Evidence for plunging river plume deposits in the Pahrump Hills member of the Murray formation,Gale crater,Mars

Recent robotic missions to Mars have offered new insights into the extent, diversity and habitability of the Martian sedimentary rock record. Since the Curiosity rover landed in Gale crater in August 2012, the Mars Science Laboratory Science Team has explored the origins and habitability of ancient fluvial, deltaic, lacustrine and aeolian deposits preserved within the crater. This study describes the sedimentology of a ca 13 m thick succession named the Pahrump Hills member of the Murray formation, the first thick fine‐grained deposit discovered in situ on Mars. This work evaluates the depositional processes responsible for its formation and reconstructs its palaeoenvironmental setting. The Pahrump Hills succession can be sub‐divided into four distinct sedimentary facies: (i) thinly laminated mudstone; (ii) low‐angle cross‐stratified mudstone; (iii) cross‐stratified sandstone; and (iv) thickly laminated mudstone–sandstone. The very fine grain size of the mudstone facies and abundant millimetre‐scale and sub‐millimetre‐scale laminations exhibiting quasi‐uniform thickness throughout the Pahrump Hills succession are most consistent with lacustrine deposition. Low‐angle geometric discordances in the mudstone facies are interpreted as ‘scour and drape’ structures and suggest the action of currents, such as those associated with hyperpycnal river‐generated plumes plunging into a lake. Observation of an overall upward coarsening in grain size and thickening of laminae throughout the Pahrump Hills succession is consistent with deposition from basinward progradation of a fluvial‐deltaic system derived from the northern crater rim into the Gale crater lake. Palaeohydraulic modelling constrains the salinity of the ancient lake in Gale crater: assuming river sediment concentrations typical of floods on Earth, plunging river plumes and sedimentary structures like those observed at Pahrump Hills would have required lake densities near freshwater to form. The depositional model for the Pahrump Hills member presented here implies the presence of an ancient sustained, habitable freshwater lake in Gale crater for at least ca 10³ to 10⁷ Earth years.     

Tidal hydrology and habitat utilization by resident nekton in<Emphasis Type="Italic">Pragmites</Emphasis> and Non-<Emphasis Type="Italic">Phragmites</Emphasis> Marshes

We compared nekton densities over a range of measured flooding conditions and locations withinPhragmites australis andSpartina alterniflora (salt marsh cordgrass) at the Charles Wheeler Salt Marsh, located on the lower Housatonic River estuary in southwestern Connecticut. Nekton were sampled on nine spring high tide events from May to October 2000 using bottomless lift nets positioned between 0–5 and 10–20 m from the creek edge. Flooding depth, duration, and frequency were measured from each vegetation type during each sampling month. Benthic macroinvertebrate density was also measured within each vegetation type in May, July, and September. Frequency of flooding was 52% lower and flooding depth and duration were also significantly reduced inP. australis relative toS. alterniflora. A total of 4,197 individuals representing 7 species, mostlyPalaemonetes pugio (dagger-blade grass shrimp) andFundulus heteroclitus (common mummichog), were captured.P. pugio densities were significantly greater inS. alterniflora as were benthic macroinvertebrate density and taxa richness during May, but not during June or October. Total fish density was not significantly different betweenP. australis andS. alterniflora and was independent of location on the marsh. Significantly more juvenileF. heteroclitus were collected withinS. alterniflora relative toP. australis in June and July, suggesting that recruitment of this species may be lower inP. australis habitat. Fish density generally did not vary predictably across the range of flooding depth and duration; there was a positive relationship between flooding depth and fish density inS. alterniflora. The measured reduction in flooding frequency (52%) withinP. australis at the Housatonic site would result in an average total monthly fish use, expressed as density, of 447 ind m⁻² forP. australis and 947 ind m⁻² forS. alterniflora. WhenP. australis expansion results in reduction of flooding frequency and duration, nekton community composition can change, access to the marsh surface is reduced twofold, and nursery habitat function may be impaired.     

The oceanography of the Sydney region

An understanding of the oceanographic processes affecting effluent plume behaviour formed an important basis for the broad range of activities which were carried out as part of the Sydney Deepwater Outfalls Environmental Monitoring Programme. The main processes responsible for coastal circulation in the Sydney region include the East Australia Current, coastal trapped waves, winds, internal waves and outflows from major estuaries. As each of these processes is dynamically distinct, they occur on differing time and space scales, and the net current strength at any location can vary as differing processes wax and wane in their relative or absolute strength. Each of these processes and their effects on the transport and dispersion of sewage effluent discharged from the Sydney Deepwater Outfalls are briefly described.     

Storms, Investor Decisions, and the Economic Impacts of Sea Level Rise

Past research on the economic impacts of aclimate-induced sea level rise has been based on thegradual erosion of the shoreline, and humanadaptation. Erosion which is accelerated by sea levelrise may also increase the vulnerability to stormdamage by decreasing the distance between the shoreand structures, and by eroding protective coastalfeatures (dunes). We present methods of assessingthis storm damage in coastal regions where structuralprotection is not pursued. Starting from the boundingcases of no foresight and perfectforesight of Yohe et al. (1996), we use adisaggregated analysis which models the random natureof storms, and models market valuation and privateinvestor decisions dynamically. Using data from theNational Flood Insurance Program and a hypotheticalcommunity, we estimate that although the total stormdamage can be large, the increase in storm damageattributable to sea level rise is small (<5% oftotal sea level rise damages). These damages,however, could become more significant under otherreasonable assumptions or where dune erosion increasesstorm damage.     

