Distribution and source apportionments of polychlorinated biphenyls (PCBs) in mariculture sediments from the Pearl River Delta, South China

Surface and core sediments collected from six mariculture farms in the Pearl River Delta (PRD) were analyzed to evaluate contamination levels of polychlorinated biphenyls (PCBs). The ∑PCBs (37 congeners) concentrations ranged from 5.10 to 11.0 ng g(-1) (mean 7.96 ng g(-1)) in surface and 3.19 to 22.1 ng g(-1) (mean 7.75 ng g(-1)) in core sediments, respectively. The concentrations were significantly higher than that measured in the sediments of their corresponding reference sites, whereby the average enrichment percentages were 62.0% and 42.7% in surface and core sediments, respectively. Significant correlations (R2=0.77, p<0.05) of PCB homologue group proportions between fish feeds and surface mariculture sediments suggested that fish feed input was probably the main source for the enrichment of PCBs. Due to the fact that PCBs could be transferred along food chains, PCB contamination in fish feeds and mariculture sediments should not be overlooked.     

A Note on Reviving the Goddard Satellite-Based Surface Turbulent Fluxes （GSSTF） Dataset

Accurate sea surface flux measurements are crucial for understanding the global water and energy cycles. The oceanic evaporation, which is a major component of the global oceanic fresh water flux, is useful for predicting oceanic circulation and transport. The global Goddard Satellite-based Surface Turbulent Fluxes Version-2 (GSSTF2; July 1987--December 2000) dateset that was officially released in 2001 has been widely used by scientific community for global energy and water cycle research, and regional and short period data analyses. We have recently been funded by NASA to resume processing the GSSTF dataset with an objective of continually producing a uniform dataset of sea surface turbulent fluxes, derived from remote sensing data. The dataset is to be reprocessed and brought up-to-date (GSSTF2b) using improved input datasets such as a recently upgraded NCEP/DOE sea surface temperature reanalysis, and an upgraded surface wind and microwave brightness temperature V6 dataset (Version 6) from the Special Sensor Microwave Imager (SSM/I) produced by Remote Sensing Systems (RSS). A second new product (GSSTF3) is further proposed with a finer temporal (12-h) and spatial (0.25^ox0.25^o) resolution. GSSTF2b (July 1987--December 2008) and GSSTF3 (July 1999--December 2009) will be released for the research community to use by late 2009 and early 2011, respectively.     

Differences in the emission line spectrum at maximum and minimum of the nuclear brightness of the Seyfert galaxy NGC 7469

We have compiled data on relative intensties, fluxes and profiles of emission lines of the NGC 7469 nuclear spectrum observed in the optical region by many authors during 1966–1986. The aim of our investigation is to reveal differences in the characteristics of the emission lines in maxima and minima of the nuclear brightness. The distinction was revealed for relative intensities, fluxes and profiles. During the extreme maxima profiles ofH ,H andH lines, colour indices of the nucleus and its high level of accretion rate resemble those of QSOs. On the other hand, during the deep minimum 1989 the nucleus had the properties of a Sy2 type. There is a relation between variable fluxes ofH and [OIII] 5007 Å lines which is different for the minima and maxima of the nuclear brightness. The fluxes of the [OIII] 5007 Å line during the minima of the nuclear brightness are systematically higher than those in maxima. The above mentioned peculiarities of the emission lines in the NGC 7469 nucleus can be understood in terms of the increase of electron temperature, electron density and velocities of the nuclear gas from minimum to maximum.     

A reconstruction of the palaeohydrological conditions of a flood‐plain: a multi‐proxy study from the Grabia River valley mire,central Poland

This study investigated the Grabia River valley mire in central Poland to reconstruct its palaeoenvironmental conditions from the Younger Dryas to the present. We analysed sedimentological, biological and geochemical data from the palaeo‐oxbow lake and valley mire to identify the principal hydrological trends, especially episodes of high water level. During the Lateglacial and Holocene, the Grabia River had a meandering channel, and its hydraulic parameters and the channel dimensions changed in response to climatic oscillations and vegetation development. We identified phases of high flood intensity and high groundwater level that correlate with regional and supraregional climatic events. The frequency and timing of palaeohydroclimatic oscillations show strong similarities to records from other sites in Poland and the rest of Europe. We show that various analytical methods, namely, pollen, plant macrofossils, Cladocera, Chironomidae, sedimentological, geochemical and radiocarbon data, can be effective tools for reconstructing past hydroclimatic changes in palaeo‐oxbow lakes and investigating the effects of past climate changes on river environments. The high sensitivity of the biota, especially Cladocera, to changes in water level permits the reconstruction of palaeoecological changes, especially flood episodes that occurred in the river valley. In particular, the increase in the proportion of sediment‐associated Cladocera and pelagic taxa was closely correlated with floods. Through comparisons with the palaeobiological data, geochemical data allowed the identification of humid phases within the fen associated with a rising groundwater table, direct fluvial activity (floods) and alluvial deposition. We also discuss the limitations of palaeohydrological reconstructions based on these proxies, especially on fossil aquatic invertebrates.     

