Tephrostratigraphy and paleo-environmental implications of Late Quaternary sediments and interstitial water in the western Ulleung Basin, East/Japan Sea

Two piston cores, collected from the western Ulleung Basin of the East/Japan Sea, were used to investigate the Late Quaternary tephrostratigraphy, lithology, and mineralogy of the sediments, as well as the elemental composition of both sediments and interstitial water, and their paleo-environmental implications. The cores show two lapilli tephra layers and one rhyolitic ash layer at the boundaries between sedimentary lithofacies units I, II, and III. These layers can be correlated with the well-known Ulleung-Oki (ca. 9.3 ka; boundary of units I/II), Ulleung-Yamato (ca. 25–33 ka), and Aira-Tanzawa (ca. 25.1 ka; boundary of units II/III) layers, respectively. These data suggest that the cores cover the period from the middle stage of marine isotope stage (MIS) 3 to the Holocene. In each core, a so-called dark laminated mud (DLM) layer in unit II commonly has high contents of Si and Al, suggesting that the DLM layer generally contains significant amounts of fine-grained silicates and/or aluminosilicates. In addition, these DLM layers are enriched in Fe relative to Mn, iron being predominantly bound in framboidal pyrite. The size distribution of pyrite in the DLM layers suggests that these have formed under anoxic (euxinic) conditions at times of reduced water circulation in the basin during sea-level lowstand (euxinic environment). The C/N ratios [5–12] suggest that sedimentary organic matter in the cores is predominantly of marine origin. Total organic carbon (TOC) contents increased shortly before Termination I. This could have been caused by an increased flux of marine organic matter in association with sea-level rise. The C and S values of units II and III (Late Pleistocene sediments; C: <2.0%; S: 0.5–2.1%) suggest a more euxinic environment than that of unit I (Holocene sediments; C: 1.0–3.5%; S: <1.0%). Concentrations of SO₄^2– in the interstitial water decrease with increasing burial depth, whereas CH₄ concentrations show the reverse trend. Therefore, it seems that sulfate reduction, probably related to microbial activity, predominates in the upper core sections (<5 m), shifting to methanogenesis in the lower core sections.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Fault Characteristics in Longmen Mountain Thrust Belt,Western Sichuan Foreland Basin,China

Through field geological survey,the authors found that abundant thrust faults developed in the Longmen (龙门) Mountain thrust belt.These faults can be divided into thrust faults and strike-slip faults according to their formation mechanisms and characteristics.Furthermore,these faults can be graded into primary fault,secondary fault,third-level fault,and fourth-level fault according to their scale and role in the tectonic evolution of Longmen Mountain thrust belt.Each thrust fault is composed of several secondary faults,such as Qingchuan (青川)-Maowen (茂汶) fault zone is composed of Qiaozhuang (乔庄) fault,Qingxi (青溪) fault,Maowen fault,Ganyanggou (赶羊沟) fault,etc..The Longmen Mountain thrust belt experienced early Indosinian movement,Anxian (安县) movement,Yanshan (燕山)movement,and Himalayan movement,and the faults formed gradually from north to south.     

基于相关系数匹配的混合像元分解算法

遥感影像中的混合像元不仅影响地物识别和分类的精度,而且已成为遥感科学向定量化发展的主要障碍.为此,人们已经提出了多种混合像元分解算法,其中应用最为广泛的是最小二乘法.该方法虽然具有意义明确、简单易行等特点,但也易受局部噪声、大气效应、环境辐射等因素的影响.本文将混合像元分解问题归结为一个基于光谱匹配的非线性最优化问题,并针对最小二乘法的不足提出了一种新的基于相关系数匹配(spectral correlation matching, SCM)的混合像元分解技术.通过在北京市北三环及其以北区域内案例的研究表明:在城市区域内,利用图像选取终端端元的办法,基于相关系数匹配的混合像元分解算法的总体精度高于带全约束的最小二乘法(LS)的分解结果.对比分析表明:在目标光谱的绝对值整体放大或缩小而光谱形状得到了很好的保持、及局部噪声使得光谱值显著变化但光谱形状得到了一定程度保持时,基于光谱形状的相关系数法可以得到比基于光谱绝对值的最小二乘法精度更高的分解结果.     

广西崇左三合巨猿大洞早更新世小哺乳动物群

最近在广西崇左三合大洞发现了步氏巨猿和似人似猿共生的新层位,与之伴生的有52种小哺乳动物,占三合大洞巨猿动物群总数的62%,其中苏门答腊兔（Nesolagus）是东南亚地区首次发现的化石。小哺乳动物群以南方早更新世常见的偏皮氏毛耳飞鼠（Belomys parapearsoni）、中间猪尾鼠（Typhlomys intermedius）、拟低冠竹鼠（Rhizomys brachyrhizomyoides）、硕豪猪（Hystrix magna）、先社鼠（Niviventer preconfucianus）、拟爱氏巨鼠（Leopoldamysedwardioidesi）等为代表,根据小哺乳动物群性质和与其他动物群对比以及磁性地层年代测定,表明其时代应是早更新世中期（约距今120¹60万年前）。该动物群由树鼩、扁颅蝠、小彩蝠、飞松鼠、笔尾树鼠、猪尾鼠等几乎是旧大陆热带-亚热带森林型动物组成,缺少北方类型,基本上属于热带森林动物群,这表明了当时的自然景观为温暖湿润的热带雨林环境。三合大洞小哺乳动物群是广西地区的首次发现,对华南早更新世巨猿动物群详细划分,探讨步氏巨猿演化和早期人类环境背景等目前科学界关注的问题具有重要的意义。     

Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.     

GIS支持的城市固体废弃物规划管理信息系统构建

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。     

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.     

Bringing GPS into harsh environments for fully automated deformation monitoring

Engineering projects that require deformation monitoring frequently utilize geodetic sensors to measure displacements of target points located in the deformation zone. In situations where control stations and targets are separated by a kilometer or more, GPS can offer higher precision position updates at more frequent intervals than can normally be achieved using total station technology. For large-scale deformation projects requiring the highest precision, it is therefore advisable to use a combination of the two sensors. In response to the need for high precision, continuous GPS position updates in harsh deformation monitoring environments, a software has been developed that employs triple-differenced carrier-phase measurements in a delayed-state Kalman filter. Two data sets were analyzed to test the capabilities of the software. In the first test, a GPS antenna was displaced using a translation stage to mimic slow deformation. In the second test, data collected at a large open pit mine were processed. It was shown that the delayed-state Kalman filter developed could detect millimeter-level displacements of a GPS antenna. The actual precision attained depends upon the amount of process noise infused at each epoch to accommodate the antenna displacements. Higher process noise values result in quicker detection times, but at the same time increase the noise in the solutions. A slow, 25 mm displacement was detected within 30 min of the full displacement with sigma values in E, N and U of ±10 mm or better. The same displacement could also be detected in less than 5 h with sigma values in E, N and U of ±5 mm or better. The software works best for detecting long period deformations (e.g., 20 mm per day or less) for which sigma values of 1–2 mm are attained in all three solution components. It was also shown that the triple-differenced carrier-phase observation can be used to significantly reduce the effects of residual tropospheric delay that would normally plague double-differenced observations in harsh GPS environments.