Sulphur-containing compounds in sulphur-rich crude oils from hypersaline lake sediments and their geochemical implications

Three sulphur-rich commercial crude oils have been studied, which contain sulphur as high as up to 4–12%. These samples were collected from Tertiary hypersaline lake sediments of the Jianghan Basin, Hubei Province at different depths, but above the oil generation threshold (2200m). FPD-GC and GC-MS data show that aromatic fractions of the crude oils are composed of different homologues of sulphur-containing compounds, including long-chain normal alkyl-thiophenes and-thiolanes, long-chain isoprenoid-thiophenes and -thiolanes, and benzothiophenes. It is worth noting that the distribution patterns of long-chain alkyl-thiophenes and -thiolanes from two shallow-seated crude oils are quite similar to those of normal alkanes showing marked even-odd predominance. It seems that the even-odd predominance of sulphur-containing compounds decreases with increasing burial depth of the crude oils. The major component of aliphatic fraction is phytane, and similarly the major peaks of aromatic fractions also represent C₂₀ isoprenoid thiophenes. Some preliminary conclusions have been drawn from the above discussion: (1) Abundant sulphur-containing compounds may be used as an indicator of low mature or immature crude oils produced from hypersaline lake sediments; (2) Sulphur-containing compounds are considered to be early diagenetic products of reactions between elemental sulphur or sulfides and alkanes or their precursors (phytols, fatty acids, alcohols, etc.), or of bacterial activities, but not direct inputs of organisms.     

Diurnal asymmetry of radio wave absorption on anomalous winter days

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Temperature-time dependence of the electrical conductivity of garnets

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The IMF structure effects in vernal and autumnal midlatitude ionosphere

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Results of a semi-implicit two-step method for the simulation of markedly nonlinear flow in coastal seas

Results of a numerical method for the simulation of nonlinear flow in coastal seas are presented. The method is based on a neutral semi-implicit scheme which is modified into a stability-enhancing two-step algorithm. By means of this method the simulation of highly nonlinear flow patterns is possible in a stable and economic way. Three examples of models of different North Sea coastal regions are discussed under certain aspects to demonstrate the reliability of the method.     

Metamorphic gradients in burial metamorphosed vesicular lavas: Comparison of basalt and spilite in Cretaceous basic flows from central Chile

Partial spilitization of a 9 km thick pile of flood basalts with highly vesicular flow tops gave rise to patterns of secondary mineralogy at different scales: (a) a local pattern of mineralogical variation from the almost unaltered bottom towards the altered top of each flow, and (b) an overall pattern, comparing flow tops throughout the pile, with changes in mineralogical composition within a sequence of metamorphic zones and facies. The local patterns mimic the trend of the overall pattern, but are of opposite direction and telescoped. Thus, a gradual ordering and Andepletion of the secondary albite and increases in the Fe^*/Al ratio of epidote and pumpellyite upwards within individual flows are comparable in range to corresponding overall changes downwards throughout several kilometres. The mineralogical changes within the flows diminish in range towards the more altered deeper part of the pile.The local and overall patterns cannot be interpreted in terms of grade. They represent trends from metastable towards stable equilibrium, this latter only approached in the flow tops of the lower part of the pile. The patterns of secondary mineralogy were formed by an interplay of metamorphic gradients at different scales at any given time, and as burial proceeded. The overall pattern was caused by depth-controlled gradients: increasing P _fluid, temperature and temperature-induced increase of reaction rates, and decreasing fO₂ (downwards in the pile). The local patterns resulted from permeability-controlled gradients: increasing reaction rates, fO₂ and contrast in chemical activity between different domains, and decreasing P _fluid (upwards in each flow). The mineralogical observations reported in this paper fall into line if the overall temperature-induced increase of reaction rates and the local permeability-controlled rate factors played the leading role during burial metamorphism of the pile.     

