Geochemical characterization of moldavites from a new locality,the Cheb Basin,Czech Republic

Abstract— Twenty‐three moldavites from a new locality, the Cheb Basin in Western Bohemia, were analyzed by instrumental neutron activation analysis for 45 major and trace elements. Detailed comparison of the Cheb Basin moldavites with moldavites from other substrewn fields in both major and trace element composition shows that the Cheb Basin is a separate substrewn field. The geochemical data obtained are discussed with respect to the source materials and processes leading to formation of moldavites. The data show that three groups of Cheb Basin moldavites exist. Ten samples of group 1 are characterized by the lowest content of Al, Fe, Na, and other elements representing phyllosilicate minerals, and by high Ca + Mg contents related probably to carbonates. They resemble the “poisonous green” moldavites, a subgroup of the Southern Bohemian moldavites. Seven samples of group 2 and 6 samples of group 3 are similar to typical moldavites of the Southern Bohemian substrewn field. These two groups differ from each other mainly in Al contents; with higher contents of Al and the elements associated with phyllosilicate minerals (namely Ba and Sr), group 3 also resembles the Moravian moldavites. Significant positive correlations between K, Ca, Mg, and Mn found in group 2 of the Cheb Basin moldavites and the enrichment in these elements observed generally in all moldavites, as well as other facts, e.g., high K/Na and K/Rb ratios and the reduced conditions during formation of moldavites, have been attributed to possible contribution to the moldavite source materials of the ash produced by burning of vegetation and soil organic matter present at the pre‐impact area.     

New data on the Neoproterozoic – Cambrian geotectonic setting of the Teplá-Barrandian volcano-sedimentary successions: geochemistry,U-Pb zircon ages,and provenance (Bohemian Massif,Czech Republic)

The Teplá-Barrandian unit (TBU) of the Bohemian Massif was a part of the Avalonian-Cadomian belt at the northern margin of Gondwana during Neoproterozoic and Early Cambrian times. New detrital zircon ages and geochemical compositions of Late Neoproterozoic siliciclastic sediments confirm a deposition of the volcano-sedimentary successions of the TBU in a back-arc basin. A change in the geotectonic regime from convergence to transtension was completed by the time of the Precambrian-Cambrian boundary. The accumulation of around 2,500 m Lower Cambrian continental siliciclastics in a Basin-and-Range-type setting was accompanied by magmatism, which shows within-plate features in a few cases, but is predominantly derived from anatectic melts displaying the inherited island arc signature of their Cadomian source rocks. The geochemistry of clastic sediments suggests a deposition in a rift or strike-slip-related basin, respectively. A marine transgression during Middle Cambrian times indicates markedly thinned crust after the Cadomian orogeny. Upper Cambrian magmatism is represented by 1,500 m of subaerial andesites and rhyolites demonstrating several geochemical characteristics of an intra-plate setting. Zircons from a rhyolite give a U-Pb-SHRIMP age of 499±4 Ma. The Cambrian sedimentary and magmatic succession of the TBU records the beginning of an important rifting event at the northern margin of Gondwana.

Propagator-matrix Technique for the Viscoelastic Response of a Multi-layered Sphere to Surface Toroidal Traction

We derive the matrix propagator for the response of a multi-layered, Maxwell viscoelastic sphere to a surface toroidal force in analytical form. Several numerical methods for 2-D and 3-D glacial-isostatic adjustment (GIA) modelling have been applied recently. The present analytical approach may be used as an aid for testing more general algorithms of GIA. The propagator-matrix solution has been tested by comparing it with the analytical solution of two-layer and three-layer spheres, with full agreement obtained.     

Underground geotechnical and geological investigations at Ekati Mine–Koala North: case study

Since 1998, BHP Billiton has mined diamonds at the Ekati Diamond Mine™ near Lac de Gras in the Northwest Territories of Canada. Current operations are based on mining multiple pipes by the open-pit method, but as some pits deepen, converting to underground mining is being considered.

As a test of underground mining methods and to provide access to the lower elevations of the Panda and Koala pipes, the Koala North pipe is being developed for underground mining. Initially, the top 40 m of the pipe were mined as an open pit to provide grade information and a prepared surface for the transition to underground mining. Currently, Koala North is being developed as an open-benching, mechanized, trackless operation. Although the method was successfully used at several De Beers diamond operations in South Africa, it has never been tested in an Arctic environment.

This case study describes basic geology, mining method layout and ongoing geological and geotechnical investigation. From the beginning of underground development, geotechnical daily routines have been fully integrated within the technical services department, which supports the operation. Geotechnical, geological and structural information obtained from underground mapping and core logging is compiled, processed, reviewed and analyzed on site by the geotechnical staff. Conclusions and recommendations are implemented as part of the operations in a timely manner. This ongoing “live” process enables the operators to make the most efficient use of resources both for ground support and excavations as well as to address safety issues, which are the top priority.     