Radiation observations at Aspendale,Australia, and their comparison with other data

Summary Results are presented of three years' measurements at Aspendale of net, global and diffuse radiation (R, G andD respectively) as well as of short-wave radiation on a north-facing surface (G _N ).The results are compared with other Australian radiation measurements, and the local character of the constants inÅngström type estimation formulae pointed out. A term is given which corrects such formulae by taking into account the uneven distribution of cloudiness over the day. The effect of orographic cloud on radiation is also discussed.After correction for climatological mean conditions, Aspendale summer values ofG are about 18% higher than those ofBlack [4] and ofBudyko [7]; the winter values agree reasonably. Summer and winter values ofR are considerably higher thanBudyko's—about 21% and 28% respectively. In addition some disagreement is found with the Australian Radiation Records 1953–1956.In winter, the amounts of diffuse and solar radiation (G-D) are about equal.

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Zusammenfassung Die Resultate dreijähriger Registrierungen der Strahlungsbilanz, der Global- und der Himmelsstrahlung (R, G undD) sowie der kurzwelligen Strahlung auf eine Nordwand (G _N ) werden mitgeteilt.Die Ergebnisse werden mit anderen australischen Strahlungsmessungen verglichen, und die örtliche Abhängigkeit der Konstanten in den vonÅngström angegebenen Formeln wird hervorgehoben. Es wird eine Korrekturgröße in die Formeln eingeführt, mit der der Einfluß der ungleichmäßigen Verteilung der Bewölkung über den Tag erfaßt werden kann. Ferner wird der Effekt der orographisch bedingten Bewölkung auf die Strahlungssummen diskutiert.Es ergibt sich, daß nach Anbringung einer Korrektur auf klimatologische Durchschnittsverhältnisse die Globalstrahlungswerte von Aspendale im Sommer ungefähr um 18% größer sind als die vonBlack [4] und vonBudyko [7] angegebenen Werte; die Winterwerte stimmen einigermaßen überein. Sommer- und Winterwerte vonR sind um ungefähr 21% und 28% größer alsBudykos Werte. Es wurden auch Unterschiede zwischenG und den Australian Radiation Records 1953–1956 festgestellt.Im Winter sind die Beträge der Himmels- und der Sonnenstrahlung (G-D) annähernd gleich.

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Résumé On décrit les résultats obtenus durant trois ans d'enregistrements du bilan du rayonnement, de la radiation globale et de celle du ciel (R, G etD), ainsi que du rayonnement d'ondes courtes reçu par une paroi exposée au nord (G _N ).Ces résultats sont alors comparés à d'autres mesures australiennes du rayonnement et l'on en tire la dépendance locale des constantes contenues dans les formules d'Ångström. On introduit ainsi un facteur de correction dans les dites formules. Ce facteur permet de tenir compte de l'influence des fluctuations de la nébulosité au cours de la journée. En outre, on discute les répercussions qu'ont les nuages orographiques sur les sommes de rayonnement.Il en résulte que, après l'application de la correction, les valeurs tirées des conditions climatologiques moyennes sont pour l'été, selon Aspendale, environ 18% supérieures à celles indiquées parBlack [4] et parBudyko [7], bien que les quantités hivernales correspondent à peu près. Les valeurs estivales et hivernales deR sont, elles, environ 21% et 28% plus importantes que celles deBudyko. On constate également une différence entreG et les «Australian Radiation Records» 1953–1956.Les valeurs de la radiation du ciel et du soleil (G-D) sont à peu près équivalentes en hiver.

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With 13 Figures     

A Multiscale Assessment of Shallow Groundwater Salinization in Michigan

Managing nonpoint-source (NPS) pollution of groundwater systems is a significant challenge because of the heterogeneous nature of the subsurface, high costs of data collection, and the multitude of scales involved. In this study, we assessed a particularly complex NPS groundwater pollution problem in Michigan, namely, the salinization of shallow aquifer systems due to natural upwelling of deep brines. We applied a system-based approach to characterize, across multiple scales, the integrated groundwater quantity–quality dynamics associated with the brine upwelling process, assimilating a variety of modeling tools and data—including statewide water well datasets scarcely used for larger scientific analysis. Specifically, we combined (1) data-driven modeling of massive amounts of groundwater/geologic information across multiple spatial scales with (2) detailed analysis of groundwater salinity dynamics and process-based flow modeling at local scales. Statewide “hotspots” were delineated and county-level severity rankings were developed based on dissolved chloride (Cl⁻) concentration percentiles. Within local hotspots, the relative impact of upwelling was determined to be controlled by: (1) streams—which act as “natural pumps” that bring deeper (more mineralized) groundwater to the surface; (2) the occurrence of nearly impervious geologic material at the surface—which restricts fresh water dilution of deeper, saline groundwater; and (3) the space–time evolution of water well withdrawals—which induces slow migration of saline groundwater from its natural course. This multiscale, data-intensive approach significantly improved our understanding of the brine upwelling processes in Michigan, and has applicability elsewhere given the growing availability of statewide water well databases.     

