Mineralogical changes during thermal demagnetization of natural continental sandstones

We study the mineralogical changes suffered by specimens of natural miocene red and green continental sandstones (from Pozuelos Formation and Tiomayo Formation) cropping out in the Argentine Puna that increase their bulk magnetic susceptibility and change color when thermally treated. We hypothesize that on heating siderite, which is present in small quantities as cement in the studied sandstones, would oxidize and decompose into maghemite and/or magnetite. Subsequent heating to higher temperatures sometimes would bring about the conversion of maghemite and/or magnetite to hematite. Mössbauer spectroscopy proved to be a very valuable tool for the determination of the presence of siderite in small amounts in the studied samples. The present results show that further work is needed in order to fully understand the mineralogical changes suffered by continental sandstones during heating. The characterization of such changes occurred during laboratory routines is relevant, since they can help to better understand natural processes.     

Passive Seismic Experiment Mosaic - A Pilot Study of Mantle Lithosphere Anisotropy of the Bohemian Massif

We present results of an array study of seismic anisotropy beneath the Bohemian Massif (BM) showing distinct lateral and directional variations of the fast shear-wave polarization and split-delay time consistent with variations in the P-residual spheres, in which directional means of relative residuals are subtracted. Our analysis of the S- and P-wave anisotropy suggests that the mantle lithosphere of the BM consists of at least three large domains with different orientation of the large-scale fabric separated by sutures cutting most likely the whole lithosphere. Boundaries of the units are characterised by a null or small shear-wave splitting, as well as by smaller values in the P-residual spheres. We present self-consistent 3D anisotropic models of the lithosphere domains of the BM resulting from joint inversion of anisotropic parameters searching for a 3D orientation of mantle fabric. While in the Saxothuringian and Sudetes parts of the BM the (a, c) foliations dip prevailingly to the N-NW, they dip to the S and SW in the southern and eastern parts of the Moldanubian.     

Assessment of the Geochemical Background and Anthropogenic Load by Bioaccumulation of Microelements in Fish

Comparative characteristic of several microelements (Ni, Cu, Sr, Al, Zn, Co, Mn, Pb, Cd, Hg, As) found in fish (case study of breams in the Volga basin reservoirs) is presented. Regularities of accumulation of these elements in fish depending on their concentration in the water are analyzed. Main disturbances in fish caused by the accumulation of microelements in their organs and tissues are considered.     

Preferential embrittlement of graphitic schists during extensional unroofing in the Alps: the effect of fluid composition on rheology in low-permeability rocks

Interlayered graphitic and non‐graphitic schists from the Tauern Window, Eastern Alps, record contrasting mechanical behaviour during extensional exhumation. Graphitic schists contain mesoscale extension fractures, pervasive microcracks in garnet, and abundant secondary fluid inclusion planes; all three types of structures are oriented perpendicular to the stretching lineation. Crack spacings in garnet from graphitic samples are tightly clustered around a mean of 180 μm. Non‐graphitic schists have fewer and more randomly oriented microcracks and fluid inclusion planes and maintained strain compatibility via crystal plasticity. The presence or absence of graphite appears to have exerted a fundamental control on rheology during unroofing. Calculations for a model graphitic rock at 500 °C and f_O2 = 10^?24 MPa show that the equilibrium metamorphic fluid evolves from X_CO2 = 0.07 to 0.38 during decompression from 700 to 400 MPa, in agreement with microcrack fluid inclusion data that show a change from X_CO2 < 0.1 to 0.45 in graphitic samples over the same pressure interval. This compositional shift results in >60% expansion of the pore fluid during decompression. H₂O‐rich fluid in non‐graphitic rocks expands <15% over the same pressure interval. The greater pore fluid expansion in low‐permeability graphitic horizons likely promoted tensile failure during unroofing. These results suggest that microcracking should be an inevitable consequence of decompression in many graphitic schists, whereas rocks that lack graphite are less likely to undergo microcracking. Microseismicity is predicted to be more common in graphitic than non‐graphitic rocks during unroofing of mountain belts.