Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.     

Geophysical signature of the vien-type uranium mineralization of Wadi Eishimbai, Southern Eastern Desert, Egypt

The application of various geophysical tools with different responses succeeded in fixing U-mineralization in Wadi Eishimbai area. The area was studied using detailed ground spectrometric, magnetic, and filtered very low-frequency electromagnetic (VLF-EM) surveys. The interpretation of the obtained spectrometric maps clearly reflects the sharp increase of equivalent uranium (eU) content. Meanwhile, K and Th contents show sharp decreases. The eU/equivalent thorium (eTh) ratio correlates positively with eU concentrations and negatively with eTh concentrations, indicating an increase in U potentiality than the surrounding granite. The N?CS shear zone displays an eU content ranging from 20 to 140?ppm. The ENE-trending lamprophyre is characterized by elongated uranium anomalies trending in the E?CW direction, with values >90?ppm. Equivalent uranium content of the brecciated granite attains values up to 700?ppm. The ground magnetic and VLF-EM surveys played important roles in providing structural information which are proven useful in geological mapping and mineral exploration for the discovery of uranium mineralization in the study area. This study follows the expected subsurface extension of the Sela shear zone under Wadi sediments. The ground total magnetic intensity map shows a relatively narrow and an elongated shape for the lamprophyre anomaly extending for about 600?m in the Wadi toward the western direction. VLF-EM contour maps of the two used frequencies (17.1 and 28.5?kHz) show excellent agreement, indicating that the shear zone is distinguished with slightly strong conductivity westwards as an extension of the main shear zone. It is elongated in an ENE?CWSW trend and extends in the western direction, referring to the existence of conductive materials. Most of the NW/SE-trending faults cause sudden changes in the magnetic and VLF-EM contour spacing over an appreciable distance, which suggests a discontinuity in depth due to their left-lateral strike-slip displacements. The interpreted faults, with an ENE?CWSW trend representing the main trend of Sela shear zone through which hydrothermal solutions flowed, cause high alteration and uranium mineralization.     

Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.     

Occurrence of diagenetic pseudobreccias within the paleokarst zone of the upper Dammam Formation in Kuwait, Arabian Gulf

A paleokarstic zone capping the Middle Eocene dolomitic Dammam Formation delineates a regional disconformity with the overlying Mio-Pleistocene fluvial deposits in Kuwait. This formation outcrops in a quarry located in the southeast of Kuwait and occurs in the subsurface of Umm Ghudair water field, west Kuwait. Karstification has affected the upper member of the Dammam Formation, which is formed of extensively chertified, vuggy chalky biodolomicrite. Karstification is manifested by two phases: a dissolution phase that was responsible for the occurrence of surface and near surface karst features and a precipitation phase during which a karst carapace and dolocretic and calcitic pseudobreccias were developed. Petrographic investigations of both the biodolomicrites host rock and the karst lithotypes revealed a complex diagenetic history that encompasses the following diagenetic events, arranged in a chronological order: (a) replacive dolomitization, (b) precipitative dolomitization, (c) precipitative silica, (d) replacive silica, (e) karstification, (f) development of karst carapace [calcretization and calcitization (development of calcitic psuedobreccia)], (g) dolocretization (development of dolocretic psuedobreccia), (h) mild karstification, (i) calcite precipitation, and (j) silica precipitation. The development of the karst carapace at the unconformity surface between the Eocene Dammam Formation dolomicrites and the overlying Mio-Pleistocene Kuwait Group clastics has played a significant role in the hydrological characteristics of Kuwait usable groundwater resources. It is recommended that the occurrence of similar diagenetic processes within the Arabian carbonate shelf deposits be investigated.     

The best fitting distribution of annual maximum rainfall in Peninsular Malaysia based on methods of L-moment and LQ-moment

This paper discusses patterns of annual and monthly precipitation variability at seven weather stations in east central Europe (1851–2007). Precipitation patterns were compared to three simple regional indices of atmospheric circulation, i.e., western circulation, southern circulation and the cyclonicity (C) index and a relationship between precipitation and the North Atlantic Oscillation index was identified. Correlations of the monthly records and multiple regression, using a principal components’ analysis, helped determine the statistical significance of the dependence of precipitation on the circulation indices. The Mann–Kendall test revealed no trend to change in any of the precipitation series, but a certain spatial regularity could be discerned in the phase of the annual periodic component. A common feature of the variability in central European annual precipitation is the dry period identified in the 1980s and the first half of the 1990s. In the northern part of the region, above-average precipitation was noted from the 1960s through to the mid-1970s as a result of the frequent prevalence of depressions. South of the divide, the wettest period was recorded at the turn of 1930s/1940s. After a number of very wet years in the last decade of the twentieth century and the beginning of the twenty-first century, precipitation began to fall at all of the region’s weather stations. The C index is the strongest circulation-linked factor influencing precipitation in central Europe and it accounts for more than 40% of the variance in spatially averaged wintertime precipitation.     

Quantification of the urban heat island under a changing climate over Anatolian Peninsula

The Anatolian Peninsula is located at the confluence of Europe, Asia, and Africa and houses 81 cities of which 79 of them have population over 100,000. We employed some criteria to select the cities from the 81 cities. After accomplishing all the criteria, eight cities were remaining for the study. Nonparametric Mann–Kendall test procedure was employed for the urban and rural stations of these cities to detect the long-term change in temperature trends. Statistical analysis of daily minimum temperatures for the period between 1965 and 2006 suggest that there is no statistically significant increase in rural areas. In contrast to the findings of the previous studies, however, all the urban sites and difference between urban and rural pairs show significant increase in temperatures, a strong indication for the existence of urban heat island (UHI) affect over the region. Regional Climate Model was also utilized to assess the changes in temperature by the end of century for the region. The findings suggest that an increase of up to 5°C is possible. Climate change effects enforced with UHI have the potential to cause serious problems for the entire region and hence needs to be studied thoroughly.     

Paleomagnetism of Carboniferous sediments from the West Sudetes (SW Poland)

The studied Carboniferous flysch and molasse sediments from the Intra-Sudetic Basin correspond to the period from Middle Visean to Early Autunian. Main magnetic minerals carrying the natural remanent magnetization (NRM) are goethite, magnetite, maghemite and hematite, all usually secondarily formed and/or remagnetized due to several tectonometamorphic events. In most samples several NRM components were isolated. One of them is usually a Jurassic-Triassic overprint. Some others define the Westphalian-Early Permian segment of the declination and inclination trajectory for the Sudetes calculated according to the reference apparent polar wander path for the Baltica plate. The Sudetic path is slightly shifted to the east compared to the reference path, suggesting the possibility of independent movements of the Sudetes during this time. The majority of isolated NRM components are secondary and related to the Sudetic orogenic phase and later tectonometamorphic activity.     

Effect of hot dry summer tropical climate on forage intake and milk yield in Holstein–Friesian and indigenous zebu cows in Sudan

The effects of dry summer ambient temperature on some physiological and productive responses were studied in an exotic European breed (Holstein–Friesian) and a local zebu breed (Butana ecotype) of cattle in Sudan. Rectal temperature and respiration rate were positively correlated, and dry matter intake and milk yield were negatively correlated with variation in ambient temperature. However, significant adverse effects on high ambient temperature were only observed in the exotic breed.