Oxygen sites in hydrous aluminosilicate glasses: the role of Al-O-Al and H2O

We describe here high-field ¹⁷O magic-angle-spinning (MAS) and triple-quantum MAS (3QMAS) NMR spectra for several alkali silicate and Na, K, and Ca aluminosilicate glasses containing up to 10 wt.% water. The H₂O site appears to have a large quadrupolar coupling constant, and its chemical shift increases from Na- to K- glasses, suggesting significant cation-H₂O interactions. In ¹⁷O one-pulse MAS and 3QMAS and ²⁷Al one-pulse NMR experiments, major differences were seen between spectra for anhydrous and hydrous calcium aluminosilicate glasses. The changes in the ¹⁷O MAS spectra can be explained by the addition of an H₂O peak and to the disappearance of an Al-O-Al peak from the ¹⁷O NMR spectrum for the hydrous glass. The ²⁷Al results are consistent with this interpretation.     

Freshwater oncolites created by industrial pollution, Onondaga Lake, New York

Onondaga Lake is a moderately saline, eutrophic lake characterized by waters rich in calcium, sodium, chloride and bicarbonate. Large quantities of CaCO₃ that are precipitated in the lake result from excess calcium supplied as calcium chloride wastes produced by soda-ash manufacturing to lake waters that are at or near saturation with respect to CaCO₃ from solution of carbonate rocks in the drainage basin. Beaches along the leeward (northeastern) shore of the lake are composed almost entirely of oncolites ranging from a few millimeters to several centimeters in maximum dimension. Offshore, in 1–2 m of water, the oncolites are biscuit-shaped concretions as much as 15 cm in diameter. The oncolites consist mainly of low-magnesium calcite, but dissolution of the carbonate with dilute acid results in a mass of blue-green algal filaments of the same approximate size and shape as the original oncolite. Most oncolites have an obvious nucleus; the most common nucleus is the hollow stem and cortication tubules of charophytes. Charophytes do not occur in Onondaga Lake today although they are common in other limestone-bedrock lakes in central New York State. Charophytes probably were eliminated by the marked increases in salinity of the lake that resulted from the introduction of soda-ash manufacturing on the lake shores around 1880 which means that growth of the oncolites began at least 100 years ago.     

Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances

We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases.     

Testing the utility of structure‐from‐motion photogrammetry reconstructions using small unmanned aerial vehicles and ground photography to estimate the extent of upland soil erosion

Quantifying the extent of soil erosion at a fine spatial resolution can be time consuming and costly; however, proximal remote sensing approaches to collect topographic data present an emerging alternative for quantifying soil volumes lost via erosion. Herein we compare terrestrial laser scanning (TLS), and both unmanned aerial vehicle (UAV) and ground photography (GP) structure‐from‐motion (SfM) derived topography. We compare the cost‐effectiveness and accuracy of both SfM techniques to TLS for erosion gully surveying in upland landscapes, treating TLS as a benchmark. Further, we quantify volumetric soil loss estimates from upland gullies using digital surface models derived by each technique and subtracted from an interpolated pre‐erosion surface. Soil loss estimates from UAV and GP SfM reconstructions were comparable to those from TLS, whereby the slopes of the relationship between all three techniques were not significantly different from 1:1 line. Only for the TLS to GP comparison was the intercept significantly different from zero, showing that GP is more capable of measuring the volumes of very small erosion features. In terms of cost‐effectiveness in data collection and processing time, both UAV and GP were comparable with the TLS on a per‐site basis (13.4 and 8.2 person‐hours versus 13.4 for TLS); however, GP was less suitable for surveying larger areas (127 person‐hours per ha^?1 versus 4.5 for UAV and 3.9 for TLS). Annual repeat surveys using GP were capable of detecting mean vertical erosion change on peaty soils. These first published estimates of whole gully erosion rates (0.077 m a^?1) suggest that combined erosion rates on gully floors and walls are around three times the value of previous estimates, which largely characterize wind and rainsplash erosion of gully walls. Copyright © 2017 John Wiley & Sons, Ltd.     

