Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province

Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well.     

pp′-DDT adsorption to suspended particulate matter in sea water

A procedure was devised to study pp′-DDT [2,2-bis($\text{p-}\text{chlorophenyl}$)-1,1,1-trichloroethane] adsorption and desorption to suspended particulates in aqueous solutions. DDT adsorption to a marine sediment, sediment fractions, clay and humic acid suspended in sea water was investigated and the humic fraction was found to have a greater adsorbing capacity than the clay or sediment. Removal of the humic fraction from sediment reduced the adsorption capacity to less than 60 per cent of the original sediment sample. It was concluded that suspended humic particulates may be important agents for transporting chlorinated hydrocarbons through the water column and for concentrating them in sediments and in detritus-feeding organisms.     

Kinetic and equilibrium study of Ni(II) sorption from aqueous solutions onto Peganum harmala-L

In this study, the adsorption behavior of Ni(II) in an aqueous solution system using natural adsorbent Peganum harmala-L was measured via batch mode. The prepared sorbent was characterized by scanning electron microscope, Fourier transform infrared spectroscopy, N₂ adsorption–desorption and pH_zpc. Adsorption experiments were carried out by varying several conditions such as contact time, metal ion concentration and pH to assess kinetic and equilibrium parameters. The equilibrium data were analyzed based on the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms. Kinetic data were analyzed using the pseudo-first-order, pseudo-second-order and intra-particular diffusion models. Experimental data showed that at contact time 60 min, metal ion concentration 50 mg/L and pH 6, a maximum amount of Ni(II) ions can be removed. The experimental data were best described by the Langmuir isotherm model as is evident from the high R ² value of 0.988. The adsorption capacity (q _m) obtained was 68.02 mg/g at an initial pH of 6 and a temperature of 25 °C. Kinetic studies of the adsorption showed that equilibrium was reached within 60 min of contact and the adsorption process followed the pseudo-first-order model. The obtained results show that P. harmala-L can be used as an effective and a natural low-cost adsorbent for the removal of Ni(II) from aqueous solutions.     

Phase Petrology and Mineral Chemistry of Coexisting Amphiboles from Telemark, Norway

Electron microprobe analyses of coexisting amphiboles, garnet,and cordierite in specimens collected from a single outcropprovide the basis for phase diagrams thought to be representativeof fixed external conditions in the sillimanite zone. A projectionthrough the compositions of quartz and plagioclase is employedto characterize the mineral facies and to facilitate comparisonswith other metamorphic terrains. Limiting recalculations whichbracket the possible range of Fe⁺³ contents in calcic amphiboleanalyses by electron probe permit an additional projection throughthe composition of magnetite, a ubiquitous phase. From thesedata the apparent non-ideality exhibited by various combinationsof coexisting cumming-tonite, anthophyllite, gedrite, and calcicamphibole is explained by intracrystalline cation ordering.     

Constraints on the timing of granite emplacement, deformation and metamorphism in the Shamva area, Zimbabwe

In order to constrain the temporal relationship between granite (sensu lato) emplacement and metamorphism, isotope work was carried out on the minerals zircon and apatite (U-Pb), garnet (Pb-Pb) and hornblende (Ar-Ar) from wall rock samples in the Shamva area in Zimbabwe. The area, encompassing parts of the Chinamora and Murehwa batholiths and a wedge-shaped greenstone belt segment in between, is commonly quoted in the literature as an example illustrating pluton emplacement processes and deformational models for the Archean. New U-Pb dating of apatite from a boudinaged pegmatite within mafic schists in the batholith-greenstone contact zone has yielded an age of 2619 +28/-24 Ma. This age is interpreted as the best estimation of the intrusion age of this unit, depending on the assumed closure temperature, and provides an upper age limit for the syntectonic emplacement of the now gneissic granites. Pb-Pb dating of late kinematic garnets in cordierite-bearing rocks within the greenstone belt wall rocks gives an age of 2623NJ Ma. Together, this timing of relatively late, syntectonic plutonism and metamorphic mineral growth at ca. 2.62 Ga compares well with existing zircon crystallization ages for felsic volcanics (2645dž Ma, 2643NJ Ma) and post-tectonic porphyritic monzogranites (2601ᆢ Ma). Ar-Ar hornblende ages for mafic schists from different areas within the greenstone belt wall rocks range between 2621 and 2498 Ma and have been interpreted to indicate mixing between metamorphic ages and cooling ages. The data support a geological model whereby volcanism and sedimentation are associated with an early phase of regional deformation at ca. 2.64 Ga, which may have started earlier and lasted longer, and evolves into the voluminous emplacement of granites (now gneissic granites) in the batholiths at approximately 2.62 Ga. Emplacement of post-tectonic tabular monzogranites takes place at ca. 2.60 Ga.     

