Upper Cretaceous bottom current deposits,north-east Greenland

Reported ancient bottom current deposits in deep marine settings are scarce and most of them remain contentious. This study describes sedimentological, ichnological and petrographical characteristics of a drill core that covers ca 10 Myr of Upper Cretaceous stratigraphy at Hold with Hope, north-east Greenland. The core is divided into four facies associations, which are interpreted to reflect deposition from bottom currents, turbidity flows and hemipelagic settling in slope and/or near slope environments. The evidence for bottom current influence is three-fold. Firstly, pervasive indications of winnowing such as marine bioclast-rich lags and outsized clasts on ‘mud on mud’ contacts are suggestive of low-sediment concentration flows capable of transporting up to pebble-sized clasts. Common Mn–Fe–Mg rich carbonate matrix cements and various types of hiatal chemogenic lag deposits showing glauconite, apatite and carbonate clasts also point to condensation, prolonged exposure at the sediment–water interface and recurrent phases of sea-floor erosion. Secondly, such deposits can show indicators for tidal processes such as double mud-drapes, tangential bottom sets in dune-scale cross-bedding and cyclic rhythmites. Thirdly, inverse to normal grading at various scales is common in fully marine, commonly seafloor-derived sediments. Ichnological data indicate considerable taxonomic variability in the bottom current deposits, but recurrent fabrics are characteristically dominated by morphologically simple burrows such as Thalassinoides and Planolites, with secondary Phycosiphon, Nereites, Zoophycos and/or Chondrites. In general, opportunistic taxa are common whereas mature composite ichnofabrics are rare. The omission surfaces are locally burrowed with stiffground to firmground trace fossil suites. The results contribute to establishing sedimentological, ichnological and mineralogical criteria for recognition of bottom current deposits as well as to the understanding of the Late Cretaceous palaeoenvironmental evolution of the Arctic region.     

Phase acceleration: a new important parameter in GPS occultation technology

Based on 40 years of radio-occultation (RO) experiments, it is now recognized that the phase acceleration of radio waves (equal to the time derivative of the Doppler shift), derived from analysis of high-stability Global Positioning System (GPS) RO signals, is as important as the Doppler frequency. The phase acceleration technique allows one to convert the phase and Doppler frequency changes into refractive attenuation variations. From such derived refractive attenuation and amplitude data, one can estimate the integral absorption of radio waves. This is important for future RO missions when measuring water vapor and minor atmospheric gas constituents, because the difficulty of removing the refractive attenuation effect from the amplitude data can be avoided. The phase acceleration technique can be applied also for determining the location and inclination of sharp layered plasma structures (including sporadic E _s layers) in the ionosphere. The advantages of the phase acceleration technique are validated by analyzing RO data from the Challenging Minisatellite Payload (CHAMP) and the FORMOSA Satellite Constellation Observing Systems for Meteorology, Ionosphere, and Climate missions (FORMOSAT-3/COSMIC).     

Resurge gullies and “inverted sombrero” morphology,Flynn Creek impact structure,Tennessee

The Flynn Creek impact structure is an approximately 3.8 km diameter, marine‐target impact structure, which is located in north central Tennessee, USA. The target stratigraphy consists of several hundreds of meters of Ordovician carbonate strata, specifically Knox Group through Catheys‐Leipers Formation. Like other, similarly sized marine‐target impact craters, Flynn Creek's crater moat‐filling deposits include, in stratigraphic order, gravity‐driven slump material, aqueous resurge deposits, and secular (postimpact) aqueous settling deposits. In the present study, we show that Flynn Creek also possesses previously undescribed erosional resurge gullies and an annular, sloping surface that comprises an outer crater rim surrounding an inner, nested bowl‐shaped crater, thus forming a concentric crater structure. Considering this morphology, the Flynn Creek impact structure has a crater shape that has been referred to at other craters as an “inverted sombrero.” In this paper, we describe the annular rim and the inner crater at Flynn Creek using geographic information system technology. We relate these geomorphic features to the marine environment of crater formation, and compare the Flynn Creek impact structure with other marine‐target impact structures having similar features.     