Proton-binding study of standard and reference fulvic acids, humic acids, and natural organic matter

The acid-base properties of 14 standard and reference materials from the International Humic Substances Society (IHSS) were investigated by potentiometric titration. Titrations were conducted in 0.1 M NaCl under a nitrogen atmosphere, averaging 30 min from start to finish. Concentrations of carboxyl groups and phenolic groups were estimated directly from titration curves. Titration data were also fit to a modified Henderson-Hasselbalch model for two classes of proton-binding sites to obtain “best fit” parameters that describe proton-binding curves for the samples. The model was chosen for its simplicity, its ease of implementation in computer spreadsheets, and its excellent ability to describe the shapes of the titration curves. The carboxyl contents of the IHSS samples are in the general order: terrestrial fulvic acids > aquatic fulvic acids > Suwannee River natural organic matter (NOM) > aquatic humic acids > terrestrial humic acids. Overall, fulvic acids and humic acids have similar phenolic contents; however, all of the aquatically derived samples have higher phenolic contents than the terrestrially derived samples. The acid-base properties of reference Suwannee River NOM are surprisingly similar to those of standard Suwannee River humic acid. Results from titrations in this study were compared with other published results from both direct and indirect titrations. Typically, carboxyl contents for the IHSS samples were in agreement with the results from both methods of titration. Phenolic contents for the IHSS samples were comparable to those determined by direct titrations, but were significantly less than estimates of phenolic content that were based on indirect titrations with Ba(OH)₂ and Ca(OAc)₂. The average phenolic-to-carboxylic ratio of the IHSS samples is approximately 1:4. Models that assume a 1:2 ratio of phenolic-to-carboxylic groups may overestimate the relative contribution of phenolic groups to the acid-base chemistry of humic substances.     

Aqueous Phase Reaction of HNO4: The Impact on Tropospheric Chemistry

We use a global atmospheric chemistry transport model to study the possible influence of aqueous phase reactions of peroxynitric acid (HNO₄) on the concentrations and budgets of NO_x, SO_x, O₃ and H₂O₂. Laboratory studies have shown that the aqueous reaction of HNO_4aq withHSO^– _3aq, and the uni-molecular decomposition of the NO₄ ^– anion to form NO₂ ^– (nitrite) occur on a time scale of about a second. Despite a substantial contribution of the reaction of HSO^– _3aq with HNO_4aq to the overall in-cloud conversion of SO₂ to SO₄ ^2–, a simultaneous decrease of other oxidants (most notably H₂O₂) more than compensated the increase in SO₄ ^2– production. The strongest influence of heterogeneous HNO₄ chemistry was found in the boundary layer, where calculated monthly average ozone concentrations were reduced between 2% to 10% andchanges of H₂O₂ between –20% to +10%compared to a simulation which ignores this reaction. Furthermore, SO₂ was increased by 10% to 20% and SO₄ ^2–depleted by up to 10%. Since the resolution of our global model does not enable a detailed comparison with measurements in polluted regions, it is not possible to verify whether considering heterogeneous HNO₄ reactions results in a substantial improvement of atmospheric chemistry transport models. However, the conversion of HNO₄ in the aqueous phase seems to be efficient enough to warrant further laboratory investigations and more detailed model studies on this topic.     

Emeishan large igneous province, SW China

In recent years, there have been major advances in our understanding of the Emeishan large igneous province (LIP) of SW China following publication of a number of LIP-focused investigations of the terrain and associated rocks. This paper reviews the current state of knowledge. The volcanic and upper-intrusive portion of the province is relatively small (0.3×10⁶ km³), even when offset fragments, eroded sections and buried portions are included in the volume calculation. The most reliable radiometric age dates (zircon U–Pb SHRIMP from an associated layered intrusive body several kilometers in area) indicate generation at 259 Ma, consistent with the end-Guadalupian (end Middle Permian) stratigraphic age. In addition, several Ar–Ar dating studies have been carried out, mainly on the volcanic rocks, with a number of reported dates 253–251 Ma (Late Permian), but a consensus is emerging that these ages are problematic because they are in conflict with the stratigraphic data (possibly due to a monitor standard miscalibration). The Ar–Ar investigations have also yielded a large number of secondary ages, which are clustered at 175, 142, 98 and 42 Ma, and these are inferred to record sub-regional tectonic events that affected the western Yangtze Block as East Asia was assembled and later deformed by India’s collision–indentation into Asia. Magnetostratigraphic data and field observations suggest that the bulk of the volcanic sequence formed within 1–2 my. The geochemistry of the volcanic rocks and bio-lithostratigraphic studies of the underlying Maokou Formation suggests a mantle plume generated the province. The basalts can be classified into low and high Ti groups with different parental magmas. The low Ti basalts are confined to the western part of the province and are overlain by the high Ti basalts. The low Ti magmas formed at shallow mantle depths in the spinel–garnet field transition zone (60–80 km), whereas the high Ti magmas formed by low degrees of partial melting within the deeper garnet stability field. This observation suggests a deepening of the melting column as the lithosphere thickened due to under-plating and a transition from peak basalt generation to the waning stage. Outstanding issues, which might focus future studies, are also outlined.     

Halley and the London Queen Anne Churches

Edmond Halley's work on two London churches makes them the first buildings planned using modern scientific techniques, argue Jason R Ali and Peter Cunich.