环境因子对菲在黄河口沉积物上吸附的影响

为研究多环芳烃从河口到近海的环境归趋行为与生态风险,考察了沉积物质量浓度、溶解性有机质、温度、盐度4种典型环境因子对菲在黄河口沉积物上吸附的影响,比较了黄河口与近海两种沉积物对菲的吸附性能。研究结果表明,沉积物质量浓度越低,单位质量颗粒物的菲吸附量越高;共存的溶解性有机质对菲的吸附具有增促作用,且腐殖酸比黄腐酸的作用更显著;温度的升高不利于菲的吸附,而盐度的增加有利于菲的吸附。菲在沉积物上的吸附是分配作用与表面吸附两种行为的耦合,其中黄河口沉积物以表面吸附为主,而近海沉积物以分配作用为主。近海沉积物菲吸附量显著高于黄河口沉积物菲吸附量。基于此,菲从河口到近海的迁移过程中,更易于在沉积物表面发生吸附沉降,从而可能降低水相中的生态危害,但对近海底栖生物具有潜在的健康生态风险。     

下扬子烃源岩新层位——中下奥陶统

中下奥陶统通常主要作为储层看待,然而皖南地区的下奥陶统宁国组主要为一套富含笔石的灰黑色—黑色薄层硅质、碳质泥岩,属广海陆棚相至深海盆地相沉积;而中奥陶统胡乐组主要为一套同样富含笔石的深灰色薄层粉砂质泥岩和中厚层硅质泥岩,属深海陆棚相至盆地相沉积。二者分布范围相当,但宁国组厚度明显大于胡乐组。下奥陶统宁国组6个样品的岩石热解数据显示,恢复后的TOC均值为1.24%。根据上升流的识别标准,宁国组和胡乐组的岩性和岩相特征以及宁国组地球化学测试结果,推测皖南地区中下奥陶统可能是一套受上升流影响的中—好烃源岩。鉴于南黄海是下扬子的主体,建议加强南黄海中下奥陶统烃源岩的研究。     

日本海天然气水合物气源成因及主控因素探讨

为了探讨日本海天然气水合物的气源成因及其控制因素, 收集和整理了日本海西南郁陵盆地和日本海东缘上越盆地及邻近的相关资料。结果显示,上越盆地及邻近海域甲烷羽状流、麻坑、自生碳酸盐岩及地震剖面上“气烟囱”和BSR等发育,块状水合物出露海底为热解成因;郁陵盆地羽状流不太发育,而自生碳酸盐岩和地震剖面上的“气烟囱”较发育,钻孔发现的水合物主要为生物成因。结合日本海构造演化特征综合分析认为,日本海东缘热解成因水合物的主控因素是近S—N向和近E—W向交互断裂作用以及NE—SW向的晚期构造挤压;日本海西南海域生物成因为主兼热解成因水合物的主控因素是NEE—SWW向的晚期构造挤压;而日本海西北海域构造定型早且缺少晚期构造挤压,因此,推测其水合物气源应该主要为生物成因,热成因的可能性很小。     

面向目标自适应三维大地电磁正演模拟

本文将面向目标的自适应算法应用于三维大地电磁数值模拟.使用基于非结构网格的矢量有限单元法对起伏地表大地电磁正演模拟问题进行求解.使用利用垂向电流密度在物性界面上的连续性对后验误差进行估算的算法指导网格优化.由于全局自适应算法针对观测点优化网格的能力较差,本文通过求解正演问题的对偶问题计算后验误差的加权系数,并对相关加权系数进行改进,从而实现了面向目标的自适应算法.与传统基于结构化网格的电磁正演算法相比,采用非结构网格能够更好地拟合起伏地表和地下不规则异常体.由于使用了面向目标的自适应算法,本文能够使用更少的网格达到较高的计算精度.通过对比本文模拟结果与半空间响应和全局自适应算法计算结果,并通过对比使用改进前和改进后加权系数得到的网格剖分结果验证了本文算法的有效性.

     

氧化还原条件对红枫湖沉积物磷释放影响的微尺度分析

选取贵州红枫湖为研究对象,在实验室条件下模拟了自然、好氧和厌氧条件下沉积物内源磷的释放过程,联合应用微电极技术和沉积物磷形态分析对沉积物—水界面开展了微尺度观测与研究.结果表明,厌氧条件下红枫湖沉积物总磷含量显著降低,且主要是NaOH提取态磷(NaOH-P)和残渣态磷(rest-P)含量降低所致,厌氧条件下沉积物孔隙水中磷酸盐浓度明显升高,而好氧条件下沉积物孔隙水磷酸盐浓度显著降低,反映厌氧条件显著促进了红枫湖沉积物磷释放.厌氧条件下沉积物内部溶解氧浓度下降、硫还原活动增强可能是导致NaOH-P释放的主要原因.O_2浓度的降低加速了沉积物还原作用并产生大量H2S,进而与二价铁离子形成硫化亚铁沉淀,最终导致NaOH-P(Fe-P)释放到孔隙水中.好氧条件向厌氧条件的转换可通过改变沉积物内部pH值分布和微生物活动促使rest-P释放:厌氧条件下,厌氧微生物不仅可以消耗硫酸根产生H_2S,导致pH值降低,还可消耗有机质,将有机磷转变为无机磷.上述研究结果表明,沉积物—水界面氧化还原环境可影响沉积物氧渗透深度、pH值分布、微生物活动、硫循环以及有机质降解过程,进而控制沉积物磷的形态转化与释放.联合应用微电极技术和沉积物磷形态分析对湖泊沉积物—水界面开展微尺度观测研究是揭示沉积物内源磷释放机制与控制因素的有效途径.     

