Biomarker lipids of the freshwater fern Azolla and its fossil counterpart from the Eocene Arctic Ocean

Eocene sediments recovered from the Lomonosov Ridge in the central Arctic Ocean during Integrated Ocean Drilling Program Expedition 302 contain high amounts of fossil remains of the free floating freshwater fern Azolla. Both extant Azolla and the sediments from the Arctic Azolla interval were found to contain relatively high quantities of compounds identified as 1,ω20 C₃₀–C₃₆ diols. Furthermore, structurally related mid-chain hydroxy fatty acids, long chain n-alkanols and keto-ols were discovered. The different series have a common feature: there is always a hydroxy group at the ω20 position. In addition, structurally related C₂₉ ω20,ω21 diols, C₂₉ 1,20,21 triols, C₂₉ dihydroxy fatty acids as well as a series of wax esters containing these mono- and dihydroxy lipids are reported. Selective extraction of Azolla surface lipids revealed that these compounds are most likely present in the leaf waxes of the fern. The suite of long-chain, mid-chain ω20 hydroxy wax constituents is described for the first time. As they are well preserved in the Eocene sediments, these lipids may serve as palaeo-environmental indicators of the Arctic Azolla interval and as markers for the past occurrence of Azolla in general.     

Small angle X-ray scattering mapping and kinetics study of sub-critical CO2 sorption by two Australian coals

Time- and position-resolved synchrotron small angle X-ray scattering data were acquired from samples of two Australian coal seams: Bulli seam (Bulli 4, R_o = 1.42%, Sydney Basin), which naturally contains CO₂ and Baralaba seam (R_o = 0.67%, Bowen Basin), a potential candidate for sequestering CO₂. This experimental approach has provided unique, pore-size-specific insights into the kinetics of CO₂ sorption in the micro- and small mesopores (diameter 5 to 175 Å) and the density of the sorbed CO₂ at reservoir-like conditions of temperature and hydrostatic pressure.For both samples, at pressures above 5 bar, the density of CO₂ confined in pores was found to be uniform, with no densification in near-wall regions. In the Bulli 4 sample, CO₂ first flooded the slit pores between polyaromatic sheets. In the pore-size range analysed, the confined CO₂ density was close to that of the free CO₂. The kinetics data are too noisy for reliable quantitative analysis, but qualitatively indicate faster kinetics in mineral-matter-rich regions.In the Baralaba sample, CO₂ preferentially invaded the smallest micropores and the confined CO₂ density was up to five times that of the free CO₂. Faster CO₂ sorption kinetics was found to be correlated with higher mineral matter content but, the mineral-matter-rich regions had lower-density CO₂ confined in their pores. Remarkably, the kinetics was pore-size dependent, being faster for smaller pores.These results suggest that injection into the permeable section of an interbedded coal-clastic sequence could provide a viable combination of reasonable injectivity and high sorption capacity.     

Organochlorine pesticides in fish from the southern Baltic Sea: levels, bioaccumulation features and temporal trends during the 1995-2006 period

The levels of HCH isomers, HCB and summation DDTs were determined in five species of Baltic fish collected during 1995-2006. Some downward time trends of HCH isomer, pp'-DDE and pp'-DDD concentrations in Baltic fish were observed; in contrast, HCB and DDT concentrations did not exhibit any obvious trend. Concentrations of summation HCHs expressed on a lipid weight basis were very similar in all species studied. In contrast, concentrations of summation DDTs varied in tested species. The most abundant HCH isomer was beta-HCH and among DDT-related compounds, pp'-DDE prevailed. In our investigations the sampling sites were not a crucial factor for organochlorine pesticide concentrations and patterns observed in fish, but the occurrence of several inter-species differences in the bioaccumulation features of OC pesticides were observed. For cod there was a positive correlation between fish size (length) and summation DDT concentration. In herring, sprat and salmon samples, summation DDT concentrations were negatively correlated with fat content.     

Diversity and conservation status of large branchiopods (Crustacea) in ponds of western Poland

A survey on temporary ponds has been conducted in search for large branchiopod crustaceans (Anostraca, Notostraca, Spinicaudata and Laevicaudata) in Wielkopolska province (western Poland). 728 pools have been studied and large branchiopods have been found in 221 of them. Seven species have been recorded, including three anostracans: Branchipus schaefferi, Chirocephalus shadini and Eubranchipus grubii; two notostracans: Lepidurus apus and Triops cancriformis; one spinicaudatan, Cyzicus tetracerus and one laevicaudatan, Lynceus brachyurus. According to the analysis of co-occurrence, the species form three groups, differing in habitat preferences and conservation status. The number of species shows that the diversity of globally threatened large branchiopods is still relatively high in the region. On the other hand, their conservation status is highly diverse and in most species unfavourable. Distribution of all species is highly clustered: large branchiopods have been generally found in 33 UTM squares (10 × 10 km) of 96 squares studied. However, only two species, i.e. E. grubii and L. apus occurred in more than five such squares and could be assessed as moderately widespread. Most water bodies inhabited by large branchiopods occur in groups forming patches of suitable habitats which are dispersed among prevailing seemingly unsuitable areas. Sustaining the existence of large metapopulations seems, therefore, to be essential for conservation of branchiopod species diversity. Field observations also bring some examples of human activities unintentionally supporting the branchiopod conservation.     

