Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.     

Analysis of the precipitation and cloudiness associated with COLs occurrence in the Iberian Peninsula

Summary The Iberian Peninsula is one of the regions in the world with higher occurrence of cut-off low systems (COL). The aim of this paper is to analyse the weather events (rainfall and cloudiness layer) associated to COLs in the Iberian Peninsula with tools not previously used: (a) the use of the new multidecadal COLs database developed by Nieto et al (2005) that permit us to study a 41 years period (1958–1998), (b) the checking of the expected weather events (rainfall and cloudiness layer) associated with COLs in a conceptual model (Winkler et al, 2005) and (c) the extensive use of radiosoundings to analyse convective instability in areas inside and close to the COL. Two points of view are used to make the analysis: (1) a source oriented method, when a particular COL is followed and its associated precipitation and cloudiness is analysed over four quadrants in which Iberia was divided and (2) a receptor oriented method, when the precipitation associated to COLs is analysed in given areas, defined by patterns of precipitation. Results reveal that the precipitation and cloudiness patterns associated to COLs in the conceptual model reproduce quite well the main characteristics found over the Iberian Peninsula. The generalized idea that most of the COLs produce intense convective rainfall is show to be misleading. Convective phenomena are important usually when the centre of the COL is located on the Mediterranean region. Most of the rainfall associated with COLs comes from the baroclinic shield; specially in cases located over the west half of the Iberian Peninsula. It is shown that nearly 30% of COLs do not induce any rainfall; most of them located in the southern half of the Peninsula, and mainly during autumn. Only 30% of COLs produce generalized rainfall over the whole analysed territory, being most of them (about 90%) located over the western half of the Iberian Peninsula.     

EJECTION–COLLISION ORBITS AND INVARIANT PUNCTURED TORI IN A RESTRICTED FOUR‐BODY PROBLEM

We study the motion of an infinitesimal mass point under the gravitational action of three mass points of masses μ, 1–2μ and μ moving under Newton's gravitational law in circular periodic orbits around their center of masses. The three point masses form at any time a collinear central configuration. The body of mass 1–2μ is located at the center of mass. The paper has two main goals. First, to prove the existence of four transversal ejection–collision orbits, and second to show the existence of an uncountable number of invariant punctured tori. Both results are for a given large value of the Jacobi constant and for an arbitrary value of the mass parameter 0<μ≤1/2. This revised version was published online in July 2006 with corrections to the Cover Date.     

Focal mechanisms of small earthquakes in the southeastern Brazilian shield: a test of stress models of the South American plate

Focal mechanisms of small earthquakes with magnitudes of about 3 in the SE Brazilian shield are calculated using S / P amplitude ratios. Low attenuation ( Q _p from 400 to 800) in the shield upper-crustal layers allowed sharp S arrivals to be recorded up to distances of 100 km. Besides P -wave polarities, SH -wave first motions were also used to constrain the nodal-plane orientations. Normal and reverse faulting mechanisms with strike-slip components were found. The inversion of four mechanisms to estimate the stress tensor indicated a strike-slip stress regime with roughly E–W-orientated σ ₁ and N–S σ ₃. Both the orientations and the shape factor ( φ =0.7) of the inverted stress are in excellent agreement with theoretical predictions for that part of Brazil from the driving-force model of Coblentz & Richardson (1996) . Good agreement with the nature of the stress, as well as its orientation, was also found for the model of Meijer (1995) . Both of these theoretical models include spreading stresses along the continent/ocean lithospheric transition. Because the earthquakes are more than 300 km from the continental shelf they should not be affected by the local flexural forces caused by sediment load in the marginal basins. The agreement between observed and theoretical stresses then confirms the importance of continental spreading forces in modelling intraplate stresses.     

Coda Q before and after the eruptions of 13 November 1985, and 1 September 1989, at Nevado del Ruiz Volcano, Colombia

 Coda Q^–1 was calculated at Nevado del Ruiz Volcano (NRV) before and after two phreatomagmatic eruptions (November 1985, September 1989) and for a period of stability (May 1987) using a functional form for coda derived from a single scattering model (Sato 1977). Substantial changes were found before and after the eruptions. The highest value of Q^–1 was found during the November 1985 eruption, an intermediate value for the September 1989 eruption, and the lowest value for May 1987. It seems that the changes in coda Q^–1 at NRV have a still-unknown relationship with the volume or magnitude of the eruption. A relatively strong frequency dependence was found for all periods. Also Q^–1 clearly changed with time, suggesting that the scattering was strong for the eruption of November 1985 and decreased for the eruption of September 1989, and that the intrinsic absorption probably increased. This suggests the possibility that crystallization is taking place in the NRV magma. The clear change of coda Q^–1 before and after the eruptions at NRV also suggests the possibility that coda Q^–1 is a premonitory tool of activity at this volcano. Received: 25 October 1996 / Accepted: 21 January 1998     

Petrological And Geochemical Characteristics Of The Granulitic Terrain Of Brejses, Bahia, Brazil

New petrological and geochemical characteristics of the Brejtes region, situated in the south of Bahia, Brazil are discussed. The region forms a part of the most important and extensive granulite facies terrain in Brazil of Archean/Paleoproterozoic age. Five groups of rock types all equilibrated in the granulite facies are identified in this region. They are: i) supracrustal and related rocks, ii) undifferentiated granulites, iii) hornblende bearing enderbite-charnockites, iv) hornblende free enderbite-charnockites, v) charnockites. The first group appears to be the oldest in the region as they form enclaves in the 2.9 Ga old undifferentiated granulites. The third and fourth group are enderbite-charnockites, whose protoliths constitute two series of calc-alkaline rocks, one titanium poor (hornblende free) and another titanium rich (hornblende bearing). U/Pb zircon SHRIMP dates indicate ages of formation at 2.81 Ga (hornblende free) and 2.69 Ga (hornblende bearing) for the two groups. The fifth group of rocks have charnockitic affinity and are present in the center of the Brejtes Dome. These rocks are also have calc-alkaline affinity, but show petrographic and geochemical characteristics distinct from those of other groups. Preliminary geochronological investigations by zircon Pb-Pb evaporation method yielded 2.6 Ga and 2.0 Ga for the charnockites from the inner core of the Brejtes Dome. These age data suggest that the circular structure was formed by the re-fusion of the 2.6 Ga old deep crustal material generating younger charnockites at 2.0 Ga.     

A Note on Extension Variances in IR2

Matheron (1971) proposed an approximation of the extension variance in IR. We propose in this note an extension of this formula in IR ² , based on a MacLaurin formula. Its application is shown in an example, the estimation of the maximum depressional storage of a soil surface.     

Thermal alteration experiments on organic matter in recent marine sediment—II. Isoprenoids

Several isoprenoid compounds were isolated from a heat-treated marine sediment in the southern California continental shelf (from Tanner Basin) which were not present in the original sediment. Among the compounds identified were: phytol, dihydrophytol, C₁₈-isoprenoid ketone, phytanic and pristanic acids, C₁₉- and C₂₀-monoolefins, and the alkanes 2,6,10-trimethylpentadecane, pristane and phytane. The significance and possible routes leading to these compounds is discussed.