Big brand sustainability: Governance prospects and environmental limits

This article introduces and evaluates the implications for global environmental change of the rising power and authority of big brand companies as global environmental governors. Contributing to the private governance literature and, in particular, addressing the gap in this research with respect to the political implications of individual firm ‘buyer power’, the article provides evidence and analysis of how big brand sustainability is altering the power relations within global supply chains, and the governance prospects and limits of this trend. The authors argue that recent brand company efforts through their global supply chains, while still a long way off from their goals, are achieving environmental gains in product design and production. Yet, these advances are also fundamentally limited. Total environmental impacts of consumption are increasing as brand companies leverage corporate sustainability for competitive advantage, business growth, and increased sales. Big brand sustainability, while important, will not on its own resolve the problems of global environmental change. In conclusion, the article highlights the importance of a co-regulatory governance approach that includes stronger state regulations, sustained advocacy, more responsible individual consumerism, and tougher international legal constraints to go beyond the business gains from big brand sustainability to achieve more transformational, ‘absolute’ global environmental progress.     

High-Ti amphibole as a petrogenetic indicator of magma chemistry: evidence for mildly alkalic-hybrid melts during evolution of Variscan basic–ultrabasic magmatism of Central Iberia

Central Iberian Variscan granite batholiths and anatectic complexes are punctuated by coeval stocks of hydrous, high-K calc-alkaline, ultrabasic to intermediate rock series. Despite their overall calc-alkaline affinity, the mafic–ultramafic members contain high-Ti amphibole oikocrysts rimmed by lower-Ti amphibole ± cummingtonite and high-Ti amphibole replacing early phlogopite. To understand the factors controlling the saturation of high-Ti amphibole in the parental magmas, clinopyroxene-melt, phlogopite-melt and amphibole-melt relationships are reviewed. This analysis reveals that for melts with intermediate compositions, the affinity of TiO₂ for amphibole rises in alkalic magmas. Accordingly, mildly alkalic trachytoid to subalkaline medium- to high-K andesite and dacite compositions are estimated for interstitial high-Ti amphibole-saturated melts. Amphibole Ce/Pb ratios reveal a mantle–crust hybrid nature for interstitial melts with subalkaline trachytoid compositions. The hydrous character of the Variscan basic magmas favoured an overall magmatic evolutionary trend with a low rate of variation of Na₂O with respect to silica during amphibole crystallization. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Mineralogical and chemical characteristics of some natural jarosites

This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at low temperatures, which suggests the presence of a solvus in the jarosite-natrojarosite system at temperatures below about 140 °C. The samples examined in this study consist of either end members or coexisting end-member pairs of jarosite and natrojarosite. Quantitative electron-probe microanalysis data for several natural hydrothermal samples show only end-member compositions for individual grains or zones, and no detectable alkali-site deficiencies, which indicates that there is no hydronium substitution within the analytical uncertainty of the method. In addition, there is no evidence of Fe deficiencies in the natural hydrothermal samples. Hydronium-bearing jarosite was detected in only one relatively young supergene sample suggesting that terrestrial hydronium-bearing jarosites generally are unstable over geologic timescales.Unit-cell parameters of the 20 natural stoichiometric jarosites and 12 natural stoichiometric natrojarosites examined in this study have distinct and narrow ranges in the a- and c-cell dimensions. There is no overlap of these parameters at the 1σ level for the two end-member compositions. Several hydrothermal samples consist of fine-scale (2-10 μm) intimate intergrowths of jarosite and natrojarosite, which could have resulted from solid-state diffusion segregation or growth zoning due to variations in the Na/K activity ratio of hydrothermal solutions.     

The Effects of Varying Salinity on Ammonium Exchange in Estuarine Sediments of the Parker River,Massachusetts

