Evaporative weathering of petroleum residues: The age of pelagic tar

The rate of evaporative weathering of a component of crude oil residue is assumed to be proportional to its equilibrium vapor pressure and to the amount remaining in the sample. This model is tested using literature data on normal paraffin profiles of crude oil weathered artificially and gas chromatographic data on crude oil residues weathered on rocky shores. Semiquantitative agreement over the time range from 1 to 400 days is demonstrated. Application of the model to gas chromatograms of pelagic tar lumps collected at Station S near Bermuda in 1972 implies that most of these lumps were formed by fragmentation of much larger and older masses, some within less than one day of the time they were collected. The weathering of pelagic tar thus involves a great deal more physical fragmentation than was previously supposed.     

Seasonal methyltin and (3-dimethylsulphonio)propionate concentrations in leaf tissue of Spartina alterniflora of the Great Bay estuary (NH)

Concentrations of total recoverable inorganic tin (TRISn), monomethyltin (MeSn³⁺), dimethyltin (Me₂Sn²⁺), trimethyltin (Me₃Sn⁺) and (3-dimethylsulphonio)propionate (DMSP) were determined in leaves of Spartina alterniflora from three sites in the Great Bay estuary (NH) from 8 May to 15 September 1989. Total methyltin concentration increased from 8·9 ng g⁻¹ (fresh weight) on 8 May to 472 ng g⁻¹ on 23 May, decreased to 52 ng g⁻¹ on 7 June and 16ng g⁻¹ on 20 June, and remained low until the last sample on 18 September. Statistical calculations showed that methyltin concentrations varied significantly with sampling week, but not with site. DMSP concentrations showed very different behaviour. During the same sampling period DMSP concentrations varied only from 7·5 to 26 μmol g⁻¹ (fresh weight). DMSP concentrations varied significantly for site, but not sampling week.     

Monitoring the status of a mechanical cable while in operation by means of the acoustic emission method

The mechanical cable is an essential element in towing operations, remote control of equipment, salvage operations, civil engineering applications, etc.Failure of these cables can result in loss of life and loss of equipment worth hundreds of thousands of dollars. Obviously then, sensors that can indicate the condition of these cables so that the risk to their continued use and their remaining safe life can be determined when in operation are very important from the point of view of commercial and military interest.This paper presents a brief review of research into failure mechanisms of various cables and the acoustic emission signatures of the various cables under simulated loading. The development of a specific operational monitor for a towed cable system is also given.     

Spatial Variation in the Structure of Kelp Forest Communities Along a Wave Exposure Gradient

Abstract. Four sites were sampled in kelp (Macrocysiis pyrifera) forests occupying rocky bottom habitats along a wave exposure gradient in central California. Consistent betwecn-site differences were found in the three major structural elements - the surface canopy, the undcrstory assemblage, and the ground cover/turf assemblage - of kelp forest communities. Macrocysiis pyrifera was found at all four sites. Nereucyslis tuelkeana only at the most exposed site. The understory kelps Laminaria setchellii and Pterygopltora californica were also characteristic of exposed sites. Articulated coralline algae were more abundant at exposed sites than protected, while fleshy red algae showed the opposite pattern. All four study sites were located along 8.5 km of coastline, and thus were assumed to have available to them the same species pool for colonization. The substrate composition was the same and the amount of unconsolidated substrate was similar at all four sites. We suggest that exposure to wave-generated water motion, through its influence on the surface canopy and therefore on the amount of light reaching the bottom, is responsible for these between-site differences.     

Observations of natural fluorescence with an underwater radiometer

Measurements of subsurface irradiance spectra in the ocean consistently indicate intensities of long-wavelength visible light (589 nm) greater than could be derived from the penetration of sunlight. This can be attributed to natural fluorescence and/or to spectral crosstalk due to light leakage through the blocking filters of each discrete detector. A comparison of observed profiles with modelled contributions from these two possible sources indicates that both factors are contributing. At 671 and 694 nm wavelength, the excess signal appears to be predominantly fluorescence while that at 589 nm is mostly crosstalk. Both effects appear to be important at 625 nm although the amount of excess light is small compared to the other wavelengths.The above observations and interpretations are consistent with the optical design of the instrument used and the shape of natural irradiance spectra. Fluorescence efficiencies derived from the irradiance measurements correlate well with measuredin situ fluorescence.     

A detailed magnetic study of the Reykjanes Ridge between 63°00′N and 63°40′N

Immediately southwest of Iceland, the Reykjanes Ridge consists of a series ofen échelon, elongate ridges superposed on an elevated, smooth plateau. We have interpreted a detailed magnetic study of the portion of the Reykjanes Ridge between 63°00N and 63°40N on the Icelandic insular shelf. Because the seafloor is very shallow in our survey area (100–500 m), the surface magnetic survey is equivalent to a high-sensitivity, nearbottom experiment using a deep-towed magnetometer. We have performed two-dimensional inversions of the magnetic data along profiles perpendicular to the volcanic ridges. The inversions, which yield the magnetization distribution responsible for the observed magnetic field, allow us to locate the zones of most recent volcanism and to measure spreading rates accurately. We estimate the average half spreading rate over the last 0.72 m.y. to have been 10 mm/yr within the survey area. The two-dimensional inversions allow us also to measure polarity transition widths, which provide an indirect measure of the width of the zone of crustal accretion. We find a mean transition width on the order of 4.5±1.6 km. The observed range of transition widths (2 to 8.4 km) and their mean value are characteristic of slow-spreading centers, where the locus of crustal accretion may be prone to lateral shifts depending on the availability of magmatic sources. These results suggest that, despite the unique volcanotectonic setting of the Reykjanes Ridge, the scale at which crustal accretion occurs along it may be similar to that at which it occurs along other slow-spreading centers. The polarity transition width measurements suggest a zone of crustal accretion 4–9 km wide. This value is consistent with the observed width of volcanic systems of the Reykjanes Peninsula. The magnetization amplitudes inferred from our inversions are in general agreement with NRM intensity values of dredge samples measured by De Boer (1975) and ourselves. Our thermomagnetic measurements do not support the hypothesis that the low amplitude of magnetic anomalies near Iceland is the result of a high oxidation state of the basalts. We suggest that the observed reduction in magnetic anomaly amplitude toward Iceland may be the result of an increase in the size of pillows and other igneous units.     

The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.     

A seasonal survey of the sterol composition of the cockle cerastoderma edule: A comparison of polluted and non-polluted environments

The sterol composition of a cockle population from an unpolluted environment in South Wales was monitored by monthly sampling over a 12-month period. In spite of the likely variation in dietary sterols during this period, the component sterols of the cockles showed no significant seasonal variation, indicating that the cockle was able to exhibit a high degree of control over the composition of its functional sterols.Dramatic differences were observed in the sterol compositions of a nearby cockle population from a highly polluted environment, near a sewage outfall; only three out of the ten sterols present were common to the unpolluted cockles. Forty-five per cent of the sterols from the ‘polluted’ samples contained fully reduced systems and included three new alkylated C-29, C-30 and C-31 stanols. It is considered possible that these structural changes may affect the stereochemistry of the functional sterols and hence alter the permeability of the animal's membranes. This may reflect a biochemical response to the polluted environment.