It all comes out in the wash: Actualistic petrofacies modeling of temper provenance,Tonto Basin,Arizona, USA

Prehistoric potters frequently tempered their pottery with sand, the provenance of which can be established petrographically. In the Tonto Basin of central Arizona, the bedrock geology is highly variable, giving rise to geographically unique sands. Zones of sands with similar compositions can be modeled at an archaeologically relevant scale. Here we use the actualistic petrofacies concept, the Gazzi–Dickinson point‐counting technique, and multivariate statistics to create a petrofacies model, then apply it to sand‐tempered utilitarian pottery recovered from three Tonto Basin project areas. Data analysis reveals strong temporal and spatial ceramic production and consumption patterns. Production of pottery for exchange was established in at least one petrofacies ca. A.D. 600–950, with increasing specialization through time. By ca. A.D. 1150, corrugated wares had been added, and specialized production by ware was established in two petrofacies. Provenance evidence suggests different regional affiliations for groups in different parts of the basin. © 2001 John Wiley & Sons, Inc.     

Influence of IHSS Standard and Reference Materials on Copper and Mercury Toxicity to Vibrio fischeri

The reduction in light emission of the marine bacterium Vibrio fischeri used in the standard Microtox^® bioassay was measured for the metals copper and mercury. The concentration at which the light emission was reduced by 50% (EC₅₀) was determined to be (3.43 ± 0.83) μmol/L for Cu²⁺ and (0.66 ± 0.01) μmol/L for Hg²⁺. The reduction of the toxicity of these metals by humic and fulvic acids were studied using IHSS Standard and Reference Materials. Copper toxicity was reduced 17...20% by the soil and peat fulvic acids and 9...20% by the aquatic fulvic acids. While there appeared to be little difference in the reduction of Cu toxicity by fulvic acids from soils, peats, or aquatic systems, Hg toxicity was reduced 3.6...7.3% by the soils and peats, while aquatic fulvic acids reduced Hg toxicity 14...16%. Soil fulvic acids appear to have significantly less capacity to reduce Hg toxicity than Cu toxicity. Humic acids had much higher reductions of Cu toxicity (44...124%) compared to the fulvic acids, with little difference between aquatic and soil or peat humic acids, 44...124% and 67...100%, respectively. However, humic and fulvic acids, regardless of origin, had approximately the same effect on Hg toxicity with 3.5...16% reduction by fulvic acids and 8...20% reduction by humic acids. Unlike the fulvic acids, no clear trend was observed relative to origin of the humic acids. There was no correlation between percent reduction of Cu or Hg toxicity by the organic compounds and copper binding capacity (CuBC), C/N ratio, or carboxyl content of the materials. Examination of natural organic matter (NOM) isolated by reverse osmosis techniques from three water sources had reductions of both Cu and Hg toxicity that were most similar to the Suwannee River and Nordic fulvic acids.     

Turbidity and suspended sediment dynamics in small catchments in the Nepal Middle Hills

The Himalayan environment has, until recently, been perceived to be in a critical state of environmental decline, resulting from rapid population growth and associated land‐use change. Recent research, however, has emphasized the difficulty of developing an objective appraisal of the state of the environment in a region where empirical data are scarce and unstructured and where an understanding of the spatial and temporal dynamics of natural environmental processes remains highly uncertain. This paper presents results from an intensive three‐year project designed to help address the regional empirical deficit, establish detailed baseline environmental data and to gain an insight into storm period and seasonal suspended sediment dynamics. The instrumentation, calibration and analysis of high‐frequency infrared turbidimetric records from a number of small subcatchments in the Nepal Middle Hills are reported. Storm period and seasonal variation in turbidity and suspended sediment are examined and hysteresis patterns explored and explained. A variety of methods to estimate seasonal suspended sediment yield in a mixed land‐use catchment are examined, and found to vary by up to a factor of five. Despite the inherent uncertainty, all estimates of catchment sediment yield are found to be high with respect to erosion plot studies from the local area, and this suggests the importance of riparian and channel erosion as major sediment sources, a finding consistent with other regional studies. Copyright © 2000 John Wiley & Sons, Ltd.     

