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331.
332.
Contamination,chemical speciation and vertical distribution of heavy metals in soils of an old and large industrial zone in Northeast China 总被引:5,自引:0,他引:5
Fayun Li Zhiping Fan Pengfei Xiao Kokyo Oh Xiping Ma Wei Hou 《Environmental Geology》2009,57(8):1815-1823
Heavy metal pollution of soils has become a major concern in China as a consequence of rapid urbanization and industrialization
in recent years. However, the evaluation on soil heavy metal pollution in Shenyang, the largest heavy industrial base city
in China, has not yet been conducted. In this study, accumulation, chemical speciation, and vertical distribution Cu, Zn,
Pb and Cd in soils were studied and pollution condition was assessed in Tiexi Industrial District of Shenyang, the largest
and oldest industrial zone in Northeastern China. The results showed that in topsoil, the average concentration of total Cu,
Zn, Pb, and Cd was 209.06, 599.92, 470.19 and 8.59 mg kg−1, respectively, much higher than the national threshold limit. The values of pollution index and integrated pollution index
showed that the pollution level was Cd > Cu > Zn > Pb, and Cd, Cu and Zn belong to heavy pollution level. The residual, Fe
and Mn oxide-bound, and organic-bound species accounted for about 90%, while carbonate-bound and exchangeable species accounted
for about 10%. This study indicates that the soils in the industrial zone were widely and extremely polluted by multi-heavy
metals as a result of long-term industrial activities. 相似文献
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以不同浓度Li元素标准样品和K、Ca、Na、Mg、Fe单元素标准样品的混合溶液为研究对象,采用3根阳离子交换树脂(AG 50W X8,200~400目)填充的聚丙烯交换柱和石英交换柱对Li进行分离富集,淋洗液分别为28 mol/L HCl、015 mol/L HCl以及05 mol/L HCl 30%乙醇,淋洗液体积小,仅为38 mL。分离回收率高,均大于976%。国际标样AGV 2(相对于IRMM 016)、BHVO 2(相对于IRMM 016)和IRMM 016(相对于L SVEC)的δ7Li值分别为(513±094)‰(2σ,n=10)、(408±060)‰(2σ,n=4)和(0038±073)‰(2σ,n=10),与前人分析结果吻合,分析精度与国际同类实验室水平相当。并对比了马里兰大学同位素实验室和笔者实验室对同种岩石矿物样品的分析结果,在误差范围内具有很好的一致性。此外,对美国地质调查局提供的准标样NKT 1霞石岩(相对于IRMM 016)给出了定值,δ7Li值为(871±046)‰(2σ,n=4)。因此,本方法可用于测定天然样品的Li同位素组成。 相似文献
335.
WANG Qi IKEGAME Keita TAKAHASHI Koretaro XUE Changhu ZHANG Weinong WANG Hongxun HOU Wenfu WANG Yuming 《中国海洋大学学报(英文版)》2013,12(3):413-417
Lipids were extracted from organs of the starfish Asterias amurensis associated with different treatments(raw-control,boiling and heating),and then analyzed for lipid content,lipid oxidation index,lipid classes and fatty acid composition.Results showed that boiling softened the hard starfish shells,thus facilitating the collection of starfish organs.As compared with raw organs,the boiled organs had lower water content and higher lipid content,possibly due to the loss of water-holding capacity caused by protein denaturation.Both boiling and heating increased the peroxide value(PV),thiobarbituric acid(TBA) value and carbon value(CV) of lipids.Despite slight increases in the content of complex lipids,associated lipid composition had no substantial variations upon boiling and heating.For simple lipids,the content of 1,2-diglyceride decreased in boiled and heated organs,with free fatty acids observed on thin layer chromatography(TLC).However,neither boiling nor heating significantly changed the fatty acid compositions of simple or complex lipids in starfish organs,suggesting that these two treatments had no significant effects on complex lipids in starfish organs.Together,our results indicated that boiling of starfish soon after capture facilitated the handling and extraction of useful complex lipids consisting of abundant glucosylceramide and eicosapentaenoic acid(EPA)-bounded phospholipids. 相似文献
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337.