Role of geology in diamond project development

For a mining operation to be successful, it is important to bring fundamental and applied science together. The mining engineer needs to understand the importance of geology, mineralogy and petrography, and how projects can benefit from the data collected during the exploration and pre-exploration stage. Geological scientists also need to understand the process of project development from the exploration stage through mine design and operation to mine closure. Kimberlite pipe or dyke emplacement, geology and petrology/mineralogy are three areas that illustrate how information obtained from the geological studies could directly influence the mining method selection and the project strategy and design. Kimberlite emplacement is one of the fundamental processes that rely on knowledge of the kimberlite body geology. Although the importance of the emplacement model is commonly recognized in the resource geology, mining engineers do not always appreciate its importance to the mine design. The knowledge of the orebody geometry, character of the contact zones, internal structures and distribution of inclusions could directly influence pit wall stability (thus strip ratio), underground mining method selection, dilution, treatability, and the dewatering strategy. Understanding the internal kimberlite geology mainly includes the geometry and character of individual phases, and the orientation and character of internal structures that transect the rock mass. For any mining method it is important to know “where the less and where the more competent rocks are located” to achieve stability. On the other hand, the detailed facies studies may not be important for the resource and mine design if the rock types have similar physical properties and diamond content. A good understanding of the kimberlite petrology and mineralogy could be crucial not only to the treatability (namely diamond damage and liberation), but also to the pit wall and underground excavation stability, support design, mine safety (mudrush risk assessment) and mine dewatering. There is no doubt that a better understanding of the kimberlite and country rock geology has a direct impact on the safety and economics of the mining operations. The process of mine design can start at the beginning of kimberlite discovery by incorporating the critical geological information without necessarily increasing the exploration budget. It is important to appreciate the usefulness of fundamental geological research and its impact on increased confidence in the mine design. Such studies should be viewed as worthwhile investments, not as cost items.     

Material versus local incompressibility and its influence onglacial‐isostatic adjustment

We present an analytical form of the layer propagator matrix for the response of a locally incompressible, layered, linear‐viscoelastic sphere to an external load assuming that the initial density stratification ϱ ₀( r ) within each layer is parametrized by Darwin's law. From this, we show that the relaxation of a sphere consisting of locally incompressible layers is governed by a discrete set of viscous modes. The explicit dependence of the layer propagator matrix on the Laplace transform variable allows us to determine the amplitudes of the viscous modes analytically. Employing Darwin's parametrization, we construct three simplified earth models with different initial density gradients that are used to compare the effects of the local incompressibility constraint, div ( ϱ ₀ u )=0, and the material incompressibility constraint, div  u =0, on viscoelastic relaxation. We show that a locally incompressible earth model relaxes faster than a materially incompressible model. This is a consequence of the fact that the perturbations of the initial density are zero during viscoelastic relaxation of a locally incompressible medium, so that there are no internal buoyancy forces associated with the continuous radial density gradients, only the buoyancy forces generated by internal density discontinuities. On the other hand, slowly decaying internal buoyancy forces in a materially incompressible earth model cause it to reach the hydrostatic equilibrium after a considerably longer time than a locally incompressible model. It is important to note that the approximation of local incompressibility provides a solution for a compressible earth model that is superior to the conventional solutions for a compressible earth with homogeneous layers because it is based on an initial state that is consistent with the assumption of compressibility.     

Numerical modeling of the atmospheric boundary layer over a hilly landscape

Summary A model for calculating the wind, turbulent exchange coefficients and a modification of the initial temperature over a hilly terrain is described. The paper mainly deals with a numerical realization of the model equations. Some features of the splitting method are discussed in detail. A special version of the splitting method suitable for solving the atmospheric boundary layer is described.

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Alternative solution to the problem of saturation adjustment in the presence of ice and water

Summary In cloud microphysics parameterization schemes, explicitly involving the co-existence of cloud water and ice in a temperature interval, it is necessary to solve the question of saturation adjustment in the presence of the mixed phase. In the present paper we propose an iteration procedure, which reliably converges with a small number of iterations, to solve this problem. The procedure is applied to a 3-D prognostic mesoscale model being developed for studying the effect of the ice phase on precipitation forecasts.     

Groundwater-quality monitoring—effective method of hydrogeological system pollution prevention

Groundwater-quality monitoring plays an important role in groundwater protection and quality conservation. National, regional, and site-specific monitoring programs operating in Czechoslovakia concern collection of back-ground data on groundwater quality and regional diffusion pollution problems. Site-specific monitoring is concerned with point sources of pollution. Pilot monitoring stations with automatic data acquisition systems optimize monitoring methods, design of monitoring networks, sampling techniques, and frequency and selection of the variables analyzed. Ground-water-quality monitoring in Czechoslovakia supports decision and policy making in areas of intensive farming. Time and spatial changes in shallow vulnerable aquifers are evaluated in several areas of national territory and support integrated land-use planning and groundwater protection management.     

Appreciation of spherically symmetric models of electrical conductivity

A procedure is suggested of a more effective and faster computation of the impedance, the transfer function and amplitudes of the induced field in a spherically symmetric model of the electrical conductivity. The existing induction data have been supplemented by about 80 new values derived from the analysis of daily means. The fit of the existing 1-D models of the electrical conductivity of the mantle to the set of induction data is investigated. The characteristic equation for the free electromagnetic oscillations of a radially inhomogeneous Earth is derived and its possible importance in solving the inverse problem of electric conductivity is pointed out.