We examined the effects of seasonal salinity changes on sediment ammonium (NH₄ ⁺) adsorption and exchange across the sediment–water interface in the Parker River Estuary, by means of seasonal field sampling, laboratory adsorption experiments, and modeling. The fraction of dissolved NH₄ ⁺ relative to adsorbed NH₄ ⁺ in oligohaline sediments rose significantly with increased pore water salinity over the season. Laboratory experiments demonstrated that small (∼3) increases in salinity from freshwater conditions had the greatest effect on NH₄ ⁺ adsorption by reducing the exchangeable pool from 69% to 14% of the total NH₄ ⁺ in the upper estuary sediments that experience large (0–20) seasonal salinity shifts. NH₄ ⁺ dynamics did not appear to be significantly affected by salinity in sediments of the lower estuary where salinities under 10 were not measured. We further assessed the importance of salinity-mediated desorption by constructing a simple mechanistic numerical model for pore water chloride and NH₄ ⁺ diffusion for sediments of the upper estuary. The model predicted pore water salinity and NH₄ ⁺ profiles that fit measured profiles very well and described a seasonal pattern of NH₄ ⁺ flux from the sediment that was significantly affected by salinity. The model demonstrated that changes in salinity on several timescales (tidally, seasonally, and annually) can significantly alter the magnitude and timing of NH₄ ⁺ release from the sediments. Salinity-mediated desorption and fluxes of NH₄ ⁺ from sediments in the upper estuary can be of similar magnitude to rates of organic nitrogen mineralization and may therefore be important in supporting estuarine productivity when watershed inputs of N are low.     

Mechanisms and reliability of future projected changes in daily precipitation

We isolate the contribution of warming, other large-scale changes and soil moisture decline and feedbacks in driving future projected changes in daily precipitation across Europe. Our confidence in each of these mechanisms differs, so this analysis then allows us to determine an overall confidence (or reliability) in the projected changes. In winter, increases in extreme precipitation over Europe as a whole are judged to be reliable, dominated by increased atmospheric moisture with warming. At scales less than about 2,000 km changing circulation patterns could enhance or offset this increase. Additionally, over the Scandinavian mountains warming-induced circulation changes do offset the effect of increased moisture and the overall change is unreliable. In summer, increases in extreme precipitation over northern Scandinavia and decreases over the Mediterranean are reliable in the absence of considerable circulation change. Over central Europe, an increase in the proportion of summer rainfall falling as extreme events is reliable.     

Linking Spatial and Temporal Variation at Multiple Scales in a Heterogeneous Landscape*

Anthropogenic, ecological, and land‐surface processes interact in landscapes at multiple spatial and temporal scales to create characteristic patterns. The relationships between temporally and spatially varying processes and patterns are poorly understood because of the lack of spatiotemporal observations of real landscapes over significant stretches of time. We report a new method for observing joint spatiotemporal landscape variation over large areas by analyzing multitemporal Landsat data. We calculate the spatiotemporal variation of the Normalized Difference Vegetation Index (NDVI) in the area covered by one Landsat scene footprint in north central Florida, over spatial windows of 10⁴–10⁸ m² and time steps of two to sixteen years. The correlations, slopes, and intercepts of spatial versus temporal regressions in the real landscape all differ significantly from results obtained using a null model of a randomized landscape. Spatial variances calculated within windows of 10⁵–10⁷ m² had the strongest relationships with temporal variances (regressions with both larger and smaller windows had lower coefficients of determination), and the relationships were stronger with longer time steps. Slopes and y‐intercepts increased with window size and decreased with increased time step. The spatial and temporal scales at which NDVI signals are most strongly related may be the characteristic scales of the processes that most strongly determine landscape patterns. For example, the important time and space windows correspond with areas and timing of fires and tree plantation harvests. Observations of landscape dynamics will be most effective if conducted at the characteristic scales of the processes, and our approach may provide a tool for determining those scales.     

Athabasca Glacier,Canada – a field example of subglacial ice and till erosion?

The Athabasca Glacier, resting on a rigid bed, provides an excellent example of subglacial ice and till erosion. The presence of a thin mobile till layer is shown by the presence of flutes, saturated till layer, push moraines and ploughed boulders. Cross‐cutting striations, v‐shaped striations and reversed stoss‐and‐lee clasts are indicative of clasts rotating within this layer. As the till moves it erodes the bedrock and clasts within it. A combination of erosion by ice and till produces stoss‐and‐lee‐clasts and generates striations on flutes and embedded clasts, as well as eroding the bedrock into a continuum of smoothed, rounded and streamlined forms. Copyright © 2005 John Wiley & Sons, Ltd.     

Towards realistic simulations of lava dome growth using the level set method

The level set method has been implemented in a computational volcanology context. New techniques are presented to solve the advection equation and the reinitialisation equation. These techniques are based upon an algorithm developed in the finite difference context, but are modified to take advantage of the robustness of the finite element method. The resulting algorithm is tested on a well documented Rayleigh–Taylor instability benchmark [19], and on an axisymmetric problem where the analytical solution is known. Finally, the algorithm is applied to a basic study of lava dome growth.