Shocked quartz grains in the early Cambrian Vakkejokk Breccia,Sweden—Evidence of a marine impact

Here we present a study of the abundance and orientation of planar deformation features (PDFs) in the Vakkejokk Breccia, a proposed lower Cambrian impact ejecta layer in the North‐Swedish Caledonides. The presence of PDFs is widely accepted as evidence for shock metamorphism associated with cosmic impact events and their presence confirms that the Vakkejokk Breccia is indeed the result of an impact. The breccia has previously been divided into four lithological subunits (from bottom to top), viz. lower polymict breccia (LPB), graded polymict breccia (GPB), top sandstone (TS), and top conglomerate (TC). Here we show that the LPB contains no shock metamorphic features, indicating that the material derives from just outside of the crater and represents low‐shock semi‐autochthonous bombarded strata. In the overlying, more fine‐grained GPB and TS, quartz grains with PDFs are relatively abundant (2–5% of the grain population), and with higher shock levels in the upper parts, suggesting that they have formed by reworking of more distal ejecta by resurge of water toward the crater in a marine setting. The absence of shocked quartz grains in the TC indicates that this unit represents later slumps associated with weathering and erosion of the protruding crater rim. Sparse shocked quartz grains (<0.2%) were also found in sandstone beds occurring at the same stratigraphic level as the Vakkejokk Breccia 15–20 km from the inferred crater site. It is currently unresolved whether the sandstone at these distal sites is related to the impact or just contains rare reworked quartz grains with PDFs.     

Validation of automated supervised segmentation of multibeam backscatter data from the Chatham Rise,New Zealand

Using automated supervised segmentation of multibeam backscatter data to delineate seafloor substrates is a relatively novel technique. Low-frequency multibeam echosounders (MBES), such as the 12-kHz EM120, present particular difficulties since the signal can penetrate several metres into the seafloor, depending on substrate type. We present a case study illustrating how a non-targeted dataset may be used to derive information from multibeam backscatter data regarding distribution of substrate types. The results allow us to assess limitations associated with low frequency MBES where sub-bottom layering is present, and test the accuracy of automated supervised segmentation performed using SonarScope® software. This is done through comparison of predicted and observed substrate from backscatter facies-derived classes and substrate data, reinforced using quantitative statistical analysis based on a confusion matrix. We use sediment samples, video transects and sub-bottom profiles acquired on the Chatham Rise, east of New Zealand. Inferences on the substrate types are made using the Generic Seafloor Acoustic Backscatter (GSAB) model, and the extents of the backscatter classes are delineated by automated supervised segmentation. Correlating substrate data to backscatter classes revealed that backscatter amplitude may correspond to lithologies up to 4 m below the seafloor. Our results emphasise several issues related to substrate characterisation using backscatter classification, primarily because the GSAB model does not only relate to grain size and roughness properties of substrate, but also accounts for other parameters that influence backscatter. Better understanding these limitations allows us to derive first-order interpretations of sediment properties from automated supervised segmentation.     

Changes in physical properties of a reservoir sandstone as a function of burial depth – The Etive Formation,northern North Sea

Rock physical properties, like velocity and bulk density, change as a response to compaction processes in sedimentary basins. In this study it is shown that the velocity and density in a well defined lithology, the shallow marine Etive Formation from the northern North Sea increase with depth as a function of mechanical compaction and quartz cementation. Physical properties from well logs combined with experimental compaction and petrographic analysis of core samples shows that mechanical compaction is the dominant process at shallow depth while quartz cementation dominates as temperatures are increased during burial. At shallow depths (<2000–2500 m, 70–80 °C) the log derived velocities and densities show good agreement with results from experimental compaction of loose Etive sand indicating that effective stress control compaction at these depths/temperatures. This indicates that results from experimental compaction can be used to predict reservoir properties at burial depths corresponding to mechanical compaction. A break in the velocity/depth gradient from about 2000 m correlates with the onset of incipient quartz cementation observed from petrographic data. The gradient change is caused by a rapid grain framework stiffening due to only small amounts of quartz cement at grain contacts. At temperatures higher than 70–80 °C (2000–2500 m) the velocities show a strong correlation with quartz cement amounts. Porosity reduction continues after the onset of quartz cementation showing that sandstone diagenesis is insensitive to effective stress at temperatures higher than 70–80 °C. The quartz cement is mainly sourced from dissolution at stylolites reflected by the fact that no general decrease in intergranular volume (IGV) is observed with increasing burial depth. The IGV at the end of mechanical compaction will be important for the subsequent diagenetic development. This study demonstrates that mechanical compaction and quartz cementation is fundamentally different and this needs to be taken into consideration when analyzing a potential reservoir sandstone such as the Etive Formation.     

