Evolution of the fogwater composition in Strasbourg (France) from 1990 to 1999

The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO_2(g) and the resulting SO₄²⁻. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.     

Analysis of Post-Failure Slope Movements within the Framework of Hazard and Risk Analysis

The paper first recalls briefly a methodological framework to assess landslide hazard and risk analysis in terms of predisposition, triggering andrevealing factors. This framework, that reflects the mechanisms involved in the landslide, is based on the Geotechnical Characterisation of slope movements proposed by Vaunat et al. (1994) and Leroueil et al. (1996). The Geotechnical Characterisation can be schematized by a 3-D matrix having the following axes: types of movement; types ofmaterial; and the four stages of movement: pre-failure, failure, post-failure andreactivation. For each relevant element of this 3-D matrix, there is a characterisationsheet including: the controlling laws and parameters, the predisposition factors, thetriggering or aggravating factors, the revealing factors and the consequences of the movement. The paper focuses afterwards on the post-failure stage, which generallyis the most destructive, and on the mobility index. It is shown that this laterindex can be described as the product of sub-indices associated with failure, brittlenessof the material, ability of the soil to develop pore pressures, geometry of the moving soil mass and characteristics of the terrain. It is also shown how these aspectscan be incorporated into the Geotechnical characterisation of slope movements. This seems to provide a rational basis for examining slope movements at the post-failure stage and assessing associated risks.     

Stability of earthquake moment tensor inversions: effect of the double-couple constraint

We show that spurious large non-double-couple components can be obtained in inversions for the full deviatoric moment tensor for shallow crustal earthquakes due to inaccurate Earth models. The traditional “best double-couple” solution does not in general provide an optimal estimate of a double-couple mechanism, and is only reliable when the non-double-couple component of the full deviatoric solution is small. The inverse problem for the moment tensors of the 1998 Antarctic Plate and 2000 Wharton Basin strike-slip earthquakes is shown in each case to have two well-fitting minima in the misfit function of pure double-couple solutions. Such pairs of solutions are most likely to exist for earthquakes which are close either to vertical strike-slip or to dip-slip on a fault plane dipping at 45°. It is shown theoretically that these pairs of solutions arise from the combination of the pure double-couple constraint and the instability of two elements of the moment tensor. No significant non-double-couple component is found for the shallow thrusting 1996 Biak, Indonesia earthquake.     

Where the buffalo roam: Boundaries and the politics of scale in the yellowstone region

For more than twenty years, the state of Montana has pursued a controversial policy of lethal control to manage winter migrations of bison from Yellowstone National Park. In the late 1990s, as the state and a number of federal agencies attempted to cooperatively outline a more palatable scenario for bison management, local environmental groups became active participants in the debate. This paper examines the strategies pursued by these organizations in the course of their attempt to construct a new, ecosystem-level territorial space and jurisdictional scale for bison, and places their struggle within the context of existing work in geography on the politics of scale. Ultimately, the failure of their efforts illustrates some of the important constraints faced by social groups that attempt to create new territorial regimes and new scales of resistance in the interstices of existing political structures.     

Fitness-for-Purpose of Reference Material Reference Values in Relation to Traceability of Measurement, as Illustrated by USGS BCR-1, NIST SRM 610 and IAEA NBS28

As in all fields of sample analysis, reference materials play a large role in supporting measurements in the geosciences. While a rather large number of materials are in distribution (> 380), not all are equally effective or fit-for-purpose in supporting laboratory data quality and thereby assuring the desired comparability of measurements between laboratories. Equally important, reference values that are not fit-for-purpose cannot be used effectively to establish traceability links between laboratory measurements and national and international standards. The needed fitness-for-purpose is not achieved for reference values either when more than one reference value has been proposed and a consensus does not exist among users as to which should be used by all, or when reference value uncertainties are too large in comparison to those of routine laboratory measurements. The focus of this review will be, first to outline the current reality, and second to suggest ways in which certifications of RMs can be improved to provide reference values that are universally accepted and more fit-for-purpose in general laboratory use. The discussion will be illustrated largely by current uses of USGS BCR-1, NIST SRM 610 and IAEA NBS28, as these three materials are those for which the largest body of newly published data exists, according to recent bibliographies of the geoanalytical literature published annually in Geostandards Newsletter: The Journal of Geostandards and Geoanalysis.     

Premier pôle paléomagnétique,d'âge Moscovien contraint par un test du pli,obtenu dans le bassin d'Illizi (Craton saharien,Algérie)First palaeomagnetic pole,of Moscovian age constrained by a fold test,in the Illizi Basin (Saharan Craton,Algeria)

Palaeomagnetic study, carried out in the Moscovian (～305 Ma) formation in the Edjeleh anticline, shows the existence of three magnetisation components. Two of them are probably Cenozoic and Permian remagnetisations. The third component determined by both well defined ChRMs and remagnetisation circles analysis passes the fold test. Because the folding started before or during the Stephano-Autunian, this third component is the primary magnetisation. Its palaeomagnetic pole (28.3°S, 58.9°E), close to other poles from the Saharan platform obtained from neighbouring periods but without palaeomagnetic tests, confirms the age of these last data. To cite this article: B. Bayou et al., C. R. Geoscience 334 (2002) 81–87.     

Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.     

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.