Wave steepness is an important characteristic of a high sea state, and is widely applied on wave propagations at ports, ships, offshore platforms, and CO2 circulation in the ocean. Obtaining wave steepness is a difficult task that depends heavily on theoretical research on wavelength distribution and direct observations. Development of remote-sensing techniques provides new opportunities to study wave steepness. At present, two formulas are proposed to estimate wave steepness from QuikSCAT and ERS-1/2 scatterometer data. We found that wave steepness retrieving is not affected by radar band, and polarization method, and that relationship of wave steepness with radar backscattering cross section is similar to that with wind. Therefore, we adopted and modified a genetic algorithm for relating wave steepness with radar backscattering cross section. Results show that the root-mean-square error of the wave steepness retrieved is 0.005 in two cases from ERS-1/2 scatterometer data and from QuikSCAT scatterometer data. 相似文献
338.
基于国家台网地震速报的实际工作需求,针对国家台网在全球地震速报中缺乏专门的地名查询系统,通过对国家台网实时、人机交互处理子系统和全国速报信息交换平台(EQIM系统)的相关协议和数据接口进行研究,并结合地震速报相关规定中对地名的要求,基于地理信息系统Arc GIS提供的Arc GIS Engine(AE)组件技术,采用Visual.Net开发平台和COM组件技术,来实现获取地震地名信息的功能,开发设计一套用于国家台网地震速报的地名查询辅助系统,希望可以有效提高国家台网地震速报的效率和准确度。 相似文献
339.
准确而可靠地预测地下水埋深对生态环境保护和水资源规划管理具有重要意义。针对吉林西部浅层地下水位动态变化的复杂性和非线性,提出了基于小波分析与人工神经网络相结合的预测方法小波神经网络(WA-ANN)模型。将研究区2002年1月2009年12月当月降水量、蒸发量、人工开采量和前月平均地下水埋深4个参数作为输入,当月平均地下水埋深作为输出,建立浅层地下水埋深预测模型,并与BP神经网络(BP-ANN)模型和自回归移动平均(ARIMA)模型进行比较,对比分析了三者的建模过程及其模拟精度。结果显示:相比两种ANN模型,ARIMA模型建模过程更为简单,计算效率更高;但WA-ANN模型的拟合精度高于BP-ANN和ARIMA模型,预测效果更好。总体来看,WA-ANN模型在浅层地下水埋深预测中具有一定的应用推广价值。 相似文献
340.
Decoding Neoarchaean to Palaeoproterozoic tectonothermal events in the Rangnim Massif,North Korea: regional correlation and broader implications 总被引:1,自引:0,他引:1
Xiaohui Zhang Yanbin Zhang Mingguo Zhai Fuyuan Wu Quanlin Hou Lingling Yuan 《International Geology Review》2017,59(1):16-28
Any knowledge about Archaean to Palaeoproterozoic magmatic and metamorphic events in North Korea has the potential to make a significant difference to our understanding of the early tectonic configuration and evolution of East Asia. This zircon U–Pb dating and Hf isotopic study documents multiple Neoarchaean to Palaeoproterozoic tectonothermal events from the meta-igneous complex in the Machollyong ‘Group’ of the Rangnim Massif. Two tonalitic-trondjemitic gneiss samples record a crystallization age of meta-igneous protoliths at ca. 2.56 Ga and multiple migmatization and metamorphism from 2.52 to 1.85 Ga. A meta-dolerite sample yields a magmatic emplacement age of ca. 1.83 Ga. In situ zircon Hf isotopic data indicate that most zircons from the gneiss samples have εHf(t) values from –16.9 to + 3.1 and crustal model ages from 2.84 to 3.73 Ga, whereas magmatic zircons from the meta-dolerite dike record εHf(t) values from –5.2 to + 5.2 and model ages of 2.05–2.44 Ga. The first-recognized Neoarchaean tonalitic-trondjemitic migmatite complex in the Rangnim Massif, together with previously identified tonalitic-trondhjemitic-granodioritic (TTG) rocks in the Rimjingang Belt and the coeval counterparts in western Gyeonggi massif, represents the oldest crustal nuclei in the Korean Peninsula. The multiple tectonothermal events in this study present reliable evidence not only for attesting to consanguinity of the basement between the Korean Peninsula and the North China Craton but also for defining the influence scope of the late Palaeoproterozoic orogeny in the Korean Peninsula. 相似文献