Multidimensional statistical technique for detection of low contrast geochemical anomalies

In this article we propose an advanced technique for detecting low contrast geochemical anomalies using a set of features. There are three principal elements in this technique: (1) a statistical measure of the contrast of the anomaly, denoted as τ; (2) selection of a background population; and (3) reduction of the dimensionality of the feature space. In the frame of the model, which describes the statistical distribution of geochemical background as a multidimensional normal distribution of logarithms of concentrations, the index, τ, is a powerful test statistic for the hypothesis of abnormality of an observation. Maps of τ anomalies can be rigorously interpreted on the basis of statistical inferences. Under all equal conditions this technique allows the detection of geochemical anomalies with at least the same contrast (if the chemical elements in a background population are correlated, then even the better) as using selective extractions of metals from soil or other techniques for data processing. The advantages of the proposed technique are demonstrated both theoretically and on examples of rare-metal and copper–nickel mineral deposits.     

A cyclicity in the early brigantian (D2) limestones east of the clwydian range,north wales and its use in correlation

For the first time, minor cyclicity is described from some limestones in the lower part of the Brigantian (D2) succession of the Mold district North Wales which can be traced throughout the area enabling a detailed correlation to be established. The minor cyclicity may have been caused by eustatic sea-level fluctuations. Periods of emergence associated with each regressive phase are demonstrated by the presence of subaerial features and terrestrial deposits. The lateral persistence of the cycles is confirmed by comparison with established faunal and lithological horizons. Correlation with other cyclic Brigantian strata in Yorkshire, Derbyshire and Bristol is briefly discussed. The Asbian/Brigantian (D1/D2) boundary in North Wales is described and distinctive faunal and lithological changes similar to those in the area of the stratotype in north England have been recorded.     

Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

Archaeal Communities of Frozen Quaternary Sediments of Marine Origin on the Coast of Western Spitsbergen

Izvestiya, Atmospheric and Oceanic Physics - The archaeal composition of permafrost samples taken during the drilling of frozen marine sediments in the area of the Barentsburg coal mine on the east...     

Landslide susceptibility analysis with a heuristic approach in the Eastern Alps (Vorarlberg, Austria)

The aim of the study is landslide hazard assessment carried out on a working scale of 1:25 000. The study area within the Northern Calcareous Alps was geologically and geotechnically mapped in order to identify causes and mechanisms of active mass movements. The field surveys were digitised by a Geographical Information System and divided into data layers. The geological units were classified according to their geotechnical properties. All layers were converted into grids and spatially analysed together with a Digital Elevation Model. Comparing the layers with the inventory of active landslides, the prevailing factors leading to sliding movements were identified. Because of the complex tectonic setting and the small number of active landslides, a statistical method of hazard assessment was not applicable. Using the heuristic approach of an index method, the data layers of geotechnical class, bedding conditions, tectonic layouts, slope angles, slope orientations, vegetation and erosion were analysed. The susceptibility of each layer has been evaluated with help of bivariate statistics. The layers have been weighted with indices due to their importance iteratively and were combined into a landslide susceptibility map.     

Paleohydrology and paleoclimate records in a saline prairie lake core: mineral,isotope and organic indicators

This pilot study examines the potential of obtaining a sedimentary record of paleoenvironmental/climatic/hydrologic conditions for saline Redberry Lake in southern Saskatchewan, Canada. The tools are mineralogy, stable isotopes and pigments. The upper meter of an offshore sediment core contains 10 to 20% by weight aragonite (CaCO₃), which apparently precipitated in the water column. The ¹⁸O and ¹³C of the bulk aragonite (corrected for content of detrital calcite) vary by 4 to 5. Enrichment in ¹⁸O in aragonite is significantly correlated with pigment concentrations (chlorophyll a, phaeophytin). The ¹⁸O and pigment data provide evidence for relatively dry and/or warm conditions and high limnetic productivity for the period 2500 to 1500 yrs B.P. After 1500 B.P., the climate was apparently similar to the present, with two episodes of relatively enhanced productivity, dryness and/or warmth, at around 1000 to 900 and 500 to 200 B.P. During the past century, Redberry Lake has decreased approximately 8 m in depth and its salinity has doubled. No clear sedimentary signal was observed in response to these recent hydrologic trends. These changes have not been associated with a significant climate trend in the region, but may have been induced by land use changes in the catchment.This publication is the third of a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor for this series.     