Post-Svecokarelian andinotype evolution in central Sweden

Granitoids and associated volcanics, postorogenic in relation to the Svecokarelian orogeny, constitute a belt in central Sweden. Evidence presented in this paper suggest that the belt originated in an Andinotype orogenic environment. The inferred development of the belt was characterized by fracture-controlled high-level emplacement of batholiths in an ensialic setting. Voluminous venting of ignimbrites and formation of grabens through cauldron subsidence accompanied the recurrent intrusive activity. Block movements and episodes of burial metamorphism appear to have been prominent features throughout the history of the post-Svecokarelian belt.

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Zusammenfassung Granitoide Plutonite und verwandte Vulkanite, post-orogen im Verhältnis zur Svekokarelischen Orogenese, bilden einen Gürtel in Mittelschweden. Es wird gezeigt, daß der Gürtel in einer andinotypen Orogenese gebildet wurde. Die vorgeschlagene Entwicklung des Gürtels ist geprägt durch spaltentektonisch kontrollierte Platznahme von Batholithen in einem seichten Niveau der Kruste in ensialischem Mileau. Umfangreiche Eruptionen von Ignimbriten sowie die Bildung von Grabenbrüchen durch Kalderen-Einstürzungen begleiten die erneute intrusive Tätigkeit. Blockbewegungen und episodische Versenkungsmetamorphosen sind charakteristisch während der gesamten Entwicklungsgeschichte des post-svekokarelischen Gürtels.

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Résumé Des granitoïdes et des volcanites associées, postorogéniques par rapport à l'orogénese svécokarélienne, forment une ceinture en Suède centrale. La présente étude suggère que la mise en place de ces roches s'est effectuée dans un environment orogénique Andinotype. L'évolution de la ceinture c'est caractérisée par la mise en place; contrée par des fractures, de batholites peu profonds, en milieu ensialique. Des volumineuses éruptions d'ignimbrites et la formation de grabens par «cauldron subsidence» ont accompagné la mise en place des batholites. Des mouvements verticaux de blocs, ainsi que des épisodes de métamorphisme d'enfouissement («burial metamorphism») semblent être des faits dominants du développement historique de la ceinture post-svécokarélienne.

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Difference between the even and odd 11-year cycles of geomagnetic activity

Summary With the aid of 36 monthly and a double 12-month running average, graphs of the smoothed run of geomagnetic activity were constructed from the monthly values of the geomagnetic activity index aa for the period 1868–1978 and they were then used to determine the run of the geomagnetic activity, expressed during a uniform period and devoid of the secular variation of geomagnetic activity, for the individual 11-year cycles Nos 12–20 and the average runs for even and odd cycles, as well as for the whole period of the 9 cycles. The analysis and comparison of the graphs substantiates and renders more accurate the tendency, observed earlier, towards a regular alternation of geomagnetic activity cycles with double and single maxima. Wheareas a saddle-like shape with a maximum in the neighbourhood of the first and third quarter of the cycle is characteristic of the shape of the even cycle, the second maximum being, as a rule, the main one, the odd cycle is characterized by a peak-like shape with the main maximum in the vicinity of the cycle's centre.     

Post-drilling destabilization of temperature profile in borehole Yaxcopoil-1, Mexico

As part of the International Continental Scientific Drilling Program (ICDP), the 1.5-km-deep borehole Yaxcopoil-1, located in the Chixculub meteor impact structure in Mexico, has undergone further study after drilling operations ceased. Temperature logs were repeated ten times at intervals 0.3–0.8, 15, 24 and 34 months after borehole shut-in. The logs bear a distinct signature of transient heat transfer by groundwater flow manifested by a gradual distortion of the linear temperature profile when a cold wave of 0.8–1.6°C amplitude was detected propagating downward from 145 to 312 m at a rate of 4–6 m/month. To understand the nature of this moving anomaly, a 20-day monitoring of the cold wave was carried out at a depth of 307 m that showed further cooling of 0.6°C during the first 16 days of the passage followed by temperature stabilisation. As an explanation of this unusual phenomenon, a theory is proposed, whereby the drilling mud has accumulated within the overlying and cooler highly porous and permeable karstic rocks during the drilling and migrates downward. The observed migration rate suggests a permeability higher than 10^?11 m². This indicates a high vulnerability to contamination of the only freshwater aquifer in the Yucatan region.