Analysis of Triphenyltin in Fish

A procedure to analyse triphenyltin and other organotins in fish tissues is described. The method consists of the following steps: homogenization of the fish, extraction by heating under reflux in a water/hexane mixture, centrifugation, separation of the hexane layer followed by reduction of the volume by evaporation, methylation of the organotin with a Grignard reaction, clean-up of the fish extract by column chromatography, and detection by gas chromatography with flame photometric detection. The extraction was carried out without adding acid or base to the aqueous phase, as the extraction efficiency was independent of pH. The methylation was successfully carried out in the fish extract. For clean-up of the fish extract a florisil column was used, from which the triphenylmethyltin was eluted with hexane. Using this method, triphenyltin has a recovery of 77 ± 10%, with a limit of detection of 0·8 ng/g for 0·1 g fish samples.     

Mechanisms controlling the temporal variation of the sea ice edge in the Southern Ocean

This paper examines the mechanism controlling the short time-scale variation of sea ice cover over the Southern Ocean. Sea ice concentration and ice velocity datasets derived from images of the Defense Meteorological Satellite Program (DMSP) Special Sensor Microwave Imager (SSM/I) are employed to reveal this mechanism. The contribution of both dynamic and thermodynamic processes to the change in ice edge location is examined by comparing the meridional velocity of ice edge displacement and sea ice drift. In the winter expansion phase, the thermodynamic process of new ice production off the ice edge plays an important role in daily advances of ice cover, whereas daily retreats are mostly due to southward ice drift. On the other hand, both advance and retreat of ice edges in the spring contraction phase are mostly caused by the dynamic process of the ice drift. Based on the above mechanism and the linear relation between the degree of ice production at the ice edge and northward wind speed, the seasonal advance of ice cover can be roughly reproduced using the meridional velocity of ice drift at the ice edge.     

The Levant Slumps and the Phoenician Structures: collapse features along the continental margin of the southeastern Mediterranean Sea

Two distinct series of slumps deform the upper part of the sedimentary sequence along the continental margin of the Levant. One series is found along the base of the continental slope, where it overlies the disrupted eastern edge of the Messinian evaporites. The second series of slumps transects the continental margin from the shelf break to the Levant Basin. It seemed that the two series were triggered by two unrelated, though contemporaneous, processes. The shore-parallel slumps were initiated by basinwards flow of the Messinian salt, that carried along the overlying Plio-Quaternary sediments. Seawater that percolated along the detachment faults dissolved the underlying salt to form distinctly disrupted structures. The slope-normal slumps are located on top of large canyons that cut into the pre-Messinian sedimentary rocks. A layer of salt is found in the canyons, and the Plio-Quaternary sediments were deposited on that layer. The slumps are bounded by large, NW-trending faults where post-Messinian faulted offset was measured. We presume that the flow of the salt in the canyons also drives the slope-normal slumps. Thus thin-skinned halokynetic processes generated the composite post-Tortonian structural patterns of the Levant margin. The Phoenician Structures are a prime example of the collapse of a distal continental margin due to the dissolution of a massive salt layer.     

On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.     

Robust Range-Only Beacon Localization

In this paper, we present a system capable of simultaneously estimating the position of an autonomous underwater vehicle (AUV) and the positions of stationary range-only beacons. Notably, our system does not require beacon positions a priori, and our system performs well even when range measurements are severely degraded by noise and outliers. We present a powerful outlier rejection method that can identify groups of range measurements that are consistent with each other, and a method for initializing beacon positions in an extended Kalman filter (EKF). We have successfully applied our algorithms to real-world data and have demonstrated a simultaneous localization and mapping (SLAM) system whose navigation performance is comparable to that of systems that assume known beacon locations     

A climatology of mesoscale model simulated low-level wind jets over Cook Inlet and Shelikof Strait, Alaska

Weather in the North Gulf of Alaska is characterized by a high frequency of deep synoptic-scale low-pressure systems, especially during the cold season. The strong pressure gradients of these storms interact with the extremely rugged terrain of the coastal mountains to produce a variety of channeled flows. These surface wind regimes are not well documented in the scientific community, due to the paucity of observations. Modeling of these phenomena in regions of complex terrain is of great interest to those working with hydrodynamic, wave, and pollutant transport models in coastal and shelf areas. Such models, when coupled with ocean and coastal-ecology counterparts, give a broad view of the role surface winds play in shaping local coastal marine ecosystem in this region. This paper presents a climatology of simulated low-level wind jets over the domain of Cook Inlet and Shelikof Strait along Alaska's south-central coast. Daily simulations using the RAMS model were conducted in a 36-h forecast mode for the cold-season period 10/1/03 to 3/31/04. Systematic analysis of the resulting simulated low-level wind field makes it possible to characterize these jets and gap flows in spatial and temporal detail. The comparison between the RAMS winds and the Synthetic Aperture Radar (SAR)-derived winds when available verifies the existence of these wind jets and the capability of the model to simulate these cases. Clearly, the results of a study in this region depend on the fidelity of the model at these scales (O[5 km]). The SAR comparisons attempt to help establish this. From the 6 months of simulations over Cook Inlet and Shelikof Strait, the low-level wind jets are classified into 10 different regimes by location and orientation. These regimes are categorized into four more general groups: cross-channel westerly, easterly, and up and down Inlet flows. The nature of a particular regime is largely a function of pressure gradient orientation and local topography. Jets in the same group have a similar occurrence distribution with time. Some form of jet occurred in the study region almost daily each month of the period, with December 2003 having the highest frequency of wind jets.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

黄、东海环流的数值研究Ⅲ——正压环流的数值模拟

依据黄、东海环流的的动力学模型 ,运用“流速分解法”对黄、东海正压环流进行了数值模拟。计算结果表明冬季黄海正压环流主要受风应力影响 ,基本形态为黄海暖流由济州岛西南进入南黄海中部 ,其东西两侧分别为两支向南流动的沿岸流 ;夏季主要受到潮致体力的影响 ,为一逆时针涡旋。东海环流主要是边界力作用驱动的结果 ,东海黑潮、台湾暖流和对马暖流较稳定。冬季风应力对东海环流表层流场有消弱作用 ,在夏季则有一定增强作用。