Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.     

Three‐dimensional gravity‐current flow within a subaqueous bend: Spatial evolution and force balance variations

The nature of three‐dimensional flow in submarine channel bends is poorly understood, largely due to the absence of detailed data from natural channels. Herein, data from density‐driven flows in a large reservoir on the Huanghe (Yellow) River are presented showing the spatio‐temporal variation of flow around a subaqueous bend. The data demonstrate for the first time that reversed helical flow, relative to that found in river channel bends, can occur from the centrifugal forcing of flow, even when the Coriolis force acts in the opposite direction. The data also suggest that reversed helical flow fields in submarine channels may be more frequent than currently estimated, notably for bends where Coriolis and centrifugal forces combine in the same direction. In addition, this study provides the first field evidence suggesting that sinuous submarine channels can exhibit an asymmetry in helical flow orientation between left and right‐turning bends, which will have major implications for the morphodynamics of submarine channels, their resultant patterns of sedimentation and, ultimately, the distribution of depositional units across submarine fan systems.     

Mixed-function oxygenases as biological monitors around petroleum hydrocarbon development sites: Potential for induction by diesel and other drilling mud base oils containing reduced levels of polycyclic aromatic hydrocarbons

The use of oil-based drilling muds has been discouraged in hydrocarbon exploration and production in the marine environment but these muds are presently being used to a considerable degree in the United Kingdom and Norwegian sectors of the North Sea. Field studies in the North Sea have demonstrated only localized impacts around individual drilling sites,^1,2 even including those sites where ‘toxic’ diesel oils were employed as base fluids in drilling muds. Yet the question of disposal of cuttings contaminated with oil from drilling muds remains somewhat controversial. The induction of mixed-function oxygenases (MFO) has been validated on a number of occasions in the field as a sensitive index of low level hydrocarbon exposure (reviewed by Payne),³ including sites in the North Sea where diesel-based muds were used.⁴ The present study demonstrates that any potential for induction by hydrocarbon contaminated cuttings will probably be reduced by substitution of low-aromatic base oils for diesel in drilling mud formulations.     

Differential signal of change among multiple components of West African rainfall

Theoretical and Applied Climatology - Rainfall components likely differ in the magnitude and direction of their long-term changes for any given location, and some rainfall components may carry a...     

Rapid magmatic processes accompany arc–continent collision: the Western Bismarck arc, Papua New Guinea

New U–Th–Ra, major and trace element, and Sr–Nd–Pb isotope data are presented for young lavas from the New Britain and Western Bismarck arcs in Papua New Guinea. New Britain is an oceanic arc, whereas the latter is the site of an arc–continent collision. Building on a recent study of the Manus Basin, contrasts between the two arcs are used to evaluate the processes and timescales of magma generation accompanying arc–continent collision and possible slab detachment. All three suites share many attributes characteristic of arc lavas that can be ascribed to the addition of a regionally uniform subduction component derived from the subducting altered oceanic crust and sediment followed by dynamic melting of the modified mantle. However, the Western Bismarck arc lavas diverge from the Pb isotope mixing array formed by the New Britain and the Manus Basin lavas toward elevated ²⁰⁸Pb/²⁰⁴Pb. We interpret this to reflect a second and subsequent addition of sediment melt at crustal depth during collision. ²³⁸U and ²²⁶Ra excesses are preserved in all of the lavas and are greatest in the Western Bismarck arc. High-Mg andesites with high Sr/Y ratios in the westernmost arc are attributed to recent shallow mantle flux melting at the slab edge. Data for two historical rhyolites are also presented. Although these rhyolites formed in quite different tectonic settings and display different geochemical and isotopic compositions, both formed from mafic parents within millennia.     

Emerging Asias: Transnational Forces,Developmental States,and “Asian Values”

Discussions of East Asian developmental states and Asian values discourse have been deformed by national-territorial frameworks that limit scholars' ability to highlight transnational phenomena. Such limits can be overcome by adopting a “Pacificist” perspective, one that highlights the transnational collaborative efforts of Pacific ruling class members, from both Asia and the United States. Such a Pacificist approach has the virtue of highlighting phenomena of transnational class formation that help account for the emergence of both developmental states in East Asia and Asian values discourse, and it also suggested the importance of attending to other kinds of emerging actors in Asian development politics, such as labor and democracy movements.     

Book Review of Accretion Power in Astrophysics (3rd Edition) by Juhan Frank,Andrew King,Derek Raine Cambridge University Press, 2002, XIV+384 pp., £27.95, hardback (ISBN 0 521 62053 8), paperback (ISBN 0 521 62957 8).

The velocity, pressure, perturbation magnetic field, helicity and electromotive force driven by an isolated buoyant parcel in an unbounded, rapidly rotating, electrically conducting fluid in the limit of small Elsasser number and very small Ekman number are calculated, visualized and analyzed. On the scale of the parcel, the solution is identical to that obtained in the limit of small Ekman number and zero Elsasser number. On the scale of the Taylor-column, it is elongated in the direction of the applied magnetic field and compressed in the direction perpendicular to it. The α-effect calculated by averaging the electromotive force on planes normal to rotation is strongly anisotropic: near the parcel and in the inner part of the Taylor-column it is strongest when the applied magnetic field is perpendicular to rotation and gravity; in the outer part of the Taylor-column it is strongest when the applied magnetic field is in the same plane as rotation and gravity.     

