Tephra stratigraphy on the North Icelandic shelf: extending tephrochronology into marine sediments off North Iceland

Tephra stratigraphical and tephrochronological studies of marine core MD99‐2275 on the North Icelandic shelf have revealed 58 new tephra horizons within the last 7050 cal. a BP, bringing the total number of identified tephra layers to 76. So far, over 100 tephra layers have been identified in the entire core spanning the last 15 000 years. The majority of the newly identified tephra layers are basaltic in composition and originate from the most active volcanic systems in Iceland, namely Grímsvötn, Veidivötn‐Bárdarbunga and Katla. A total of 40 tephra layer land–sea correlations have been made within this time period, of which 16 represent absolutely dated tephra markers. In addition, two tephra marker series are revealed in the marine sediments and in the terrestrial tephra stratigraphy, located between c. 2300–2600 and between 5700–5900 years. For the last 15 000 years, 21 tephra markers have been recognized. The marine tephra layer frequency (TLF) reveals two peaks, within the last 2000 years, and between 5000 and 7000 years ago. It shows the same general characteristics as the terrestrial TLF curve in Iceland, which indicates that marine sediments can yield important information about volcanism in Iceland. This is useful in time segments in which terrestrial records are poor or non‐existent. The study contributes to a high‐resolution tephrochronological framework on the North Icelandic shelf, with core MD99‐2275 representing a potential stratotype section in the area, and for the northern North Atlantic–Nordic Seas region, as well as being an important contribution to the Lateglacial–early Holocene volcanic history of Iceland.     

Temporal and spatial variation of soil erosion in wooded rangelands of southwest Spain

Changes in land use are common in Mediterranean areas and are reported as having produced changes in the intensity of soil erosion. Dehesas are rangelands with a disperse tree cover, widespread in the south-western part of the Iberian Peninsula and similar ecosystems are also common in other areas with a Mediterranean climate. The aim of the present study is to analyse temporal and spatial variations of soil erosion rates estimated along three hillsides, located in two farms (Buitrera and Parapuños) in southwest Spain. To understand the temporal variation, soil erosion rates were studied in light of land use-management changes that took place during the last few centuries. Results indicate very low erosion rates prior to the 18^th century in both farms. In Buitrera, a first increase of soil loss rates was identified during the period 1831-1897, amounting to 7.4 t ha^-1 y^-1. A further increase took place during the 20^th century, reaching a mean erosion rate of 29.1 t ha^-1 y^-1. In Parapuños, data points to a significant increase from 1881 onwards, with an estimated mean erosion rate of 18.5 t ha^-1 y^-1. Those increases were presumably connected with an intensification of land use, such as cultivation and excessive livestock populations. Regarding spatial variation, the bare surface and the erosive power of run-off along the hillsides accounts for 76% of the soil erosion rates dispersion. At a local scale, the variability of erosion rates could not be explained, because of (i) uncertainty related to the micromorphology of the past soil surface and (ii) the role of tillage erosion in the past. However, the results obtained offer valuable data on the temporal and spatial variation of erosion rates in dehesas at the hillslope scale and a similar approach could be used for other rangelands with a disperse tree cover. © 2019 John Wiley & Sons, Ltd.     

Evaluation of sampling devices for the determination of polycyclic aromatic hydrocarbons in surface microlayer coastal waters

The sea surface microlayer (SML) may play an important role on the transport and fate of persistent organic pollutants in the marine environment. In order to evaluate the appropriateness of a number of sampling devices for the analysis of 14 parent polycyclic aromatic hydrocarbons (3-5 aromatic rings), marine SML waters were sampled using a glass plate, a rotating drum/roller, a metal screen and a surface slick sampler. The underlying waters were also sampled for the determination of the corresponding enrichment factors (EF = [C](microlayer)/[C](underlying water)). The EFs were phase dependent, ranging from 1 to 3 for the dissolved phase and between 4 and 7 for the particulate phase. In order to better assess the performance of the different sampling methods, in terms of phase partitioning, the truly dissolved and colloidal phases were also estimated. Generally, no significant differences were found for the enrichment factors provided by the different methods, due to the observed large variability in concentrations that can be attributed to small-scale coastal processes. However, the metal screen is recommended as the most efficient sampling method for the study of PAHs taking into account the amount of water collected versus time.     

Throughfall patterns in sugarcane and riparian forest: understanding the effect of sugarcane age and land use conversion

Sugarcane is an annual crop with a dynamic canopy that changes over time mainly because of genetic adaptation. There is uncertainty about the temporal trends of throughfall (TF) in this important commercial crop. In the present paper, we used troughs to measure TF in a third and fourth ratoon and subsequently in a fourth and fifth ratoon. Additional measurements were carried out in an adjacent riparian forest. There were no significant differences between cycles of sugarcane, growth phases and riparian forest. The TF results for ratoon crop and riparian forest in 2011/2012 were 76% and 79.5% of gross rainfall, respectively, while in 2012/2013, they were 79% and 78%, respectively. However, TF was remarkably lower in the riparian forest relative to ratoon from the second half of the culm formation and elongation phase (280 days after harvest) until harvest. Copyright © 2016 John Wiley & Sons, Ltd.     

