Age and isotopic studies of some Pan-African granites from North-Central Nigeria

Twenty-nine Rb-Sr whole-rock isotopic analyses and three U-Pb zircon analyses on foliated granites and largely unfoliated charnockitic rocks indicate that the central part of the Pan-African belt in west Africa was characterised by intense orogenic plutonism. These data and Rb-Sr analyses on muscovite books from late cross-cutting pegmatites indicate that the peak of magmatic activity occurred 610 ± 10 m.y. ago.Initial ⁸⁷Sr/⁸⁶Sr ratios for the granitic and charnockitic rocks are in the range 0.7065–0.7125, and indicate a significantly older crustal component in the magmas.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

Subpollen Particles as Atmospheric Cloud Condensation Nuclei

Izvestiya, Atmospheric and Oceanic Physics - Bioparticles constitute a significant fraction of atmospheric aerosol. Their size range varies from nanometers (macromolecules) to hundreds of...     

A climatological data set of temperature and salinity for the Baltic Sea and the North Sea

Ocean Dynamics - A climatological monthly mean data set for temperature and salinity in the area of the North Sea and Baltic Sea is presented. More than 3.1 million temperature observations (2.9...     

Hydrodynamic and dynamic analysis to determine the directional stability of an underwater vehicle near a free surface

A theoretical methodology to determine the open-loop directional stability of a near-surface underwater vehicle is presented. It involves a solution of coupled sway and yaw equations of motion in a manner similar to that carried out for surface ships. The stability derivatives are obtained numerically through simulation of motions corresponding to planar motion mechanism (PMM) model tests. For the numerical simulation, a boundary-integral method based on the mixed Lagrangian-Eulerian formulation is developed. The free-surface effect on the vehicle stability is determined by comparing the results with that obtained for vehicle motion in infinite fluid. The methodology was used to determine the stability of the Florida Atlantic University’s Ocean EXplorer (OEX) AUV. The presence of the free surface, through radiation damping, is found to suppress unsteady oscillations and thereby enhance the directional stability of the vehicle. With effects of free surface, forward speed, location and geometry of rudders, location of the center of gravity etc. all being significant factors affecting stability, a general conclusion cannot be drawn on their combined effect on the vehicle stability. The present computational methodology is therefore a useful tool to determine an underwater vehicle’s stability for a given configuration and thus the viability of an intended mission a priori.     

Concerning the multiscale structure of solar convection

The discrete scale spectrum of the convective flows observed on the Sun has not yet received a convincing explanation. Here, an attempt is made to find conditions for the coexistence of convective flows on various scales in a horizontal fluid layer heated from below, where the thermal diffusivity varies with temperature in such a way that the static temperature difference across a thin sublayer near the upper surface of the layer is many times larger than the temperature variation across the remainder of the layer. The equations of two-dimensional thermal convection are solved numerically in an extended Boussinesq approximation, which admits thermal-diffusivity variations. The no-slip conditions are assumed at the lower boundary of the layer; either no-slip or free-slip conditions, at the upper boundary. In the former case, stable large-scale rolls develop, which experience small deformations under the action of small structures concentrated near the horizontal boundaries. In the latter case, the flow structure is highly variable, different flow scales dominate at different heights, the number of large rolls is not constant, and a sort of intermittency occurs: the enhancement of the small-scale flow component is frequently accompanied by the weakening of the large-scale one, and vice versa. The scale-splitting effects revealed here should manifest themselves in one way or another in the structure of solar convection.     

A numerical study of the nocturnal heat island over a medium-sized mid-latitude city (Columbus,Ohio)

A numerical investigation is conducted of the nocturnal heat island over Columbus, Ohio, a relatively flat mid-latitude city. Specifically, a cross-sectional steady-state numerical model to simulate the (thermal) structure of the nocturnal urban boundary layer is developed from a one-dimensional, time-dependent model due to Estoque. The model is applied to Columbus for special periods in September 1968 and March 1969 during which comparable experimental data were collected. The numerical simulations agree well with the observed data with respect to the detailed spatial form of the surface-based thermal boundary layer across the city. The use of the model for other metropolitan areas, for ascertaining the relative effect of city size and building geometry on the development of the thermal boundary layer, and for determining the effect of alternate land-use strategies on the thermal stratification are also discussed.Digest of portion of a dissertation submitted to the Pennsylvania State University in partial fulfillment of the requirements for the degree of Doctor of Philosophy.Presented in part at the Air Pollution, Turbulence and Diffusion Symposium, Las Cruces, New Mexico, 7–10 December 1971.On assignment from the National Oceanic and Atmospheric Administration (NOAA), U.S. Department of Commerce.     

A Unified Variational Principle of Fluid Mechanics and Application on Solitary Subdomain or Point

-According to basic equations of fluid mechanics, this paper presents a unified variational principle of fluid mechanics (UVPFM) by using the optimization method of weighted residuals (OMWR). The advantages are as follows, the establishment of the functional and the variational principle is easy, it can change various problems of fluid mechanics derived by basic equations into a unified optimization problem, and the solution is the optimum one in some sense. According to the OMWR for the solitary subdomain, this paper uses UVPFM onto any solitary subdomain and gives the solution of the hydrodynamics equation which is suitable only for that solitary subdomain. According to the OMWR for solitary point, this paper uses UVPFM to any solitary point and gives the solution of the hydrodynamics equation (point solution) which is suitable only for that solitary point. As the solution for the solitary subdomain or solitary point is developed independently, the compatibility with other subdomain or other points, do