New U-Pb zircon and Ar/Ar muscovite age constraints on the emplacement of the Lizio syn-tectonic granite (Armorican Massif, France)

LA-ICP-MS U-Pb analyses performed on zircon grains from the Lizio granite yielded an emplacement age of 316 ± 6 Ma. Typical S-C structures show that the Lizio granite was emplaced contemporaneously with dextral shearing along the northern branch of the South Armorican Shear Zone and that it was therefore active at that time. ⁴⁰Ar/³⁹Ar analyses performed on muscovite grains yielded plateau dates ranging between 311.5 and 308.2 Ma. Muscovite chemistry is typical of primary magmatic muscovite, which precludes a late fluids-induced resetting of the K-Ar isotopic system. ⁴⁰Ar/³⁹Ar dates thus likely correspond to the cooling ages below the argon closure temperature. Considering the uncertainties on the measured ages, we can propose that either the Lizio granite cooled down quickly in less than a million of years or that it remained in a hot environment for several millions of years after its emplacement. This latter scenario could have been sustained by shear heating during dextral shearing along the northern branch of the South Armorican Shear Zone.     

Intercomparison of Sensible Heat Flux from Large Aperture Scintillometer and Eddy Covariance Methods: Field Experiment over a Homogeneous Semi-arid Region

Scintillometers are becoming increasingly popular for the validation of satellite remote sensing sensible heat-flux estimates due to the comparable spatial resolutions. However, it is important to gain confidence in the accuracy of the sensible heat-flux measurements obtained by the scintillometer. Large aperture scintillometer (LAS) and eddy-covariance (EC) measurements were collected over a homogeneous, dry and semi-arid region near Las Cruces, New Mexico, USA, where the homogeneity allowed direct comparison of the two instruments despite their differences in footprint sizes. The differences between the sensible heat-flux measured by both LAS and EC systems fall within the differences between two EC systems. We conclude that the large aperture scintillometer is a reliable system for measuring sensible heat flux in a dry semiarid region.     

New data on the Indus Kohistan seismic zone and its extension into the Hazara–Kashmir Syntaxis, NW Himalayas of Pakistan

This paper deals with the data obtained from local networks in northern Pakistan for 251 earthquakes of magnitude ≥4.0 for October 8, 2005 to December 31, 2006 period. The study presents focal mechanism solutions (FMS) of 12 pre- (1904–2005) and 17 post- (October 8, 2005–December, 2005) Muzaffarabad Earthquake, their detailed tectonic interpretation, and correlation with surface evidence of co-seismic rupture with published synthetic aperture radar data. Distribution of landslides obtained from National Engineering Services of Pakistan and the earthquake damages are also discussed. Aftershock distribution, which is more prominent in the crystalline zone (northwest of Muzaffarabad), defines a 50-km-wide NW–SE trending zone that extends for 200 km from the main mantle thrust to the center of the Hazara–Kashmir Syntaxis. The FMS of the main shock and 16 aftershocks having magnitude ≥4.0 indicate thrusting to be the dominant mechanism with rupture planes having NW–SE trend and NE dip. In addition, 12 FMS of pre-Muzaffarabad Earthquake (1904–2004) from the same area have been determined and results are compared. This leads to the conclusion that the wedge-shaped NW–SE trending blind zone, referred to by earlier workers as the Indus Kohistan Seismic Zone (IKSZ), has been activated during the Muzaffarabad earthquake. The right-lateral component in all FMS, supported by the surface evidences, suggests the involvement of Balakot–Bagh Fault (BBF). We propose that the IKSZ is the source of the October 8, 2005 Muzaffarabad earthquake that reactivated the BBF. Furthermore, the IKSZ does not end at the nose of the syntaxis but extends further southeast of it. Tectonic complexity seems to be due to a variety of factors. Also, thrust and reverse solutions near the northern collisional boundary (main mantle thrust) have mostly NE/SW-directed P-axis orientations. From the detailed FMS analysis, three conclusions have been drawn: (1) Shallow events (depth ≤10 km) with prominent strike slip solutions (earlier earthquakes) are associated with the surface strike slip faults (e.g., Muzaffarabad Fault) and/or the Besham domal structure; (2) moderate depth events (depth 10–25 km) with thrust/reverse solutions but having minor right-lateral strike slip component (all Muzaffarabad earthquakes and two earlier) are associated with the IKSZ; (3) deeper earthquakes (depth below IKSZ) with pure thrust/reverse solutions may be related to the under-thrusting of the Indian plate beneath the IKSZ, which represents a major thrust zone. Imbricate thrusting and breaking and thickening of the crust are considered to be caused by steep bending of the under-thrusting plate at the collisional boundary. An erratum to this article can be found at     