考虑劣化屈服老化裂纹后混凝土水库堤坝排水边坡抗震性研究

针对在水库堤坝排水边坡混凝土裂纹的抗震性研究中,未考虑岩土体抗剪强度参数的劣化屈服效应以及混凝土裂纹的老化,存在抗震性判断结果准确率较差等问题,提出水库堤坝排水边坡混凝土考虑老化后产生裂纹的抗震性能研究方法。模拟强震下边坡混凝土的开裂破坏过程,根据D-P屈服准则,实现对闸墩混凝土材料的屈服判断。采用薄层整体单元模拟和分离式裂纹单元,实现混凝土裂纹的数值模拟,加载地震波后,获取混凝土裂纹的强震响应规律与破坏特征。实验结果可知,本文方法对坝体位移变化的研究精度高,得到的混凝土裂纹扩展范围更为准。运用本文方法对水库堤坝排水边坡混凝土的抗震性研究准确率以及可信度较高,说明本文方法具有一定的可取性。     

波动有限元方程显式逐步积分格式稳定性分析

对常用的波动有限元方程的两种显式格式的稳定性进行了分析,利用单元的最大频率乃是系统的特征频率的上界的概念结合模态分析方法,给出了便于实际应用的稳定性必要条件。同时,利用Von Neumann方法给出了这两种格式稳定性的充分条件,并通过算例对这两种稳定性条件进行验证。     

Seismic wavefield modeling based on time-domain symplectic and Fourier finite-difference method

Seismic wavefield modeling is important for improving seismic data processing and interpretation. Calculations of wavefield propagation are sometimes not stable when forward modeling of seismic wave uses large time steps for long times. Based on the Hamiltonian expression of the acoustic wave equation, we propose a structure-preserving method for seismic wavefield modeling by applying the symplectic finite-difference method on time grids and the Fourier finite-difference method on space grids to solve the acoustic wave equation. The proposed method is called the symplectic Fourier finite-difference (symplectic FFD) method, and offers high computational accuracy and improves the computational stability. Using acoustic approximation, we extend the method to anisotropic media. We discuss the calculations in the symplectic FFD method for seismic wavefield modeling of isotropic and anisotropic media, and use the BP salt model and BP TTI model to test the proposed method. The numerical examples suggest that the proposed method can be used in seismic modeling of strongly variable velocities, offering high computational accuracy and low numerical dispersion. The symplectic FFD method overcomes the residual qSV wave of seismic modeling in anisotropic media and maintains the stability of the wavefield propagation for large time steps.     

天然地震与人工爆破波形信号HHT特征提取和SVM识别研究

天然地震和人工爆破信号属于非线性非平稳信号,而传统信号分析方法是针对线性系统平稳信号的,本文采用希尔伯特—黄变换(Hilbert-Huang Transform,简称HHT)试图提取可明确区分天然地震和人工爆破事件的波形特征.通过经验模态分解(Empirical Mode Decomposition,简称EMD)把原信...     

Origin and Evolution of Aquitard Porewater in the Western Coastal Plain of Bohai Bay,China

High‐salinity paleowater from low‐permeability aquitards in coastal areas can be a major threat to groundwater resources; however, such water has rarely been studied. The chemical and isotopic compositions of porewater extracted from a 200‐m‐thick Quaternary sedimentary sequence in the western coastal plain of Bohai Bay, China, were analyzed to investigate the salinity origin and chemical evolution of porewater in aquitards. Porewater samples derived at depths shallower than 32 m are characterized by Cl‐Na type saline water (total dissolved solids [TDS], 10.9–84.3 g/L), whereas those at depths greater than 32 m comprise Cl·SO₄‐Na type brackish water (TDS, 2.2–6.3 g/L). Saline porewater is interpreted as evaporated seawater prior to halite saturation, as evidenced by Cl‐Br relationships. Although substantial dilution of saline porewater with meteoric water is supported by a wider Cl^? range and δ²H‐δ¹⁸O covariance, the original marine waters were not completely flushed out. The deeper brackish porewater is determined to be a mixture of fresher porewater and brine groundwater and had a component of old brine of less than 10%, as indicated by a mixing model defined using δ²H and Cl^? tracers. Porewater δ²H‐δ¹⁸O relationships and negative deuterium excess ranging from ?25.9‰ to ?2.9‰ indicate the existence of an arid climate since Late Pleistocene in Tianjin Plain. The aquitard porewaters were chemically modified through water‐rock interactions due to the long residence time.