Evaluation of hydrogeochemical parameters and quality assessment of the groundwater in Kottur blocks, Tiruvarur district, Tamilnadu, India

A study was conducted to evaluate the water quality of Kottur block, Thiruvarur district, Tamilnadu. Groundwater samples from hand pumps and tube wells of 16 stations were analyzed during postmonsoon and premonsoon (2008) with the help of standard methods of APHA (1995). Dominance of cations are in the following order Na>Ca>K>Mg and Cl>SO₄>HCO₃>NO₃ by anions in both the seasons. The analytical results shows higher concentration of total dissolved solids, electrical conductivity, sodium, chloride, and sulfate which indicate signs of deterioration but values of pH, calcium, magnesium, and nitrate are within permissible limit as per World Health Organization standards. From the Piper trilinear diagram, it is observed that the majority of groundwater samples are Na-Cl and Ca-Mg-SO₄ facies clearly indicates seawater incursion. In Wilcox diagram, most of the samples fall in low to very high sodium hazard and low to very high salinity hazard indicates moderately suitable for agricultural activities. Kelly’s ratio and magnesium ratio indicates most of the samples fall in suitable for irrigation purpose.     

Propagation of Coronal Mass Ejections Observed During the Rising Phase of Solar Cycle 24

In this study, we investigate the interplanetary consequences and travel time details of 58 coronal mass ejections (CMEs) in the Sun–Earth distance. The CMEs considered are halo and partial halo events of width \({>}\,120\)°. These CMEs occurred during 2009?–?2013, in the ascending phase of the Solar Cycle 24. Moreover, they are Earth-directed events that originated close to the centre of the solar disk (within about \(\pm30\)° from the Sun’s centre) and propagated approximately along the Sun–Earth line. For each CME, the onset time and the initial speed have been estimated from the white-light images observed by the LASCO coronagraphs onboard the SOHO space mission. These CMEs cover an initial speed range of \({\sim}\,260\,\mbox{--}\,2700~\mbox{km}\,\mbox{s}^{-1}\). For these CMEs, the associated interplanetary shocks (IP shocks) and interplanetary CMEs (ICMEs) at the near-Earth environment have been identified from in-situ solar wind measurements available at the OMNI data base. Most of these events have been associated with moderate to intense IP shocks. However, these events have caused only weak to moderate geomagnetic storms in the Earth’s magnetosphere. The relationship of the travel time with the initial speed of the CME has been compared with the observations made in the previous Cycle 23, during 1996?–?2004. In the present study, for a given initial speed of the CME, the travel time and the speed at 1 AU suggest that the CME was most likely not much affected by the drag caused by the slow-speed dominated heliosphere. Additionally, the weak geomagnetic storms and moderate IP shocks associated with the current set of Earth-directed CMEs indicate magnetically weak CME events of Cycle 24. The magnetic energy that is available to propagate CME and cause geomagnetic storm could be significantly low.     

Long-term increase in diffuse groundwater recharge following expansion of rainfed cultivation in the Sahel,West Africa

Rapid population growth in sub-Saharan West Africa and related cropland expansion were shown in some places to have increased focused recharge through ponds, raising the water table. To estimate changes in diffuse recharge, the water content and matric potential were monitored during 2009 and 2010, and modeling was performed using the Hydrus-1D code for two field sites in southwest Niger: (1) fallow land and (2) rainfed millet cropland. Monitoring results of the upper 10 m showed increased water content and matric potential to greater depth under rainfed cropland (>2.5 m) than under fallow land (≤1.0 m). Model simulations indicate that conversion from fallow land to rainfed cropland (1) increases vadose-zone water storage and (2) should increase drainage flux (～25 mm year^?1) at 10-m depth after a 30–60 year lag. Therefore, observed regional increases in groundwater storage may increasingly result from diffuse recharge, which could compensate, at least in part, groundwater withdrawal due to observed expansion in irrigated surfaces; and hence, contribute to mitigate food crises in the Sahel.     