全球重要农业文化遗产(GIAHS)保护与适应性管理(英文)

世界各地世代居住的农牧民,以多样化的自然资源为基础,通过因地制宜的生产实践活动,创造、形成并保持着许多独具特色的农业系统和景观。这些在本土知识和传统经验基础上所建立起来的农业文化遗产巧夺天工,充分反映了人类及其文化多样性和与自然环境之间深刻关系的演进历程。这些系统不仅维持并适应了具有全球重要意义的农业生物多样性,形成了丰富的本土知识体系,而且更为重要的是,还为人类持续提供了多样化的产品和服务,保障了食物安全和生计安全,提高了人们的生活质量。但是,许多这样的农业生产系统正面临着包括全球化在内的多种影响因素的威胁。2002年,联合国粮农组织发起了一个国际合作计划"全球重要农业文化遗产(GIAHS)保护与适应性管理"。这一全球性倡议旨在建立这些农业文化遗产及其有关的生物多样性、食物与生计安全、景观与文化的保护体系,并在世界范围内得到认可,实现动态保护和可持续管理。     

Seasonal variations in energy exchange and evapotranspiration of an oasis-desert ecotone in an arid region

Knowledge of exchanges of energy and water over terrestrial surfaces is the first step towards understand the ecohydrological mechanisms, particularly in water-limited ecosystems in dryland environments. However, patterns of energy exchange and evapotranspiration (ET) are not well understood in the oasis-desert ecotone, which plays an important role in protecting oases against the threat of desertification in arid regions of northwestern China. Here, the continuous measurements of surface energy fluxes were made using eddy covariance in conjunction with auxiliary measurements for 2 years (2014–2015) in an oasis-desert ecotone mainly covered by phreatophyte shrubs Haloxylon ammodendron, Nitraria tangutorum/sphaerocarpa, and Calligonum mongolicum in arid northwestern China. Based on the collated data for 2 years, statistical analysis on a 30-min time scale indicated that approximately 50% of daytime net radiation (R_n) in the ecotone was dissipated as H on average, and one-third of R_n was consumed by soil heat flux (G). Only 9% of R_n was consumed for latent heat flux (λE), which peaked in summer (21% in 2014 and 16% in 2015), corresponding to the highest rainfall season. Daily mean ET was approximately 1 mm days⁻¹ during the growing season of the shrub species. Accumulated annual ET was 195 and 181 mm in 2014 and 2015, respectively, exceeding the corresponding precipitation (P) by approximately 87 and 77 mm, indicating that groundwater may be another important source of water for ET in the ecotone aside from rainfall. Results within provide valuable insights into the mechanisms responsible for sustaining energy and water balance in the ecotone, a potentially groundwater-dependent ecosystem. These results also offer a foremost ecohydrological implication for water and land resources management and ecotone conservation, such as avoiding heavy groundwater pumping for extensive agricultural irrigation use to sustain groundwater availability for these shrub species in the ecotone.     

Wonders of Nature in each Quarter of the World: a nineteenth century geological game

Wonders of Nature in each Quarter of the World was an early nineteenth century educational board game designed to teach children about some of the natural wonders of the world, such as volcanoes. The game was produced at a time of advances in geological thinking and geographical expeditions and this study places such changes and events within the context of the pastime, and presents an interesting window on the way geology was perceived almost two centuries ago.     

Groundwater resources and quality in northeastern Jordan: safe yield and sustainability

Over-abstraction of groundwater is one concern of the Badia Research and Development Programme. The upper aquifer of the Azraq basin forms the largest resource of good-quality water, but current abstraction exceeds both average recharge and the safe yield of the aquifer, which is over-exploited. Although there has been no deterioration in water quality and only minor drawdown, the springs at Azraq have dried up, with severe, undesirable environmental impacts. Total abstraction of 20 × 10⁶ m³ yr⁻¹ appears to be sustainable and would allow some springflow, but this leaves a shortfall of 40 × 10⁶ m³ yr⁻¹ for domestic supply and agriculture.     

Spatial variations of DMS, DMSP and phytoplankton in the Bay of Bengal during the summer monsoon 2001

Data on the distribution of dimethylsulphide (DMS) and dimethylsulphoniopropionate (DMSP) in relation to phytoplankton abundance in different oceanic environments is important to understand the biogeochemistry of DMS, which plays an important role in the radiation balance of the earth. During the summer monsoon of 2001 measurements were made for DMS and DMSPt (total DMSP) together with related biological parameters in the Bay of Bengal. Both DMS and DMSPt were restricted to the upper 40 m of the water column. Diatoms accounted for more than 95% of the phytoplankton and were the major contributors to the DMS and DMSPt pool. The mean concentration of DMS in the upper 40 m was observed to be around 1.8+/-1.9 nM in the study area, while DMSPt concentrations varied between 0.7 nM and 40.2 nM with a mean of 10.4+/-8.2 nM. The observed lower DMSPt in the northern Bay in spite of higher mean primary productivity, chlorophyll a and phytoplankton cell counts seemed to result from grazing. Though salinity divides the Bay into different biogeochemical provinces there is no relation between salinity and DMS or DMSPt. On the other hand DMS was linearly related to chlorophyll a:phaeopigments ratio. The results suggest the need for deeper insight into the role of diatoms in the biogeochemical cycling of DMS.