层序古地理背景下河南省二_1煤聚集规律研究

对河南省晚石炭世-早二叠世含煤岩系(太原组中部碎屑岩段、上部灰岩段和山西组二1煤层段、大占砂岩段)进行层序分析,共识别出以胡石砂岩底面、二1煤底面、大占砂岩底面和香炭砂岩底面为代表的4个层序界面,将该层段含煤岩系划分为3个三级层序。通过对层序S1和层序S3岩相古地理图和二1煤厚度等值线图耦合分析发现,障壁岛-潟湖沉积环境为二1煤的聚集提供一个较好的前期环境,分流间湾沉积环境为二1煤的保存提供一个较好的后期环境,而分流河道对二1煤的保存起到了破坏性的作用。     

河南泌阳凹陷新生代天文地层研究

为油气成烃成藏定量研究,特别为油田剥蚀量的计算,需要建立新生代天文地层年代表。该表的数据是立足于天文学"米氏旋回假说"中地球轨道三要素的周期性和准周期性变化,求出各组(段或亚段)地质年龄。计算方法是选定泌阳凹陷11口井从大仓房组至凤凰镇组的地层分层、测井曲线数据等作频谱分析,寻找响应0.405Myr周期中的最大优势旋回和提出的三个‘基准面'的绝对年龄值。研究和计算的最后成果年龄为:1)大仓房组‘红层'顶/核三4亚段底是以邻近渤海湾盆地东营凹陷沙四下亚段‘红层'顶42.671Ma作为年龄对比和标定,向上计算出核三3亚段底为40.951Ma、核三3～1亚段顶为36.490Ma,核二段的顶为34.845Ma;2)廖庄组底/核一段之间是以邻近渤海湾盆地东营凹陷东营组底32Ma计算的数据作对比和标定,向下计算出核一段底的年龄为34.468Ma,核二段/核一段之间可能为一个大约时长为0.4Myr的小剥蚀面;向上计算廖庄组现有顶平均年龄为26.811Ma,即泌阳凹陷廖庄组全沉积的顶在中新世23.03Ma,地质构造上升和沉积回剥时间平均为3.781Myr;3)平原组底界的年龄标定为目前"国际地层表"(2004)中年龄为2.588Ma,向下计算出凤凰镇组底界平均年龄为4.155Ma。     

1668年郯城8 1/2 级地震构造应力场分析

1668年郯城8 1/2 级地震,发震断层南起郯城窑上北到莒县土岭,全长为130 km,由5条北北东走向的活断层段组成。郯城地震断层南段沿沂沭断裂带内的F₂断裂分布,倾向南东东,倾角为30°～60°。北段紧邻F₁断裂分布,倾向不稳定,倾角较陡(多为70°以上)。南段表现为右行逆冲或逆右行的运动性质,北段则以右行走滑为主。郯城地震断层南、北两段均发育断层泥带、断层角砾带和碎裂带,南段总宽度为几米到十几米,北段总宽度为几十米到近百米,局部发育多条断层泥带。郯城地震断层的排列方式及其几何学特征表明:为老断层复活,而非新生断层。通过断层擦痕的反演同震应力场显示:北段为北东东-南西西向挤压应力场,南段为北东-南西向的挤压应力场,该地震是发生在区域性挤压应力场状态下。这种应力场空间变化可能是地震断层几何学空间变化导致的。其同震应力场与该地区现代区域应力场是一致的,这说明郯城地震并未造成震后应力场调整或震后应力场调整时间较短,未影响到现今应力场。     

滨里海盆地东缘石炭系KT-Ⅰ油层组白云岩地球化学特征

哈萨克斯坦滨里海盆地东缘上石炭统KT-Ⅰ油层组主要发育局限海台地-开阔海台地碳酸盐沉积,间夹蒸发岩层。由于区域性白云石化作用,KT-Ⅰ油层组中白云岩广泛分布,为主要油气储集层。研究表明,白云岩中白云石为泥晶、粉晶或细晶,半自形-他形;略富钙,有序度较低(0.336～0.504);δ¹⁸O_PDB值在-1.06‰～+2.45‰之间,比石炭纪海水(δ¹⁸O_PDB值介于-1‰～-2‰之间)偏正;δ¹³C_PDB值在+3.36‰～+5.94‰之间,与石炭纪海水(δ¹³C_PDB值介于+3.1‰～+4.7‰之间)接近;锶同位素值接近石炭纪海水(⁸⁷Sr/⁸⁶Sr值在0.7082～0.7088之间);微量元素Mn含量平均为92.57 μg/g,Fe含量平均为447.52 μg/g,接近被交代的灰岩含量;Na和K含量的平均值分别为198.80 μg/g 和5.89 μg/g,显示交代流体为蒸发海水。上述岩石学和地球化学资料表明,研究区石炭系KT-Ⅰ油层组白云岩具有渗透-回流机理白云岩的特征。     

Mantle metasomatism and generation of Early Permian ultramafic rocks in northern North China CratonSCIEI北大核心CSCD

