Spatial variability of water vapor turbulent transfer within the boundary layer

Although the physics of evaporation within the inner region of the boundary layer is believed to be well understood, observations of mass-energy exchange processes have been hindered by the limitations of point sensors. A combination of point sensors and active remote sensing, namely, water-Raman Lidar measurements, offers new opportunities to study relatively large areas at temporal and spatial scales previously unattainable. Results from experiments over uniform canopies both confirm some traditional theories and challenge some of the underlying assumptions concerning the homogeneity of the surface-atmosphere interface and the use of point sensors to characterize large areas.This work was performed under the auspices of the U.S. Department of Energy. The authors would like to thank F. Archuleta, J. Archuleta, F. Barnes, W. Clements, K. Muller and W. Porch of LANL, R. Whitis of USDA, R. Jackson and P. Pinter of USDA-WCL, and L. Balick of EG&G for their invaluable time and support.     

Case Histories of Shallow Time Domain Electromagnetics in Environmental Site Assessment

Time domain electromagnetic (TDEM) soundings were utilized in site assessment studies for the purpose of accomplishing two objectives: (1) measuring the migration of brines from oil and gas field evaporation pits, and (2) mapping the continuity of clay strata. Both case histories are representative of common objectives in site assessment. The data for both examples were analyzed by one-dimensional ridge regression inversions.
Both case histories illustrate that TDEM is an effective method for determining the lateral and vertical resistivity distribution (geoelectric section) of the subsurface in the depth range from about 5 m to 100 m, and it is known from other investigations that depths of investigations up to 2500 m can be achieved with TDEM.
Frequently, the lateral extent of contaminant plumes emanating from localized sources are of limited areal extent. The case history involving the use of TDEM to map a brine plume shows that a TDEM measurement has a relatively small zone of influence, so that meaningful information about the lateral and vertical extent of the plume can be obtained. Both case histories demonstrate the ability of TDEM to determine geoelectric sections below layers of low resistivity.     

Monthly suspended sediment load prediction using artificial intelligence: testing of a new random subspace method

ABSTRACT

The predictive capability of a new artificial intelligence method, random subspace (RS), for the prediction of suspended sediment load in rivers was compared with commonly used methods: random forest (RF) and two support vector machine (SVM) models using a radial basis function kernel (SVM-RBF) and a normalized polynomial kernel (SVM-NPK). Using river discharge, rainfall and river stage data from the Haraz River, Iran, the results revealed: (a) the RS model provided a superior predictive accuracy (NSE = 0.83) to SVM-RBF (NSE = 0.80), SVM-NPK (NSE = 0.78) and RF (NSE = 0.68), corresponding to very good, good, satisfactory and unsatisfactory accuracies in load prediction; (b) the RBF kernel outperformed the NPK kernel; (c) the predictive capability was most sensitive to gamma and epsilon in SVM models, maximum depth of a tree and the number of features in RF models, classifier type, number of trees and subspace size in RS models; and (d) suspended sediment loads were most closely correlated with river discharge (PCC = 0.76). Overall, the results show that RS models have great potential in data poor watersheds, such as that studied here, to produce strong predictions of suspended load based on monthly records of river discharge, rainfall depth and river stage alone.     

Calibration of diatoms along a nutrient gradient in Florida Everglades Water Conservation Area-2A, USA

The relationship between diatom taxa preserved in surface soils and environmental variables at 31 sites in Water Conservation Area 2A (WCA-2A) of the Florida Everglades was explored using multivariate analyses. Surface soils were collected along a phosphorus (P) gradient and analyzed for diatoms, total P, % nitrogen (N), %carbon (C), calcium (Ca), and biogenic silica (BSi). Phosphorus varied from 315-1781 g g^-1, and was not found to be correlated with the other geochemical variables. Canonical correspondence analysis (CCA) was used to examine which environmental variables correlated most closely with the distributions in diatom taxa. Canonical correspondence analysis with forward selection, constrained and partial CCA, and Monte Carlo permutation tests of significance show the most significant changes in diatom assemblages along the P gradient (p < 0.01), with additional species differences correlated with soil C, N, Ca, and BSi.Weighted-averaging (WA) regression and calibration models of diatom assemblages to P and BSi were developed. The diatom-based inference model for soil [P] had a high apparent r² (0.86) with RMSE_boot = 218 g g^-1. Indicator diatom species identified by assessing species WA optima and WA tolerance to [P], such as Nitzschia amphibia and N. palea for high [P] (~1300-1400 g^-1) and Achnanthes minutissima var. scotica and Mastogloia smithii for low [P] (~400-600 g g^-1), may be useful as monitoring tools for eutrophication in WCA-2A as well as other areas of the Everglades. Diatom assemblages analyzed by cluster analysis were related to location within WCA-2A, and dominant taxa within clusters are discussed in relation to the geochemical variables measured as well as hydrology and pH. Diversity of diatom assemblages and a Disturbance Index based on diatom data are discussed in relation to the historically P-limited Everglades ecosystem. Diatom assemblages should be very useful for reconstructions of [P] through time in the Florida Everglades, provided diatoms are well preserved in soil cores.     

The transformation and export of phosphorus from Wetlands

There is widespread acceptance of the phosphorus retention capability of wetlands even though research findings are often inconclusive and contradictory. The results of a one year phosphorus budget study indicate that internal wetland processes may transform sediment bound phosphorus to plant available orthophosphorus. While total phosphorus imports were nearly double the total phosphorus exports for the study wetland, orthophosphorus exports were 22 per cent greater than imports. This study supports the recent finding that wetlands have limited capability to retain orthophosphorus and indicates that wetlands may even increase the export of orthophosphorus. The generally accepted nutrient retention function of wetlands and their possible role in eutrophication is thus questionable.     

Comparison of heat and bromide as ground water tracers near streams

Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present.     

Look out, aurorae about!

Jim Wild recounts the rationale and success of AuroraWatch, a service that alerts you when you might be able to see aurorae.