Cenozoic erosion and sediment yield in the drainage area of the Storfjorden Fan

The western Barents Sea continental margin, between 74° and 77°N, comprises 7–8 km post-Paleocene sediments. The margin sediments have been divided into four seismic sequences dated by seismic correlation to adjacent areas. This chronostratigraphy shows that the uppermost three sequences are of glacial origin, deposited during the last 2.3 m.y. A huge sedimentary wedge, the Storfjorden Fan, was deposited in front of the Storfjorden Trough between 2.3 and 0.44 Ma, whereas during the last 0.44 m.y. a more evenly distribution pattern is observed. The outbuilding of the fan is related to the onset of the northern hemisphere glaciations causing intense glacial erosion of predominantly consolidated rocks. Seismic facies interpretations indicates that the fan outbuilding was connected to large-scale mass movements. Within the uppermost part of the glacial sequence parallel and continuous reflectors and locally disturbed pattern on the upper slope are associated with downslope change in facies. Volumetric calculations, based on velocity studies and isopach maps, have been used to quantify Cenozoic erosion, sediment yield, sedimentation and erosion rates. Approximately 3300 m of post-Paleocene erosion is calculated within the drainage area of the Storfjorden Fan, of which about 1700 m was eroded in late Pliocene-Pleistocene times giving an average denudation rate of 0.63 mm/yr.     

Geophysical Field Pattern in The West Bohemian Geodynamic Active Area

Regional geophysical data from detailed gravity survey, airborne magnetometry and gamma-ray spectrometry were analysed in order to determine the subsurface extent of contrasting geological bodies and to highlight subtle anomalies which can be related to the occurrence of earthquake swarms. Potential field data were compiled into contour and colour-shaded relief maps suitable for detecting structural tectonic elements. A shaded relief map of the horizontal gradient of gravity was used to detect considerable structural and tectonic features. The results of airborne gamma-ray spectrometry, showing the regional total gamma-ray activity, abundance of uranium, thorium and potassium, were included in this study. Only the two most instructive maps – the total gamma-ray activity and the abundance of potassium are shown. The main line of epicentres Nový Kostel – Poátky coincides well with the N-S configuration of abundances of these natural radioactive elements. The epicentres of micro-earthquakes detected by the local seismological network KRASLICE for the 1991 to 1998 period were plotted in the geophysical maps. The hypocentres of earthquakes in the main epicentral zone at Nový Kostel were projected onto the crustal density model based on the interpretation of seismic reflection profile 9HR and gravity data. The average distance between the Nový Kostel epicentral zone and the seismic profile was 4-5 km. Based on the interpretation of gravity data the hypocentres of the main epicentral zone seem to be associated with the western margin of the Eibenstock - Nejdek (Karlovy Vary) Pluton and, beside that, they follow the depth level where the allochthonnous part of the Saxothuringian Zone is thrust over the European parautochton. A drawing of the geodynamic model of the area is also shown.     

青海省东部农业区冰雹天气特征分析及预警指标研究

采用青海省东部农业区14个地面气象站冰雹观测资料,对2003-2017年青海东部农业区冰雹天气进行特征分析,利用天气雷达、高空、雷电观测资料对2003-2017年青海东部农业区20例典型冰雹天气个例进行分析研究。得出：(1)冰雹和雹灾集中出现在每年5-9月,冰雹天气7月最多,冰雹成灾8月最多。(2)0 ℃层高度变化对冰雹融化作用不明显;高空垂直风切变比对流有效位能更有指示意义。(3)冰雹雷达回波顶高普遍大于10 km,冰雹直径与回波顶高的线性相关强于冰雹直径与强回波中心高度的线性相关;垂直累积液态水含量普遍大于20 kg?m-2且垂直累积液态水含量增量大于10 kg?m-2时易发生雹灾;风暴顶部辐散正负速度差值对雹灾预警有指示意义,但与冰雹直径无明显相关性。(4)不同冰雹云产生的闪电频次差别很大,同一雹云相同时间内正闪次数越多,则降雹直径越大。利用以上结论统计得出冰雹预警指标、权重和预警区间,通过对预警指标进行历史回代和预报检验,历史回代拟合率达86.9％,预警准确率为80％。