Potential protonation sites in the Al<Subscript>2</Subscript>SiO<Subscript>5</Subscript> polymorphs based on polarized FTIR spectroscopy and properties of the electron density distribution

Potential protonation sites for, kyanite, sillimanite, and andalusite, located in a mapping of the (3, −3) critical points displayed by their L(r) = −∇²ρ(r) distributions, are compared with polarized single-crystal FTIR spectra of kyanite and sillimanite determined earlier and with andalusite measured in this study. For andalusite, seven peaks were observed when the electric vector, E, is parallel to [100]: four intense ones at 3,440, 3,460, 3,526, and 3,597 cm⁻¹ and three weaker ones at 3,480, 3,520, and 3,653 cm⁻¹. Six peaks, three intense ones at 3,440, 3,460, and 3,526 cm⁻¹ and three weaker ones at 3,480, 3,520, and 3,653 cm⁻¹ when E parallels [010]. No peaks were observed when E is parallel to [001]. The concentration of water in andalusite varies between 110 and 168 ppm by weight % H₂O. Polarized FTIR spectra indicate that the OH vector is parallel to (001) in andalusite and sillimanite and in kyanite. Examination of the L(r) (3, −3) critical points in comparison with the polarized FTIR indicates that H prefers to bond to the oxygen atoms O1 and O2 in andalusite and O2 and O4 in sillimanite which correspond to the underbonded oxygen atoms and those with the largest L(r) maxima. In kyanite, comparison of the FTIR spectrum and the critical points indicates that H will preferentially bond to the two 4-coordinated O2 and O6 atoms.     

Paleoclimate of Southwestern China for the Past 50,000 yr Inferred from Lake Sediment Records

Long sediment cores (12.5 and 13.5 m) from two lakes in Yunnan Province were used to infer the paleoclimate of southwest China over the past 50,000 yr. During the Holocene and marine isotope stage (MIS 3), bio-induced carbonate precipitation and organic matter (OM) production was high, suggesting warm temperatures and high primary productivity. In contrast, sediment inorganic carbon (IC) and organic carbon (OC) concentrations were low in last glacial deposits from 38,000 to 12,000 cal yr B.P., indicating cool temperatures and low productivity. The 50,000-yr record has alternating peaks of carbonate and coarse-grain (>38 μm) quartz that reflect warm, moist interglacial or interstadial conditions alternating with cold, dry glacial or stadial conditions, respectively. Spectral analysis of the carbonate and quartz signals reveals power concentrated at periods of 7200 and 8900 cal yr, respectively, that may reflect a nonlinear climate response to precessional forcing at a time of reduced eccentricity modulation (McIntyre and Molfino, 1996). Oxygen isotope values of calcite from Yunnan lake cores indicate the summer monsoon was weak during the last glaciation from 50,000 to 12,000 cal yr B.P. The summer monsoon intensified between 12,000 and 8000 cal yr B.P., but weakened gradually in response to insolation forcing during the mid-to-late Holocene. Our results support the Overpeck et al. (1996) model that posits a weak summer monsoon during the last glaciation that responded nonlinearly to insolation forcing when its intensity was affected by Eurasian snow cover and ice-sheet extent. The summer monsoon intensified and responded linearly to seasonal insolation forcing in the Holocene when ice volume diminished.     

Magnetostratigraphic reinvestigation of the Palaeocene/Eocene boundary interval in Hole 690B, Maud Rise, Antarctica