华北克拉通北部高寺台晚古生代环状杂岩体是一套富单斜辉石的超镁铁质岩,是研究华北北部地幔碳酸盐化熔体交代作用的理想对象,同时也是华北克拉通北部晚古生代岩浆活动与深部碳循环联系的纽带。作者在岩体西部边缘识别出一套早二叠世早期富铁角闪单斜辉石岩,形成时代为297.8±3.4Ma。结合岩体东部辉石岩早泥盆世和早石炭世的成岩年龄,表明高寺台超镁铁质杂岩体可能是晚古生代多期岩浆侵位的产物。其次,高寺台环状超镁铁质杂岩体缺少大面积辉长岩和闪长岩、硫化物和Cu-Ni-PGE矿化,单斜辉石成分具有裂谷带堆晶岩矿物特征,角闪石也具有相对低的结晶温度(933~947℃)和压力(287~323MPa)及水含量(4.06%~5.10%),而且区域上尚未发现同期环状杂岩体和蛇绿岩,与岛弧拼贴到陆块后沿俯冲带延伸数万米侵位的阿拉斯加型环状杂岩体明显不同。另外,前人的研究显示,与铬铁矿中富镁单斜辉石包裹体平衡的苦橄质母岩浆显示出OIB的特征,具有强烈的重稀土分馏、富Nb和高Nb/La,异常高的Ca/Al和(La/Yb)N,低的Ti/Eu、Zr/Sm和Hf/Sm,这些特征都表明苦橄质母岩浆起源于石榴石相软流圈地幔,且源区遭受过显著的碳酸盐熔体交代。单斜辉石岩中单斜辉石及角闪石成分及其平衡岩浆成分记录了母岩浆与岩石圈地幔相互作用后的岩浆演化过程,也显示出比母岩浆弱的源区碳酸盐熔体交代印记。此外,岩浆房在地壳浅部经历了多期深部岩浆补给和富铁熔体贯入,同时带来热量和挥发分,触发晶粥体活化,促进了岩浆的上升运移。高寺台环状超镁铁质杂岩体具有板内成因特征,可能是陆内岩石圈伸展的产物。华北克拉通北部晚石炭世-早二叠世三个岩浆事件峰期很好地对应着全球三次升温和CO_(2)回升事件,岩石圈伸展能有效促进强烈的中酸性岩浆活动及起源于碳酸盐化地幔的基性岩浆释放出大量的CO_(2),它们可能是晚石炭末期-早二叠世早期全球大气CO_(2)回升的贡献者之一。     

广东二叠纪动物群的古生态

广东二叠纪地层分布广泛,尤以粤北、粤东、粤西北发育最好,也是广东的主要含煤地层。二叠纪动物群繁盛,大量的动物化石大多采自泥岩和灰岩,计有138属421种,主要包括（?）、腕足、双壳类、头足类和牙形刺等。根据动物的生态特征、分布状况以及沉积环境,广东二叠纪古生物地理区可分成连阳区和粤北-粤东-粤中区,同时依照不同的年代、不同的地区有12个动物群。这些动物群总属于浅海相和海陆交互相的古生态环境。      

Mixture of populations

A simple example simulating a mixture of two normal populations results in some important observations, nonnormality and nonsymmetry of the mixture conditional pdf, nonlinearity of the conditional mean as a function of the conditioning data, heteroscedasticity of the conditional variance and its nonmonotonicity as a function of distance of the unknown to the conditioning data. A comparison of the mixture statistics with those predicted by traditional models ignoring the mixture reveals the inadequacy and inappropriateness of these traditional approaches. A mixture of two multivariate normal populations is illustrated through the analytical expressions of its conditional distribution and moments.     

New Attempt to Reduce the Harm of Smoking: Reducing the Nitrosamines Level in Tobacco Smoke by Microwave Irradiation

In order to protect the environment and public health, microwave irradiation was investigated as a means of reducing the nitrosamines level of tobacco smoke under mild conditions where the microwave energy was 1 kW and the irradiation time was shorter than 2 min. The microwave‐induced elimination of nitrosamines such as N‐nitrosopyrrolidine (NPYR) and N‐nitrosodiphenylamine (NDPA) was investigated and the impact of the presence of water and salt in the medium on the reduction was assessed in detail. The existence of water in the medium was crucial for the microwave‐induced reduction of NDPA, because the rapid movement of water molecules under the influence of microwaves strongly affects the adjacent nitrosamines leading to their decomposition. This was the first time that microwaves have been used to directly irradiate cigarettes sealed in their packaging, and the nitrosamines content of tobacco and smoke of these irradiated cigarettes were analyzed with care. Irradiation for 90 s with microwave energy of 1kW was seen to reduce 25 to 30% of the nitrosamines in tobacco and 50 to 60% of the levels present in the mainstream smoke of the cigarette. Moreover, lower mutagenic activity and higher CHO cell livability were found for the irradiated cigarettes in comparison with the control according to the results of in vitro tests.     

Removal of Ni(II) from Aqueous Solutions by Nanoscale Magnetite

Magnetite nanoparticles were applied to remove Ni(II) from aqueous solutions as a function of pH, contact time, supporting electrolyte concentration, and analytical initial Ni(II) concentration. The highly crystalline nature of the magnetite structure with diameter of around 10 nm was characterized with transmission electron microscopy (TEM) and X‐ray diffractometry (XRD). The surface area was determined to be 115.3 m²/g. Surface chemical properties of magnetite at 25°C in aqueous suspensions were investigated. The point of zero charge (pHzpc) was found to be 7.33 and the intrinsic acidity constants (${\rm p}K_{{\rm a}1}^{{\rm s}} $ and ${\rm p}K_{{\rm a}2}^{{\rm s}} $ ) were found to be 9.3 and 5.9, respectively. The surface functional groups were investigated with Fourier transform‐infrared spectroscopy (FTIR) as well. Batch experiments were carried out to determine the adsorption kinetics and mechanism of Ni(II) by these magnetite nanoparticles. The adsorption process was found to be pH dependent. In NaCl solutions, Ni(II) adsorption increased with increasing ionic strength while in NaClO₄ solutions, Ni(II) adsorption exhibited little dependence on the ionic strength of the solution. The adsorption process better followed the pseudo‐second order equation and Freundlich isotherm.     

多层基础隔震房屋结构在水平地震力作用下的振动传递

文章将周期结构原理与导纳方法结合起来，分析了带复合结构单元的有阻尼的有限周期系统的波传播和振动特性，得到了有限周期结构自振频率的一般表达式。