The use of caesium‐137 to estimate agricultural erosion on steep slopes in a tropical watershed

The estimation of erosion and sediment delivery rates in tropical mountain watersheds is difficult and most of the methods widely used for estimating soil erosion over large areas have serious limitations. The ¹³⁷Cs approach has potential for quantifying soil erosion because it can provide retrospective estimates of long‐term (since 1963) net sediment redistribution relatively quickly. Despite its great potential, ¹³⁷Cs has not yet been used in an extensive, reconnaissance level survey of erosion in complex tropical mountain environments. The objective of this study was to examine the applicability of the ¹³⁷Cs method to estimate erosion on steep tropical agricultural lands (23 to 80% slopes) in the Nizao watershed, a humid, tropical mountain area of the Dominican Republic. In this study we (i) examine the variation of ¹³⁷Cs in ten reference sites—eight coffee groves and two forested sites—and (ii) estimate erosion from 14 cultivated fields. The soil pool of ¹³⁷Cs ranged from to 150 to 192 mBq cm⁻² on reference sites with minimal erosion. Variability among reference sites was less than expected for such complex mountain terrain. The variability within coffee and forested reference (average CV=28%) sites was similar to the variability found on grassland and forested reference sites in the temperate zone. The estimated annual soil loss from 14 sampled fields ranged from 6 to 61 t ha⁻¹ year⁻¹ with an overall mean of 26 t ha⁻¹ year⁻¹. Overall, the soil erosion estimates found using the ¹³⁷Cs method were much lower than those often assumed for such steep tropical hillsides. These erosion estimates account for soil loss since 1963 only and it seems likely that soil losses may have been much higher in earlier decades immediately after initial forest clearing earlier in the 20th century. Copyright © 2000 John Wiley & Sons, Ltd.     

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas,Kansas, Missouri and Oklahoma,USA

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.     

Modelling road surface sediment production using a vector geographic information system

Field investigations indicate that unpaved roads are the largest sediment source on St John, US Virgin Islands. Cross-sectional measurements of eroded road surfaces were used to establish an empirical relationship to predict annual road surface erosion as a function of road gradient and contributing drainage area. A model (ROADMOD) for estimating and mapping average annual sediment production from a road network was developed by combining this empirical relationship with a series of network algorithms to analyse road data stored in a vector geographic information system. ROADMOD was used to estimate road surface erosion in two St John catchments with very different road densities but similar land cover, topography and soils. Unpaved roads were found to increase sediment production in the more densely roaded catchment by a factor of three to eight, and in the less-roaded catchment by a factor of 1·3–2·0. Turbidity measurements in the receiving bays of these two catchments are consistent with model predictions and observed sediment delivery processes. Although this model was developed specifically for St John, it can easily be adapted to other locations by substituting a locally derived predictive equation for road erosion. Model assumptions, limitations and potential improvements are discussed. © 1998 John Wiley & Sons, Ltd.     

Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.     

Floodplain sedimentation and sensitivity: summer 1993 flood,Upper Mississippi River Valley

Patterns of overbank sedimentation in the vicinity of, and far removed from, levee breaks that occurred in response to the >100 year, summer 1993 flood in the upper Mississippi River valley are elucidated. Two suites of overbank deposits were associated with the failure of artificial levees within a 70 km long study reach. Circumjacent sand deposits are a component of the levee break complex that develops in the immediate vicinity of a break site. As epitomized by the levee break complex at Sny Island, these features consist of an erosional, scoured and/or stripped zone, together with a horseshoe-shaped, depositional zone. At locales farther removed from the break site, the impact of flooding was exclusively depositional and was attributed to the settling of suspended sediment from the water column. The overall picture was one of modest scour at break sites and minimal suspended deposition (<4 mm) at locales farther removed from the breach. Downriver from the confluence with the Missouri River, suspended sediment deposition was of a similar magnitude to that observed within the study reach and levee break complexes exhibited a similar morphology, but scour at break sites was greatly enhanced and the excavated sand formed extensive deposits on the floodplain surface. The different erosional response was probably engendered by the higher sand content and reduced aggregate cohesion of the floodplain soils downriver from the confluence with the Missouri River. A qualitative comparison serves to highlight the influence that the resistance threshold may have on the sensitivity of floodplains bordering large low-gradient rivers to high magnitude floods. © 1997 John Wiley & Sons, Ltd.