Hole 690B, drilled on Maud Rise near Antarctica, provides one of the most important Palaeocene/Eocene boundary interval sections. Magnetostratigraphy plays a key role in dating Palaeocene/Eocene boundary events, but there are two problems with the published scheme in Hole 690B. The first concerns major mismatches of several magnetozones and biozones in the succession. The second is an unexplained pervasive declination cluster, which should not be present in these azimuthally unoriented piston cores. To resolve these issues, a palaeomagnetic reinvestigation was carried out on 98 specimens from 12 cores through the upper Palaeocene–middle Eocene section in Hole 690B.
The bulk of the samples carry an approximately uniformly directed magnetically hard component resulting in a declination cluster effectively identical to that of the earlier study. The spurious magnetization can be explained either as an 'inward-radial magnetization' or as a 'core-split overprint'. By estimating the extent of the overprint within each sample, it has been possible to construct a filtered magnetostratigraphy for the section. The result is that many of the magnetozone–biozone mismatches are eliminated, and the record of the 2.5 Myr Chron C24r, which brackets the various events associated with the Palaeocene/Eocene boundary, is considerably cleaner. It is not possible to define the upper and lower boundaries of this magnetochron, so we recommend that the dating of the events within this section be based on the biostratigraphy only.     

Detection of terracettes in semi-arid rangelands using Fourier-based image analysis of very-high-resolution satellite imagery

Terracettes are repeating step-like microtopographic features roughly following the contours of hillslopes that are often associated with livestock tracks. These common features in many semi-arid rangelands have been shown to alter soil moisture, slope stability, sediment transport, infiltration rates and coincident vegetation patterns. The spatial extent and distribution of terracettes is currently unknown and therefore their landscape-scale hydrological influence is absent in modelling and land management decision making. When viewed in uncalibrated very-high-resolution satellite imagery, terracettes appear as repetitious parallel lines within a specific frequency range. Here we used the two-dimensional discrete Fourier transform to identify terracettes at three test sites in the Inland Pacific Northwest, USA. We created an automated rule-based classification of terracetted sites based on spatial frequency, orientation, slope angle and land-use class. Results show a detection accuracy of 77% based on an optimized spatial frequencies search window between 0.3 and 0.7 m⁻¹. Terracette orientation did not contribute significantly to detection accuracy because orientations varied ±50° from digital elevation model-derived aspects. We found terracettes occurred predominantly on north-facing slopes at our test sites, although this estimate may be exaggerated by the timing of image capture. We feel that the method developed in this paper provides a way forward to map terracettes at large scales and enable new insights into the functions of terracettes in the landscape. © 2020 John Wiley & Sons, Ltd.     

Response of arid northeast Mexico to global climate changes during the late Pleistocene to the middle Holocene

Anthropogenic global warming might cause expansion of the drylands and trigger socio-economic challenges in the water-deficit subtropical regions. Changes in hydroclimate during the intervals of variable global temperature over the recent geological past, however, could provide useful information about the possible responses of these arid ecosystems to the near future warmer conditions. We evaluated hydroclimates of two different parts of subtropical North America by generating new records of surface processes and regional vegetation from drought-prone northeast Mexico and subsequently compared them with the paleoclimate of the central-southern United States. Our study suggests that congruent changes occurred in both parts during ~13.5–9.5 cal ka BP, an interval with no warm pool in the northern Gulf of Mexico. The precipitation and erosion responded to temperature-modulated variations in positions of the Inter-Tropical Convergence Zone (ITCZ). Conditions were wetter than today in the subsequent warmer interval (~9.5–8.2 cal ka BP) with generally stable ITCZ and the highest summer insolation. Hydroclimate changes of both parts lacked congruency during ~8.2–6.8 cal ka BP as the northern Gulf of Mexico began hosting a warm pool. Similar to the modern conditions, this warm pool might have modified trajectories of the tropical storms. Erosion and abundance of C₃ plants decreased in northeast Mexico. Higher wetness in the Mississippi River Basin and the southern Great Plains during this interval suggested that the storms made landfall more frequently in the central-southern United States. © 2019 John Wiley & Sons, Ltd.     