Forecasting future changes in Manzala Lake surface area by considering variations in land use and land cover using remote sensing approach

This study assesses the changes in surface area of Manzala Lake, the largest coastal lake in Egypt, with respect to changes in land use and land cover based on a multi-temporal classification process. A regression model is provided to predict the temporal changes in the different detected classes and to assess the sustainability of the lake waterbody. Remote sensing is an effective method for detecting the impact of anthropogenic activities on the surface area of a lagoon such as Manzala Lake. The techniques used in this study include unsupervised classification, Mahalanobis distance supervised classification, minimum distance supervised classification, maximum likelihood supervised classification, and normalized difference water index. Data extracted from satellite images are used to predict the future temporal change in each class, using a statistical regression model and considering calibration, validation, and prediction phases. It was found that the maximum likelihood classification technique has the highest overall accuracy of 93.33%. This technique is selected to observe the changes in the surface area of the lake for the period from 1984 to 2015. Study results show that the waterbody surface area of the lake declined by 46% and the area of floating vegetation, islands, and land agriculture increased by 153.52, 42.86, and 42.35% respectively during the study period. Linear regression model prediction indicates that the waterbody surface area of the lake will decrease by 25.24% during the period from 2015 to 2030, which reflects the negative impact of human activities on lake sustainability represented by a severe reduction of the waterbody area.     

Kinematics of the eastern Caucasus near Baku, Azerbaijan

The potential for large, shallow earthquakes and their associated seismic hazard in the eastern Caucasus, an area of dense population and sensitive industrial infrastructure, remains speculative based on historical precedent and current geologic and seismologic observations. Here we present updated and expanded results from a GPS network between the northern edge of the Lesser Caucasus and Greater Caucasus, providing geodetic constraints to the problem. A significant strain rate is observed in a profile over a distance of about 150?km across the Kura Basin. We attribute this to inter-seismic strain accumulation on buried fault structures and present simple elastic dislocation models for their plausible geometry and slip rate based on the known geology, seismicity and the GPS velocities. Due to the close proximity of the strain anomaly to Baku, further observations are needed to determine whether observed contraction is due to inter-seismically locked faults and, if so, implications for the seismic hazard in the region.     

Geochemistry,zircon UPb ages and Hf isotopes of granites and pegmatites from Gubrunde region in the Eastern Nigeria Terrane: Insight into magmatism and tectonic evolution of the late Pan-African orogeny

This study reports a new dataset of whole-rock geochemistry, biotite chemistry, in situ zircon UPb geochronology and Hf isotope for a suite of granite and associated pegmatite samples from the Gubrunde region in the Eastern Nigeria Terrane (ENT), Nigeria. The Gubrunde granitic rocks are weakly ferroan, peraluminous and calc-alkalic to alkali-calcic in composition, and show I-type affinity. The zircon UPb geochronology gives an age of ~580 Ma for the rocks, although the presence of inherited zircons with early Pan-African ages of 696 ± 12, 647 ± 7 and 624–613 Ma are evident indicative of a complex history of their source rocks. The Gubrunde granite and the pegmatite yielded similar average Hf crustal model age T_DM2 of 1.9 ± 0.1 Ga and εHf(t) values ?6.2 ± 1.2, suggesting that they may have sourced from reworked old crustal rocks with minor contributions from the mantle. The granite and the pegmatite were likely to connect by fractional crystallization under low to moderate pressure (~2.2 to 3.0 kbar) and temperature (~717 °C), and low oxygen fugacity (<ΔNNO ?1.14). The ca. 580 Ma magmatism may have been triggered by delamination of the lithospheric mantle as a consequence of crustal thinning during waning stage of the Pan-African orogeny.     