Optical Fiber Interferometers for Referencing Surface Benchmarks to Depth

—We have developed and operated optical fiber interferometers for monitoring displace ments within boreholes, as part of a program of crustal deformation measurement. These optical fiber strainmeters—a total of twelve instruments at two sites in southern California—were installed to sense the motion of the end-monuments of much longer baseline strainmeters and tiltmeters, allowing correction for any near-surface ground movement. One of the installations was specifically designed to investigate the distribution of deformation with depth, measuring over several borehole length-intervals from 5 m to 50 m. The displacements recorded over year-long time scales along these length intervals range up to 6 mm and show internal consistency and stability at the 50 μ m level. The use of these interferometers to provide correction signals for kilometer-scale crustal strain measurements has resulted in greatly improved records.     

The Sumba enigma: Is Sumba a diapiric fore-arc nappe in process of formation?

The anomalous updomed morphological expression of Sumba island, its enigmatic lack of strong Neogene deformation and the northward morphological indentation of southern Sumbawa and Flores require explanation.The stratigraphy of Sumba may be correlated with the Cretaceous to Miocene part of the Timor allochthon. The sedimentary and eruptive rock succession in Sumba shows remarkable similarities with the allochthonous Palelo, Wiluba and Cablac deposits of Timor. In both islands the Cretaceous parts of these sequences are regarded as characteristic of fore-arc deposits built on thin continental crust.The Timor nappe is interpreted as a 5 km thick tectonic flake of the Banda fore-arc thrust onto the Australian continental margin in the mid-Pliocene collision. The postulated Sumba nappe has not yet been thrust onto the Australian margin which, in the Sumba region, has not yet converged as close to the arc as in the Timor area. The postulated Sumba nappe is interpreted as a diapiric elongated dome of the Sunda fore-arc that is being squeezed by the converging margin of Australia against the volcanic islands of Sumbawa and Flores.The absence of indications on the seismic reflection profiles for the presence of the thrust fault of the Sumba nappe may perhaps be explained by the thrusts being nearly horizontal within flat-lying strata.The Savu thrust is correlated with the probably older (pre-Late Pliocene) Wetar Suture as a major southward dipping lithospheric rupture. East of 124°E, this suture does not seem to have moved much since the mid-Pliocene collision that emplaced the nappes on Timor. However, microearthquake data suggest some activity is continuing.     

Age and geochemistry of zircon from the oldest metamorphic rocks of the Omolon Massif (Northeast Russia)

This study provides SHRIMP-RG data on zircons from garnet gedritites, the products of retrograde metamorphism of eclogite-like rocks constituting belonging to the basement of the Omolon Massif. The earliest episode recorded by oscillatory-zoned cores having high HREE and Ti contents occurred at 3.25–3.22 Ga (Paleoarchean) and is interpreted to represent an upper age limit of a metamorphic or magmatic protolith. One zircon core with a pronounced negative Eu anomaly yielded a concordant age of 2.6 Ga, which is interpreted to mark a Neoarchean episode of granite formation. The studied population of zircons provides the most distinct record of a Paleoproterozoic (1.9 Ga) event, which is marked by formation of garnet gedritites under amphibolite-facies conditions. This event is recorded by transparent recrystallization rims of preexisting large zircon grains and small newly-formed grains, which are characterized, compared with their cores, by lower crystallization temperatures and one order of magnitude lower concentrations of U, Th, and HREE, and the presence of garnet micro-inclusions.