Hydrogeochemical methods for base metal exploration in the northern Canadian shield

The use of lake waters for base metal exploration has been studied in the northern part of the Slave Geological Province of the Canadian Shield. The area is north of the treeline, within the zone of continuous permafrost, and, like most other regions of the Shield, has a high density of small lakes.A regional sampling of 1218 lakes established that less than 2 ppb (μg/l) Zn or Cu is typical of waters from unmineralized terrane. These samples had a median pH of 6.8 and a median specific conductivity of 19.5 μmhos. Lake waters were also taken from the areas surrounding five massive sulphide occurrences: High Lake, Canoe Lake, Takiyuak Lake, Hackett River and Agricola Lake. In all cases there are unambiguous anomalies for Zn. Anomalies are also present for Cu, but are less intense and extensive. This difference between the two elements is related to the superior mobility of Zn in surface waters and its more consistent presence as a major constituent of massive sulphides.A water sampling apparatus has been developed and tested on a light turbine helicopter. Using this, thirty sites may be sampled each hour when sampling at a density of 1 site per 2.8 km². Measurement of pH, conductivity and water temperature are recorded in the helicopter during sampling.A number of factors have been investigated that may influence the utility of lake water sampling for base metal exploration:

1. (1) Seasonal variability, while present to moderate degree, is unlikely to hinder application of the method.

2. (2) For the size of lakes sampled (2 km² or less), elements are homogeneously distributed across the lake surface during the ice-free season. During the initial period of break-up there are marked variations in element content around the ice-free lake margin. Sampling during this period may help define the source of metals for anomalous lakes.

3. (3) Study of sample preservation suggests that mobile elements, such as Zn, that are stable in solution within lakes, are also relatively stable when untreated water is stored in plastic bottles.

4. (4) Care must be taken to avoid contamination of the samples, particularly from the bottle.

The areal extent of lake water base metal anomalies appears to be less than equivalent lake sediment anomalies. Thus for wide-interval, regional geochemical reconnaissance, lake sediment sampling is the method of choice. Lake waters are an appropriate medium for detailed exploration of areas of interest, such as volcanic belts. For this application, the principal attractions are rapid sampling rates, and hence low costs, high contrast anomalies, and a uniform sampling medium.     

Flood-tide Delta Morphological Change at the Gippsland Lakes Artificial Entrance,Australia (1889–2009)

Analysis of historical survey and navigation charts, aerial imagery, and digital hydro-data (representing a time-series of 1889–2009) allows the morphological evolution of a flood-tide delta at the artificial entrance to the Gippsland Lakes (Victoria, Australia) to be visualised and quantified. Analysis shows that flood-tide delta growth has imposed progressively greater demands upon port managers for publicly funded maintenance dredging. This flood-tide delta growth corresponds with a progressive diminution of Gippsland Lakes catchment river discharge volumes, and dampening of flow variability, due to both regional precipitation pattern changes and changes in catchment water resource allocation. Future climate change predictions for the Gippsland Lakes catchment and coastal area suggest both further decreases in catchment river discharge, and changing sediment flux along this sector of the Ninety Mile Beach. Thus, scope for flood-tide delta nourishment will probably increase, as will the demand for mitigation of the inevitable effects upon entrance channel navigability. Information derived from the analysis of time-series bathymetry used for this study offers baseline information in support of stakeholder consensus building regarding options for maintaining navigability. Analysis points to the merit of considering (and testing via morphological modelling) alternative options for navigation channel maintenance than those in present practice. We argue that the circumstances prevailing at the artificial entrance call for consideration of engineered configuration changes practised elsewhere by entrance managers faced with similar issues.     

Book reviews

Climate change in contrasting river basins: adaptation strategies for water, food and environment. Edited by J Aerts and P Droogers. Published in 2004 by CABI Publishing, 288 p., hardcover. ISBN: 0–85199–835–6. Price: US$100 (orders: services@dadirect.com.au).

Australian water bugs. Their biology and identification (Hemiptera‐Heteroptera, Gerromorpha &; Nepomorpha). By Nils M Andersen? and Tom A Weir. Published in 2004 by CSIRO Publishing/Apollo Books, P.O. Box 1139, Collingwood, VIC 3066, Australia. 344 p., hardcover. ISBN: 0–643–090517. Price: AU$135.00 (orders: publishing.sales@csiro.au).

The Lakes Handbook. Volume I: Limnology and Limnetic Ecology. Volume II: Lake restoration and rehabilitation. Edited by Patrick O'Sullivan and Colin Reynolds. Published by Blackwell Publishing Ltd., 109 Cowley Road, Oxford OX4 1JF, United Kingdom (http//www.blackwellpublishing.com). Volume I (published in 2003) 712 p., hardcover. ISBN: 0632047976. Price: £125. Volume II (published in 2004) 568 p., hardcover. ISBN: 063204795X. Price: £125.