Environmental impact of Gümüşhane City,Turkey, waste area in terms of heavy metal pollution

China has become the biggest CO₂ emitter in the world. In China, economic development in different regions is not the same. Thus, it is necessary to study the regional decoupling relationship between energy-related CO₂ emission and economic development. Considering the regional difference of economic development, energy consumption and CO₂ emission, provincial regions in China are divided into seven economic bands. The Tapio decoupling method is adopted to calculate the decoupling index in the seven regions over the study period 1996–2013. Furthermore, the WCDM is developed to study the driving factors governing the decoupling state. The result showed that decoupling development differed in each economic band; North-East and North-West, showed a better trend and a worse one, respectively, than the others. Economic factor showed a stable trend of negative effect, and energy intensity factor was the crucial factor to accelerate the process of CO₂ emission decoupling. Only in Yangtze River delta, economic band had structural factor shown a positive effect during the research period, and emission efficiency factor was not stable and showed a negative effect in most years in every region.     

Discovery and Significance of Diamonds and Moissanites in Chromitite within the Skenderbeu Massif of the Mirdita Zone Ophiolite, West Albania

In recent years diamonds and other unusual minerals(carbides,nitrides,metal alloys and native elements) have been recovered from mantle peridotites and chromitites(both high-Cr chromitites and high-Al chromitites) from a number of ophiolites of different ages and tectonic settings.Here we report a similar assemblage of minerals from the Skenderbeu massif of the Mirdita zone ophiolite,west Albania.So far,more than 20 grains of microdiamonds and 30 grains of moissanites(SiC) have been separated from the podiform chromitite.The diamonds are mostly light yellow,transparent,euhedral crystals,200~300 μm across,with a range of morphologies;some are octahedral and cuboctahedron and others are elongate and irregular.Secondary electron images show that some grains have well-developed striatums.All the diamond grains have been analyzed and yielded typical Raman spectra with a shift at ~1325 cm~(-1).The moissanite grains recovered from the Skenderbeu chromitites are mainly light blue to dark blue,but some are yellow to light yeUow.All the analyzed grains have typical Raman spectra with shifts at 766 cm~(-1),787 cm~(-1),and 967 cm~(-1).The energy spectrums of the moissanites confirm that the grains are composed entirely of silicon and carbon.This investigation expands the occurrence of diamonds and moissanites to Mesozoic ophiolites in the Neo-Tethys.Our new findings suggest that diamonds and moissanites are present,and probably ubiquitous in the oceanic mantle and can provide new perspectives and avenues for research on the origin of ophiolites and podiform chromitites.     

Groundwater management scenarios for the Biyadh-Wasia aquifer systems in the eastern part of Riyadh region,Saudi Arabia

Groundwater stored in the deep seated sedimentary aquifers is the most important source of water supply. The lack of sufficient groundwater recharge and the overdependence on groundwater might lead to unavailability of this precious natural resource if proper management practices are not adopted. Finite difference modelling using the MODFLOW program was carried out in the east of Riyadh city to simulate the groundwater level conditions under different abstraction scenarios. The simulated aquifer system combines the Wasia and Biyadh aquifer (composed of sandstone) and Aruma aquifer (limestone) which lies between 24°30'00"- 25°30'00" N and longitudes 47°00'00"- 48°00'00"E. The transmissivity and storage coefficient values of Biyadh aquifer are 7.0x10^-3 to 7.0x10^-2 m²/day and 3.7x10^-4 to 9.4x10^-4 respectively. The transmissivity and storage coefficient values of Wasia aquifer ranges from 6.7x10^-3 to 8.5x10^-2 m²/day and 2x10^-4 to 2.3x10^-4 respectively. The model calibration involved altering the values of model input parameters to match field conditions within certain acceptable limits to forecast the aquifer response over a period of 35 years (2015-2050). The modelling grid consisted of 20 and 24 columns with the grids spacing of 4 km for the small grids and 6 km for large grids. The results showed that though the Wasia aquifer was productive, it showed a large decline in water levels if water abstraction continued at the present rate. If the existing trends of groundwater withdraw continues; the piezometric heads in Wasia and Biyadh aquifers will decline by the year 2050. A reduction in 25% of the existing groundwater pumping rate in the well field will minimize the rate of groundwater decline in the aquifer to a considerable extent.