Quartz cementation in Late Cretaceous mudstones,northern North Sea: Changes in rock properties due to dissolution of smectite and precipitation of micro-quartz crystals

Late Cretaceous mudstones from two wells located in the northern North Sea and the Norwegian Sea have been examined with respect to quartz cement. Two different types of quartz cement (Type 1 and Type 2) have been identified using SEM/EDS/CL-analysis of drill-bit cuttings at depths 2370–2670 m (80–85 °C). Type 1 appears as relatively large aggregates (30–100 μm) of depth/temperature related crypto- or microcrystalline to macrocrystalline irregular quartz cement formed by local re-crystallization of biogenic silica. The CL-responses of Type 1 quartz cement give a clear indication of an authigenic origin. Type 2 quartz cement represents relatively high amounts of extremely fine-grained micro-sized (1–3 μm) crystals embedded as discrete, short chains or small clusters/nests within the illitized clay matrix. The CL-responses of micro-quartz crystals indicate an authigenic origin. The micro-quartz is most probably sourced from silica released during the smectite to illite dissolution–precipitation reaction. The petrographic evidence indicates that most of the silica released by the smectite to illite reaction has not been exported out of the mudstones. The silica released produce a subtle inter-connected micro-quartz network interlocked with aggregates of micro-quartz and authigenic clay crystals. This micro-quartz cementation process causes a significant and sharp change in the mudstone stiffness at the onset of the chemical compaction regime. This is indicated by an abrupt increase in well log velocity (Vp) and change in seismic facies close to 2500 m (80/85 °C).     

Determination of Trace Elements in the Quartz Reference Material UNS-SpS and in Natural Quartz Samples by ICP-MS

A procedure for the digestion and analysis of quartz samples was developed to measure trace element concentrations in natural quartz. The certified glass sand reference material UNS-SpS was chosen to assess the precision, accuracy and detection limit of the analytical method. Quartz was digested with HF/HNO₃ in a closed glassy carbon vessel and analysed by means of quadrupole ICP-MS with external calibration. Analyte concentrations of the sand UNS-SpS were compared with certified and other values from the literature. The abundances of a number of elements (Pr, Gd, Ho and Er) in the reference material are reported here for the first time. The procedure was then applied to three quartz samples from different geological settings to show that trace element data by ICP-MS can distinguish the origin of the sample.     

High resolution climate simulations over the Arctic

The regional atmospheric climate model HIRHAM has been applied to the Arctic. Simulations for the whole year 1990 and for an ensemble of winter months (January of 1985-1995) have been performed. The comparison of the simulations with observational data analyses shows that the general spatial patterns are in good agreement with the data, in both the vertical structure and the annual cycle. For an additional validation of the model results, a multivariate classification of large-scale circulation patterns has been applied to the January ensemble model simulations.     

Cenomanian oysters from the Sergipe Basin, Brazil

Cenomanian (mid Cretaceous) oysters from the Sergipe Basin in northeastern Brazil are described, with revisions of previously described forms. Nine genera and subgenera, including eleven species, are distinguished: Rastellum diluvianum (Linné, 1767), Amphidonte (Ceratostreon) reticulata (Reuss, 1846), A. (Ceratostreon) flabellata (Goldfuss, 1833), Exogyra (Costagyra) olisiponensis Sharpe, 1850, Ilymatogyra (Afrogyra) africana (Lamarck, 1801), Rhynchostreon (Rhynchostreon)mermeti (Coquand, 1862), R. (Laevigyra) obliquatum (Pulteney, 1813), R. (Laevigyra) sp., Pycnodonte (Phygraea) vesiculosa (J. Sowerby, 1823), Curvostrea rouvillei (Coquand, 1862) and Ambigostrea sp. No undoubted Turonian oysters are known from Sergipe, althoughR. (R.) mermeti possibly straddles the Cenomanian–Turonian boundary. This is in sharp contrast with the situation in the more northerly Brazilian basins, from where several Turonian but no Cenomanian forms have been described. Well-preserved material from Sergipe confirms the close relationship between Exogyra (Costagyra) Vialov andVultogryphaea Vialov. The palaeobiogeographical affinity of the oyster fauna is typically Tethyan with many taxa that are known particularly from the southern Tethys. The inferred palaeoenvironment as implied by the oysters is that of a shallow shelf.