Redox problems in the “metallogenic specialization” of magmatic rocks and the genesis of hydrothermal ore mineralization

Considering the history and current state of the problem of the so-called metallogenic specialization of magmatic rocks, the paper places emphasis onto various aspects of the genesis of ore mineralization depending on the redox state of magmas (as a logical continuation of S. Ishihara’s works), fluids, and host rocks. These problems were inadequately poorly explored and discussed by researchers dealing with ore deposits. Various possible variants of ore-forming redox processes for different types of mineral deposits, with ore mineralization affiliated to granites (Ta, Sn, W, Mo, and Be) and mafic magmas (Au, Ag, U, Cu, Zn, Pb, As, Sb, and Hg) and, accordingly, to crustal and mantle origin, are discussed. On the basis of analyzed geological data, including those published over the past three decades, it is shown that the redox state of ore-producing magmas commonly significantly impacted not only the ore potential of magmatic complexes but also the genetic type of the ore mineralization. The redox state of the fluids predetermined the transport and precipitation speciation of metals. Influence mechanisms of hydrocarbons from sedimentary country rocks and gaseous products of their pyrolysis on ore deposition of various metals are considered. Understanding these mechanisms can be helpful for predicting the possible precipitation sites of ore mineralization of noble, radioactive, and chalcophile metals.     

Analysis of wind instability using the measurements at the chernobyl meteorological station in 2000–2010

Using the data from the Chernobyl meteorological station for 2000–2010 and the wavelet analysis, the seasonal variations are analyzed of the average daily wind speed, wind gusts, wind speed variability, and instability coefficient (the ratio of the maximum wind speed to the average wind speed for each measurement). It is revealed that all parameters have pronounced seasonal variations, and the positions of seasonal maximum and minimum values of all variables under study are shifted relative to each other. The mean values of the shift between the seasonal variations of maximum and the average wind speed amount to 60–70 days, and those of the shift between the average speed and the instability coefficient, to about 145 days. The mentioned peculiarities of the display of seasonal variations are explained by atmospheric turbulent conditions. Proposed is a model that interprets the variability of the parameters under consideration as the statistics of separate eddies in the atmosphere.     

Geochemical constraints on the origin of the late Jurassic proto-Caribbean oceanic crust in Hispaniola

The nature of the oceanic crust produced through rifting and oceanic spreading between North and South America during the Late Jurassic is a key element for the Caribbean plate tectonic model reconstruction. Located in the Cordillera Central of Hispaniola, the Loma La Monja volcano-plutonic assemblage (LMA) is composed of gabbros, dolerites, basalts, and oceanic sediments, as well as metamorphic equivalents, which represent a dismembered fragment of this proto-Caribbean oceanic crust. Petrologic and geochemical data show that the LMA have a relatively broad diversity in composition, which represent the crystallization products of a typical low-pressure tholeiitic fractionation of mid-ocean ridge basalts (MORB)-type parental magmas, ranging from N- to E-MORB. Three geochemical groups have been distinguished in the volcanic sequence: LREE-flat to slightly LREE-enriched basalts of groups II and III occur interlayered in the lower stratigraphic levels; and LREE-depleted basalts of group I in the upper levels. Mantle melt modeling suggests that group III magmas are consistent by mixing within a mantle melt column of low-degree (<1%) melts of a deep garnet lherzolite source and high-degree (>15%) melts of a shallow spinel source, and groups II and I magmas are explained with moderate to high (14–18%) and very high (>20%) fractional melting degrees of a shallower spinel mantle source, respectively. Thus, upward in the volcanic sequence of the LMA, the magmas represent progressively more extensive melting of shallower sources, in a plume-influenced spreading ridge of the proto-Caribbean oceanic crust. Nb/Y versus Zr/Y systematics combined with recent plate tectonic model reconstructions reveal that Caribbean Colombian oceanic plateau fragments in Hispaniola formed through melting of heterogeneous mantle source regions related with distinct plumes during at least from Aptian–Albian (>96 Ma) to Late Campanian.