense wolframite powder, represented the asthenosphere. In the models, as in nature, isostatic compensation resulted in uplift of ridges and subsidence on their flanks. The resulting relief was responsible for ridge push. We tested two main configurations: straight ridges and offset ridges. In all the models, ridge push was sufficient to cause plate motion, underlying advection, and symmetrical rifting at the ridge axis. There was no need to impose plate motions through external pistons and motors. In models of straight ridges, the style of normal faults in the axial rift zone depended on the local thickness of the brittle sand layer. For thick layers, normal faults rafted out from the active zone of rifting, creating a fossil topography of tilted blocks, between faults dipping toward the ridge. In a model of an offset ridge, with thin lithosphere at the ridge crest and no embedded weakness, ridge push was responsible for a short transform fault, linking en-échelon rifts. In a similar model, but with thick lithosphere, an oblique rift formed at about 20° to the offset trace. We conclude that ridge push was not adequate to create an ideal transform fault. In a model of an offset ridge, with an embedded thin vertical layer of pure PDMS at 90° to the ridge, transform motion concentrated along this weak layer, and the resulting structural style was very similar to that in nature. On the basis of these results, we infer that, in nature, (1) ridge push can indeed drive plate motion, and (2) ridge push can drive strike-slip motion on transform faults, provided that these are weaker than the adjacent oceanic lithosphere and that they form early in the history of spreading.     

Short-term environmental impact of clam dredging in coastal waters (south of Portugal): chemical disturbance and subsequent recovery of seabed

The physical and chemical changes in sediment and near bottom water caused by clam dredging were examined during July and September 1999, at two locations Vilamoura (VL) and Armona (AR), south coast of Portugal. Sediment cores and near bottom water were collected simultaneously before dredging (control samples) and within short time intervals (min-h) after dredging. After dredging operations, microphytobenthos coming from the path were accumulated in the re-worked sediment (ridge). Chlorophyll a in superficial sediment increased from 1.2 microg x g(-1) before dredging to 1.7 microg x g(-1) after dredging and these higher values remained for a few hours. However, the expected increase of chlorophyll a in near bottom water due to re-suspension was not observed. After sediment disturbance an instantaneous sorption of phosphorus onto iron oxides occurred in the upper sediment layers (from 2 to 3 micromol x g(-1) before dredging to 4-5 micromol x g(-1) after dredging). A microcosm experiment showed that after sediment disturbance HPO(4)(2-) dissolved in pore water decreased from 40 to 10 microM being simultaneously sorbed onto iron oxides formed in the top layer of sediment. The ammonium, nitrates, organic nitrogen, phosphate and silicate dissolved in pore water decreased immediately after dredging activity and simultaneously an increase in near bottom water was sporadically observed. Generally, the re-establishment of seabed was reached within a short time (min-h), at both stations (VL and AR).