Lake Floor Morphology and Sediment Architecture of Lake Torneträsk,Northern Sweden

Here we present datasets from a hydroacoustic survey in July 2011 at Lake Torneträsk, northern Sweden. Our hydroacoustic data exhibit lake floor morphologies formed by glacial erosion and accumulation processes, insights into lacustrine sediment accumulation since the beginning of deglaciation, and information on seismic activity along the Pärvie Fault. Features of glacial scouring with a high‐energy relief, steep slopes, and relative reliefs of more than 50 m are observed in the large W‐basin. The remainder of the lacustrine subsurface appears to host a broad variety of well preserved formations from glacial accumulation related to the last retreat of the Fennoscandian ice sheet. Deposition of glaciolacustrine and lacustrine sediments is focused in areas situated in proximity to major inlets. Sediment accumulation in distal areas of the lake seldom exceeds 2 m or is not observable. We assume that lack of sediment deposition in the lake is a result of different factors, including low rates of erosion in the catchment, a previously high lake level leading to deposition of sediments in higher elevated paleodeltas, tributaries carrying low suspension loads as a result of sedimentation in upstream lakes, and an overall low productivity in the lake. A clear off‐shore trace of the Pärvie Fault could not be detected from our hydroacoustic data. However, an absence of sediment disturbance in close proximity to the presumed fault trace implies minimal seismic activity since deposition of the glaciolacustrine and lacustrine sediments.     

Influence of the natural organic matter in the removal of caffeine from water by fixed-bed column adsorption

The removal of caffeine from tap water by F-400 granular activated carbon in fixed-bed adsorption experiments was carried out. Textural and chemical characterization of the adsorbent through N₂ adsorption–desorption isotherms, Fourier transform infrared spectrometry, isoelectric point determination and scanning electron microscopy studies was developed in studies previously reported. Caffeine breakthrough curves and total organic carbon profiles at different operation conditions (inlet concentration, volumetric flow rate and mass of adsorbent) were obtained. These experimental results showed a displacement of the natural organic matter from the active sites exerted by caffeine molecules due to their higher affinity to the surface carbon. This behavior led to an overshooting, a local outlet natural organic matter concentration higher than the feed quantity. A competitive effect seems to be observed in the removal of the target compound, decreasing the efficiency of the process. Axial dispersion coefficients and dimensionless numbers were estimated for the caffeine removal onto F-400 activated carbon. Therefore, the regeneration of the adsorbent by adsorption–desorption cycles was studied.     

Alkaline phosphatase activity and its relationship to inorganic phosphorus in the transition zone of the North-western African upwelling system

The enzymatic activity of alkaline phosphatase (APA) was studied in the transition zone between the African upwelling system and the open ocean waters of the Canary Islands region. This region is recurrently dominated by the presence of upwelling filaments that may transport nutrient-enriched waters out into the open ocean before nutrients become exhausted by plankton. Turnover rates by APA were generally low in the whole region, but detectable in all the measurements carried out. On average, turnover rates were higher in the upwelling stations, and APA in those waters seemed to be mainly generated by heterotrophic bacteria to supply easily assimilable organic C. APA outside the upwelling area showed an inverse hyperbolic relationship with increasing phosphate, suggesting the presence of both constitutive and Pi-inducible APA. In these offshore waters, a threshold of 0.1 μM of phosphate could be defined for the regulatory function of Pi on APA. Thus, APA in nutrient-poor waters seemed to be induced to compensate for Pi-deficiency. Turnover rates in the filaments showed basal (probably constitutive) levels, whereas they increased in the surrounding waters, where phosphate concentration presumably did not satisfy plankton P-demands. The fertilising effect of the filaments and associated cyclonic eddies extended to at least 175 km offshore, where basal alkaline phosphatase activities were still found. The magnitude of this effect depends probably on the intensity of upwelling events and the degree of recirculation of filament water back to the coastal jet.     

Historical record of heavy metals in a highly contaminated Mediterranean deposit: The Besòs prodelta

The Besòs prodelta, located around a highly populated area, receives the discharge of the Besòs River, one of the most contaminated rivers discharging into the Mediterranean sea. The record of heavy metals accumulated in this prodelta is studied to assess the sedimentary behaviour and the history of the anthropogenic heavy metals in the area.

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dated sediments have allowed the identification of the sedimentation patterns and the elaboration of dated heavy metals and cenospheres profiles, which reflected the evolution of the anthropogenic impact in this marine environment. Sediments accumulated during the 18th and 19th centuries were already affected by a moderate heavy metal contamination. This contamination increased drastically in the sediments accumulated during the last decades. This data is well correlated with the increase in industrialisation, population and energy consumption in the Besòs drainage basin during the last century.