A study on soil physico-chemical, microbial and metal content in Sukinda chromite mine of Odisha, India

Soil samples from chromite mining site and its adjacent overburden dumps and fallow land of Sukinda, Odisha, were analysed for their physico-chemical, microbial and metal contents. Chromite mine soils were heterogenous mixture of clay, mud, minerals and rocks. The pH of the soils ranges between 5.87 and 7.36. The nutrient contents of the mine soils (N, P, K and organic C) were found to be extremely low. Analysis of chromite mine soils revealed accumulation of a number of metals in high concentrations (Fe > Cr > Mn > Ni > Zn > Pb > Sr) which exceeded ecotoxicological limits in soil. Correlation and cluster analysis of metals revealed a strong relation between Cr, Ni, Fe, Mn among the different attributes studied. Assessment of different microbial groups such as fungi, actinomycetes and bacteria (heterotrophic, spore forming, free-living nitrogen fixing, phosphate solubilising and cellulose degrading) from mine soils were found to be either extremely low or absent in some soil samples. Further chromium tolerant bacteria (CTB) were isolated using 100 mg/L Cr(VI) enriched nutrient agar medium and were screened for their tolerance towards increasing concentrations of hexavalent chromium and other toxic metals. Out of 23 CTB isolates, three bacteria tolerated up to 900 mg/L, 6 up to 500 mg/L, 20 up to 200 mg/L of Cr(VI). These bacteria were also found to be sensitive towards Cu > Co > Cd and very few CTB strains could show multiple metal tolerance. These strains have great scope for their application in bioremediation of toxic chromium ions in presence of other metals ions, which needs to be explored for their biotechnological applications.     

Petrogenesis and chronology of lunar meteorite Northwest Africa 4472: A KREEPy regolith breccia from the Moon

Northwest Africa (NWA) 4472 is a polymict lunar regolith meteorite. The sample is KREEP-rich (high concentrations of potassium, rare earth elements and phosphorus) and comprises a heterogeneous array of lithic and mineral fragments. These clasts and mineral fragments were sourced from a range of lunar rock types including the lunar High Magnesian Suite, the High Alkali Suite, KREEP basalts, mare basalts and a variety of impact crater environments. The KREEP-rich nature of NWA 4472 indicates that the sample was ejected from regolith on the nearside of the Moon in the Procellarum KREEP Terrane and we have used Lunar Prospector gamma-ray remote sensing data to show that the meteorite is most similar to (and most likely sourced from) regoliths adjacent to the Imbrium impact basin.U-Pb and Pb-Pb age dates of NWA 4472 phosphate phases reveal that the breccia has sampled Pre-Nectarian (4.35 Ga) rocks related to early episodes of KREEP driven magmatism. Some younger phosphate U-Pb and Pb-Pb age dates are likely indicative of impact resetting events at 3.9-4 Ga, consistent with the suggested timing of basin formation on the Moon. Our study also shows that NWA 4472 has sampled impact melts and glass with an alkali-depleted, incompatible trace element-rich (high Sc, low Rb/Th ratios, low K) compositional signature not related to typical Apollo high-K KREEP, or that sampled by KREEPy lunar meteorite Sayh al Uhaymir (SaU) 169. This provides evidence that there are numerous sources of KREEP-rich protoliths on the Moon.     

Phase relations of pyroxene and amphibole in greenstone,blueschist and eclogite of the Franciscan Complex,California

The phase relations of pyroxenes, amphiboles and associated minerals in metamorphic rocks of the Franciscan Complex can be graphically depicted on a ternary diagram which has at its apices the metamorphic clinopyroxene end members, viz NaAl-NaFe³⁺-Ca(Fe²⁺, Mg). Phases are plotted by projection from a constant subassemblage of minerals. This analysis allows interpretation of the effects of pressure, temperature, bulk rock composition and fluid composition on stability of minerals within the Franciscan.Pyroxenes in meta-igneous rocks and metagraywackes have a limited compositional range and fall into two groups: the omphacites, with 50±5% diopside +hedenbergite component; and the jadeitic pyroxenes with 10±5% diopside+hedenbergite. Pyroxenes intermediate between these two groups are unstable relative to assemblages containing Na-amphibole+other minerals.Coexisting pyroxenes and amphiboles in eclogites and associated coarse blueschists comprise equilibrium assemblages, and the proportion of pyroxene to amphibole is a function of rock composition. Eclogites are stable at higher temperature than regionally developed fine-grained greenstones and blueschists in the Franciscan, and at higher pressure than amphibolites. X _H2O ^fluid is not an important factor in the stability of Franciscan eclogite relative to amphibolite.     