Optical properties of chromophoric dissolved organic matter (CDOM) in surface and pore waters adjacent to an oil well in a southern California salt marsh

Chromophoric dissolved organic matter (CDOM) optical properties were measured in surface and pore waters as a function of depth and distance from an oil well in a southern California salt marsh. Higher fluorescence and absorbances in pore vs. surface waters suggest soil pore water is a reservoir of CDOM in the marsh. Protein-like fluorophores in pore waters at distinct depths corresponded to variations in sulfate depletion and Fe(II) concentrations from anaerobic microbial activity. These variations were supported by fluorescence indexes and are consistent with differences in optical molecular weight and aromaticity indicators. Fluorescence indices were consistent with autochthonous material of aquatic origin in surface waters, with more terrestrial, humified allochthonous material in deeper pore waters. CDOM optical properties were consistent with significantly enhanced microbial activity in regions closest to the oil well, along with a three-dimensional excitation/emission matrix fluorescence spectrum peak attributable to oil, suggesting anaerobic microbial degradation of oil.     

Rehabilitation of earthquake damaged external RC beam‐column joints by joint enlargement using prestressed steel angles

The effectiveness of a rehabilitation method based on joint enlargement using prestressed steel angles to enhance the seismic behavior of damaged external reinforced concrete beam‐column joints was experimentally investigated. Three half‐scale joints having either non‐seismic or seismic reinforcement details were tested both before and after rehabilitation by applying lateral cyclic loading of increasing amplitudes. Two defects were considered for the two non‐seismic units, being the absence of transverse steel hoops and insufficient bond capacity of beam bottom steel reinforcing bars in the joint panel zone. The damaged specimens were rehabilitated by injecting epoxy grout into existing cracks and installing stiffened steel angles at the re‐entrant corners of the beam‐column joint, both above and below the beam, that were mounted and held in place using prestressed high‐tensile strength bars. The test results indicated that the seismic performance of the rehabilitated specimens in terms of strength, stiffness, and ductility was fully recovered and comparable with the performance of the seismically detailed specimen. Copyright © 2016 John Wiley & Sons, Ltd.     

Insight into sediment transport processes on saline rangeland hillslopes using three‐dimensional soil microtopography changes

In arid and semi‐arid rangeland environments, an accurate understanding of runoff generation and sediment transport processes is key to developing effective management actions and addressing ecosystem response to changes. Yet, many primary processes (namely sheet and splash and concentrated flow erosion, as well as deposition) are still poorly understood due to a historic lack of measurement techniques capable of parsing total soil loss into these primary processes. Current knowledge gaps can be addressed by combining traditional erosion and runoff measurement techniques with image‐based three‐dimensional (3D) soil surface reconstructions. In this study, data (hydrology, erosion and high‐resolution surface microtopography changes) from rainfall simulation experiments on 24 plots in saline rangelands communities of the Upper Colorado River Basin were used to improve understanding on various sediment transport processes. A series of surface change metrics were developed to quantify and characterize various erosion and transport processes (e.g. plot‐wide versus concentrated flow detachment and deposition) and were related to hydrology and biotic and abiotic land surface characteristics. In general, erosivity controlled detachment and transport processes while factors modulating surface roughness such as vegetation controlled deposition. The extent of the channel network was a positive function of slope, discharge and vegetation. Vegetation may deflect runoff in many flow paths but promoted deposition. From a management perspective, this study suggests that effective runoff soil and salt load reduction strategies should aim to promote deposition of transported sediments rather than reducing detachment which might not be feasible in these resource‐limited environments. Copyright © 2016 John Wiley & Sons, Ltd.     

<Emphasis Type="Italic">Acanthaster planci</Emphasis> outbreaks in Vanuatu coincide with ocean productivity,furthering trends throughout the pacific ocean

This study identifies linkages between regional ocean productivity and the emergence of large Acanthaster planci starfish populations in Vanuatu. Positive correlations were found between wind stress, chlorophyll-a, and upwelling during January–February 2009, corresponding with coral-eating starfish occurrences. Further, temporal associations have existed between monthly wind stress and upwelling since 2000, and were predictors of past starfish events. Links between starfish emergence and oceanographic features are discussed, drawing upon evidence from other asteroid echinoderms. High regional productivity associated with anomalous oceanographic conditions in Vanuatu, and globally, can be used as early warning indicators of probable, future starfish emergence to aid the foundation and success of local management efforts.