The Late Cretaceous Impact of the Trindade Mantle Plume: Evidence from Large-volume, Mafic, Potassic Magmatism in SE Brazil

When the subcontinental lithospheric mantle undergoes heatingand/or extension, some of the earliest mafic melts to be generatedare those rich in volatUes and potassium. In some cases, e.g.when a plume impinges on thick cratonic lithosphere or whenthe amount of extension is very small, K-rich mafic igneousrocks may be the only surface expression of mantle melting.The Alto Paranaiba Igneous Province, in SE Brazil, is one ofthe world's most voluminous mafic potassic provinces (>15000km³),which until recently was relatively unknown. The magmas wereemplaced into a narrow Proterozoic mobile belt close to thesurface margin of the Sao Francisco craton, and it is one ofseveral Cretaceous alkaline igneous provinces that are locatedaround the margin of the Parana sedimentary basin in Braziland Paraguay.Detailed geochemical analyses of samples from throughoutthe Alto Paranaiba Igneous Province show that it is composedof a relatively diverse suite of ultrapotassic-potassic, ultramaficmqfic,silica-undersaturated lavas and hypabyssal intrusions, i.e.kimberlites, madupitic olivine lamproites and kamafugitic rocks.These all have very high concentrations of incompatible traceelements and are all strongly enriched in light rare earth relativeto heavy rare earth elements (e.g. La/Yb=50-230). Wide variationsin major element ratios, which are unrelated to the effectsof crystal fractionation in these magmas (e.g. CaO/Al₂O₃), suggestthat the mafic potassic rocks were derived from a heterogeneousmantle source. They show relatively restricted ranges of initial⁸⁷Sr/⁸⁶Sr (070436-070588) and Nd₂₅ values of -4 to -8, intermediatebetween Group I and II South African kimberlites. T_DM Nd isotopemodel ages of 900 Ma suggest that the magmas were derived bythe remobilization of subcontinental lithospheric mantle thathad been enriched by small-volume K-rich melt fractions sincethe Late Proterozoic.New K/Ar ages for mica separates show thatthe kimberlites, madupitic olivine lamproites and kamafugiticrocks were emplaced together with large carbonatite-bearingplutonic complexes at 85 Ma. Reconstructions of plate motionsshow that, at this time, the location of the Alto ParanaibaIgneous Province coincided with the postulated position of thepresent-day Trindade(or Martin Vaz) plume. We propose that thewidespread Late Cretaceous alkaline magmatism in SE Brazil mayhave been caused by impingement of this plume on the base ofthe subcontinental lithosphere. Heat penetrating the lithosphere,both by conduction and advection by asthenospheric-source decompressionmelts, may have caused melting of the readily fusible partsof the lithospheric mantle and the genesis of mafic potassicand (after fractionation) carbonatite magmas. The Proterozoicmobile belt (the Brasilia Belt) appears to have acted as a Hhinspofrelative to the adjacent Sao Francisco craton, allowing greaterupwelling and melting of the asthenosphere. Subsequently, asthe craton passed over the plume, volcanism was switched off'until the Early Tertiary when the plume reemerged from beneaththe westward drifting South America continent and was the magmasource for oceanic-islands and seamounts of the Trindade-Vitriachain. Corresponding author     

Importance of heavy metal-organic matter interactions in natural waters

The role of organic ligands in metal complexing in natural waters has received little attention because of uncertainties regarding both the abundance and nature of dissolved organic carbon compounds. Recent data show that the bulk of dissolved organic matter in natural waters consists of highly oxidized and chemically and biologically stable polymeric compounds closely resembling soil humic substances. Average molar concentrations of these aquatic humics in major U.S. rivers range from 5 × 10^?6to 3 × 10^?5 moles 1^?1. Fractional elution of soil organic matter by meteoric waters may be considered to be the main process contributing to the presence of humic matter in rivers. The aquatic humic polymers participate in complex formation through ionizable functional groups with a range of differential acidities. The stabilities of metal-humic complexes in natural waters are higher than those of the corresponding inorganic metal complexes. Quantitative evaluation of the metal-organic interactions can be approached by applying variable equilibrium functions which take into account the differential physico-chemical characteristics of the active complexing sites on the polymer molecule. Assuming an average humic concentration of 10 mg 1^?1, complexation of trace metals can be significant even in the presence of excess concentrations of major cations.